Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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A long polymer chain, such as polyethylene ( -CH2CH2- )n, can potentially exist in solution as a chiral object. Give two examples of chiral structures that a polyethylene chain could adopt.
Palmitoleic acid, a fatty acid with various pharmaceutical
applications, is mainly obtained from macadamia nuts. The
condensed structural formula for a triacylglycerol containing
three palmitoleic acid units is provided below. Which of the
following statements is NOT true regarding this
triacylglycerol?
O
||
CH,−O−C–(CH,)–CH=CH—(CH2)5–CH3
O
||
CH−O−C−(CH2)–CH=CH–(CH,)5–CH3
O
CH,−O−C−(CH,)–CH=CH–(CH,)5–CH,
O
Its name is glyceryl tripalmitate or tripalmitin.
O It is most likely to be liquid at room temperature.
O It is an oil (not a fat).
O It contains 3 molecules of the same unsaturated fatty acid.
2-bromopentane is an optically active compound. Draw the two possible structures of optical
isomer and label the chiral center with an asterisk (*) in each of the optical isomer structure.
Chapter 19 Solutions
Chemistry: An Atoms-Focused Approach
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