Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Question
Chapter 18, Problem 18.58P
Interpretation Introduction
Interpretation:
The amide formation between the given combination of dicarboxylic acid and diamine will lead to the formation of a polymer has to be shown.
Concept introduction:
Polyamides:
It is a family of
An amide linkage is shown below:
In the polymer nylon-6,6, the carbon atoms are joined together by amide bonds.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
1 Aromatic amines can be made from reacting benzene in the presence of
concentrated nitric and sulfuric acid.
a State the electrophile in the first stage of this reaction.
b State the conditions required to reduce the nitro group to an amine group.
c Draw the skeletal formula and state the name of the amine product of this
two-stage reaction.
Q4:- Draw structures, give names, and classify as primary, secondary, or tertiary amine :
the eight isomeric amines of formula CaHi.N
Q5:- Give structures and names of the principal organic reactants and products of the following reactions.
a- conversion of Carboxylic Acids into Esters
b- Hydrolysis of nitrites.
c- Hofmann degradation of amides
Q6:- Arrange the compounds of each set in order of basicity ? Explain your choice.
ethylamine, 2-aminoethanol, 3-amino-l-propanol
19. Which of the following amines does not belong to the same group?
a) aniline
c) dimethylamine
b) ethylmethylamine
d) N-isobutylmethylamine
20. Which among the following is not an alkane isomer with 6 carbon atoms?
a) Hexane
21. What will be the product between the reaction of phenol and methyl chloride with AICl catalyst?
aJm-chlorophenol
c) o-hydroxytoluene and p-hydroxytoluene
22. Which of the following alkynes goes by the common name of acetylene?
a) ethyne
b) 2,3-dimethylbutane
c) 2,2-dimethylbutane
d) Neopentane
b) o-chlorophenol and p-chlorophenol
d) m-hydroxytoluene
b) propyne
c) 1-butyne
d) 2-butyn
23. How many carbon atoms are there if an alkane has 16 hydrogen atoms
a) 5
b) 6
c) 7
d) 8
24. The name of the compound shown at the left side is
a) 3-ethyl-4-iodo-1-methylbenzene
c) 2-ethyl-1-iodo-4-methylbenzene
b)1-ethyl-2-iodo-5-methylbenzene
d) 6-ethyl-1-lodo-4-methylbenzene
25. For which of the following is cis-trans isomerism possible?
a) 1,2-dibromoethyne
b)…
Chapter 18 Solutions
Organic Chemistry
Ch. 18.1 - Prob. 18.1PCh. 18.2 - Prob. 18.2PCh. 18.4 - Prob. 18.3PCh. 18.4 - Prob. 18.4PCh. 18.4 - Synthesis of nitriles by nucleophilic displacement...Ch. 18.5 - Complete the following transesterification...Ch. 18.6 - Complete and balance equations for the following...Ch. 18.8 - Prob. AQCh. 18.8 - Several compounds have been found to inhibit...Ch. 18.8 - Prob. CQ
Ch. 18.8 - The following sequence of steps is used to create...Ch. 18.9 - Prob. 18.8PCh. 18.9 - Prob. 18.9PCh. 18.10 - Prob. 18.10PCh. 18.10 - Show how to convert (R)-2-phenylpropanoic acid to...Ch. 18 - Prob. 18.12PCh. 18 - Write the IUPAC name for each compound. (a)...Ch. 18 - Prob. 18.14PCh. 18 - Prob. 18.15PCh. 18 - Propose a structural formula for compound A,...Ch. 18 - Propose a structural formula for compound B,...Ch. 18 - Propose a structural formula for each compound...Ch. 18 - Draw a structural formula for the principal...Ch. 18 - Prob. 18.20PCh. 18 - Prob. 18.21PCh. 18 - Prob. 18.22PCh. 18 - Prob. 18.23PCh. 18 - Prob. 18.24PCh. 18 - Show the product expected when the following...Ch. 18 - The reagent diisobutylaluminum hydride (DIBALH)...Ch. 18 - Prob. 18.27PCh. 18 - Prob. 18.28PCh. 18 - Prob. 18.29PCh. 18 - Nicotinic acid, more commonly named niacin, is one...Ch. 18 - Prob. 18.31PCh. 18 - Prob. 18.32PCh. 18 - Prob. 18.33PCh. 18 - Prob. 18.34PCh. 18 - Prob. 18.35PCh. 18 - Isoniazid, a drug used to treat tuberculosis, is...Ch. 18 - Prob. 18.37PCh. 18 - A step in a synthesis of PGE1 (prostaglandin E1,...Ch. 18 - Prob. 18.39PCh. 18 - Prob. 18.40PCh. 18 - Show how to synthesize 5-nonanone from...Ch. 18 - Prob. 18.42PCh. 18 - The following sequence of steps converts...Ch. 18 - Prob. 18.44PCh. 18 - Prob. 18.45PCh. 18 - Prob. 18.46PCh. 18 - Prob. 18.47PCh. 18 - Following is a retrosynthetic analysis for the...Ch. 18 - Prob. 18.50PCh. 18 - Given this retrosynthetic analysis, propose a...Ch. 18 - Prob. 18.52PCh. 18 - Prob. 18.53PCh. 18 - Prob. 18.54PCh. 18 - In Problem 7.28, we saw this step in Johnsons...Ch. 18 - Prob. 18.56PCh. 18 - Prob. 18.57PCh. 18 - Prob. 18.58PCh. 18 - Prob. 18.59PCh. 18 - Prob. 18.60PCh. 18 - Prob. 18.61PCh. 18 - Prob. 18.62PCh. 18 - Using your reaction roadmap as a guide, show how...Ch. 18 - Using your reaction roadmap as a guide, show how...Ch. 18 - Using your reaction roadmap as a guide, show how...Ch. 18 - Using your reaction roadmap as a guide, show how...Ch. 18 - Minoxidil is a molecule that causes hair growth in...Ch. 18 - Prob. 18.69PCh. 18 - Prob. 18.70PCh. 18 - Prob. 18.71P
Knowledge Booster
Similar questions
- H NH₂ ཡིནྣཾ ༥ ཨ ཨནྡྷ༥ ༠ ཨི་ཝཱ, ཙ ཨ་ར༩ H NH3+ the acidity of the amine ion drives the reaction to shift toward the conjugate base of the carboxylic acid product. the resulting carboxylic acid ion is a weaker base than an acetate ion. O aldehydes are more reactive toward nucleophiles than ketones. Onucleophilic attack occurs preferentially at the less hindered carbon of the formyl group.arrow_forward14. Write the name of different product formed when primary (aniline), secondary (N-methylaniline) and tertiary aromatic amine (N,N-dimethylaniline) reacts with nitrous acid (NaNO2 + HCl).arrow_forwardOne frequently used method for preparing methyl esters is by reaction of carboxylic acids with diazomethane, CH2N2. The reaction occurs in two steps: (l) protonation of diazomethane by the carboxylic acid to yield methyldiazonium ion, CH3N2+, plus a carboxylate ion; and (2) reaction of the carboxylate ion with CH3N2+. (a) Draw two resonance structures of diazomethane, and account for step 1. (b) What kind of reaction occurs in step 2?arrow_forward
- Naming Amides Named as a derivative of the carboxylic acid Take carboxylic acid name, remove-ic acid Add-amide to common name or IUPAC H-C-OH Formic acid (methanoic acid) O H–C—NH, Formamide (methanamide) 2 O NH₂arrow_forwardEsters and amides can both be hydrolyzed under acidic or basic conditions. Given the molecule below, choose the 3 products that it would break up into when it is hydrolyzed. A B с OH D H+, heat, H₂O E F HO OH G HO. zu Gigué OH _OH H 1+ I کمه نکنندarrow_forward5. Complete the neutralization reaction of the following amine by hydrochloric acid (HCI). CH,-CH,-CH,-CH,-N-CH,-CH, HCI ČH, 6. Complete the reaction for the acid hydrolysis of the following amide. CH,-CH-CH,-C-N-CH,-CH, CH, Нeat + H,0 + HCI 7. Draw the condensed structural formula for the amide needed for the base hydrolysis resulting in the formation of the following products. heat NAOH H-C-ONA + CH; - CH, - NH,arrow_forward
- When hexanoic acid (a carboxlic acid) is heated, a reaction takes place that generates water (which must be removed) and a non-acidic product. What is the product? carboxylate carboxylic acid anhydride ester amide lies! all lies! no reaction will take place!arrow_forwardThe reaction of any carbonyl group with an amine produces the imine * true false The cationic methoxy group is a resonant impulse group* O true O false Carmine is an indole compound produced by the reaction of all amino acids true falsearrow_forwardMethyl amine reacts with nitric acid. You should be able to predict the products of this reaction.arrow_forward
- reactions similar? How are the reactions different? Give an example of each reaction. Draw structures and name Compare and contrast the neutralization of a carboxylic acid to the neutralization of an amine. How are the 3. the compounds involved. bos nimensc thabi hne ebo onede wend loby hom upo yant 4. Start with NH3 and show step-by-step how the compound N-sec-butyl-N-isopropyl-3-pentanamine can be formed. Draw and name the reactants and products in each reaction (3 separate reactions.) slee-uns ns sis muiboz e ni boeszinmbs clevlo tiez raulbo 5. Salicylic acid (shown below) is a polyfunctional molecule (contains more than one functional group.) Circle and identify the functional groups on salicylic acid. Salicylic acid can react with ethanoic acid (acetic acid) to form aspirin. It can also react with ethanol to form ethyl salicylate, a compound with a minty smell used in perfume and artificial flavors. Draw out structures to illustrate each of these reactions. Discuss how these two…arrow_forwardDraw a structure for the product formed in this reductive amination reaction. Upload a jpg image of your answer showing the full reaction (not just the product). + HN NaBH₂CN, EtOH, pH= 4arrow_forward3. React the following three components. Which type of molecule will you obtain after the complete reaction? Make sure you draw the structure and label the amide bond, the phosphoester bond, and ester bond. OH O Myrstic acid + HO + 7:0 :0: NH₂ -Harrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning