(a)
Interpretation:
The product formed by treating butanol with the given reagent has to be drawn.
(b)
Interpretation:
The product formed by treating butanol with the given reagent has to be drawn.
(c)
Interpretation:
The product formed by treating butanol with the given reagent has to be drawn.
(d)
Interpretation:
The product formed by treating butanol with the given reagent has to be drawn.
(e)
Interpretation:
The product formed by treating butanol with the given reagent has to be drawn.
(f)
Interpretation:
The product formed by treating butanol with the given reagent has to be drawn.
(g)
Interpretation:
The product formed by treating butanol with the given reagent has to be drawn.
(h)
Interpretation:
The product formed by treating butanol with the given reagent has to be drawn.
(i)
Interpretation:
The product formed by treating butanol with the given reagent has to be drawn.
(j)
Interpretation:
The product formed by treating butanol with the given reagent has to be drawn.
(k)
Interpretation:
The product formed by treating butanol with the given reagent has to be drawn.
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Chapter 16 Solutions
Organic Chemistry
- Predict the major products formed when benzoyl chloride (PhCOCl) reacts with the following reagents.(a) ethanol (b) sodium acetate (c) anilinearrow_forwardPredict the major product when each reagent reacts with ethylene oxide.(a) NaOCH2CH3 (sodium ethoxide) (b) NaNH2 (sodium amide)arrow_forwardWhich is the stronger acid in each of the following pairs? Explain your reasoning. (a) Phenol or p-hydroxybenzaldehyde (b) m-Cyanophenol or p-cyanophenol (c) o-Fluorophenol or p-fluorophenolarrow_forward
- The odor of ripe bananas and many other fruits is due to the presence of esters. For example: Banana oil (isopentyl acetate) (a) Write the name (common or IUPAC) of the ester responsible for the fragrance of the following: pineapple, orange, apple, peach, & lavender (b) Choose one fragrant from (a) and name the alcohol and the carboxylic acid needed to synthesize this ester. (c) Show the detailed mechanism of the Fischer Esterification reaction that will be involved in the synthesis of the fragrant you have chosen in part (a).arrow_forward(a) Although phenoxide ion has more number of resonating structures than carboxylate ion, carboxylic acid is a stronger acid than phenol. Give two reasons.(b) How will you bring about the following converstions?(i) Propanone to propane (ii) Benzoyl chloride to benzaldehyde(iii) Ethanal to but-2-enalarrow_forward(a) Give chemical tests to distinguish between the following pairs of compounds :(i) Pentan-2-ol and Pentan-3-ol (ii) Methanol and Phenol(b) o-nitro phenol is more acidic than o-methoxy phenol. Explain why.arrow_forward
- (a) How will you convert:(i) Benzene to acetophenone (ii) Propanone to 2-Methylpropan-2-ol(b) Give reasons :(i) Electrophilic substitution in benzoic acid takes place at meta position.(ii) Carboxylic acids are higher boiling liquids than aldehydes, ketones and alcohols of comparable molecular masses.(iii) Propanal is more reactive than propanone in nucleophilic addition reactions.arrow_forwardWrite a balanced chemical equation for each of the following reactions: (a) Phenol + sodium hydroxide (b) Product of part (a) + ethyl bromide (c) Product of part (a) + butyl p-toluenesulfonate (d) Product of part (a) + acetic anhydride (e) o-Cresol + benzoyl chloride (f) m-Cresol + ethylene oxide (g) 2,6-Dichlorophenol + bromine (h) p-Cresol + excess aqueous bromine (i) Isopropyl phenyl ether + excess hydrogen bromide + heatarrow_forward6) If you are given a mixture consisting of following 3 compounds, explain how you would separate the components by solvent extraction method NH2 ÇOOH (A) Cyclopentylamine (B) 2,4-Cyclopentadiene-1-carboxylic acid (C) Benzenearrow_forward
- Electrophilic aromatic substitution usually occurs at the 1-position of naphthalene, also called the a position. Predict the major products of the reactions of naphthalene with the following reagents.(a) isobutylene and HF (b) cyclohexanol and BF3 (c) fuming sulfuric acidarrow_forwardPredict the major product when each reagent reacts with ethylene oxide. (a) KCN (potassium cyanide) (b) NaN3 (sodium azide)arrow_forwardArrange each group of compounds in order of increasing basicity.(a) CH3COO-, ClCH2COO-, and PhO- (b) sodium acetylide, sodium amide, and sodium acetate(c) sodium benzoate, sodium ethoxide, and sodium phenoxide (d) pyridine, sodium ethoxide, and sodium acetatearrow_forward
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