(a) Interpretation: Whether CO 2 would have pure vibrational spectra or not is to be stated. Concept introduction: Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

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Answer 1

Question

Chapter 14, Problem 14.60E

Interpretation Introduction

(a)

Interpretation:

Whether CO2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(b)

Interpretation:

Whether H2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(c)

Interpretation:

Whether NaCl would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(d)

Interpretation:

Whether SO32− would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

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P7E.1 If the vibration of a diatomic A-B is modelled using a harmonic oscillator, the vibrational frequency is given by w=(k; /u)", where u is the effective mass, µ=m,m,/(m, +m,). If atom A is substituted by an isotope (for example H substituted for 'H), then to a good approximation the force constant remains the same. Why? (Hint: Is there any change in the number of charged species?) (a) Show that when an isotopic substitution is made for atom A, such that its mass changes from m, to m, the vibrational frequency of A'-B, wAp can be expressed in terms of the vibrational frequency of A-B, @ An as o x=0 A (H/H", where u AB and u, are the effective masses of A-B and A'-B, respectively. (b) The vibrational frequency of 'HCl is 5.63 x 10"s". Calculate the vibrational frequency of (i) 'H*Cl and (ii) 'H"Cl. Use integer relative atomic masses. A'B

Answer 2

Question

Chapter 14, Problem 14.60E

Interpretation Introduction

(a)

Interpretation:

Whether CO2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(b)

Interpretation:

Whether H2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(c)

Interpretation:

Whether NaCl would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(d)

Interpretation:

Whether SO32− would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

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Answer 3

Question

Chapter 14, Problem 14.60E

Interpretation Introduction

(a)

Interpretation:

Whether CO2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(b)

Interpretation:

Whether H2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(c)

Interpretation:

Whether NaCl would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(d)

Interpretation:

Whether SO32− would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Expert Solution & Answer

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Answer 4

Question

Chapter 14, Problem 14.60E

Interpretation Introduction

(a)

Interpretation:

Whether CO2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(b)

Interpretation:

Whether H2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(c)

Interpretation:

Whether NaCl would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(d)

Interpretation:

Whether SO32− would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Expert Solution & Answer

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Answer 5

Chapter 14, Problem 14.60E

Interpretation Introduction

(a)

Interpretation:

Whether CO2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(b)

Interpretation:

Whether H2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(c)

Interpretation:

Whether NaCl would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(d)

Interpretation:

Whether SO32− would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 6

Chapter 14, Problem 14.60E

Interpretation Introduction

(a)

Interpretation:

Whether CO2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 7

Chapter 14, Problem 14.60E

Interpretation Introduction

(a)

Interpretation:

Whether CO2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether H2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether H2 would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Whether NaCl would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Whether NaCl would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Whether SO32− would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Whether SO32− would have pure vibrational spectra or not is to be stated.

Concept introduction:

Vibrational spectroscopy is the observed due to vibration of accompanied in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Answer 14

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Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 14 - Prob. 14.1E Ch. 14 - Determine if the following integrals can be...Ch. 14 - What is the frequency of light having the...Ch. 14 - What is the wavelength of light having the given...Ch. 14 - What is the energy of light having each...Ch. 14 - The Cu(H2O)62+ complex has octahedral symmetry. Is...Ch. 14 - What are the wavelength, speed, and energy of a...Ch. 14 - Prob. 14.8E Ch. 14 - Prob. 14.9E Ch. 14 - Prob. 14.10E

Solution Summary: The author explains that vibrational spectroscopy is observed due to vibration of accompanied in a molecule.

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Chapter 14 Solutions