The reason as to why rotational spectrum cannot be observed for the rotation of a linear molecule about its linear axis is to be stated. Concept introduction: An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant. This is known as the Franck-Condon principle.

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Answer 1

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Chapter 14, Problem 14.1E

Interpretation Introduction

Interpretation:

The reason as to why rotational spectrum cannot be observed for the rotation of a linear molecule about its linear axis is to be stated.

Concept introduction:

An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant. This is known as the Franck-Condon principle.

Expert Solution & Answer

Answer to Problem 14.1E

The rotational spectrum for the rotation of a linear molecule about its linear axis is not observed because when a linear molecule is rotated along its linear axis, the position of dipole remains unchanged.

Explanation of Solution

The rotational spectrum for a molecule is observed when the rotation of molecule changes the position of dipole. When a linear molecule is rotated along its linear axis, the position of dipole remains unchanged. Therefore, the rotational spectrum is not observed for rotation of a linear molecule.

Conclusion

The rotational spectrum for the rotation of a linear molecule about its linear axis is not observed because when a linear molecule is rotated along its linear axis, the position of dipole remains unchanged.

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Answer 2

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Chapter 14, Problem 14.1E

Interpretation Introduction

Interpretation:

The reason as to why rotational spectrum cannot be observed for the rotation of a linear molecule about its linear axis is to be stated.

Concept introduction:

An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant. This is known as the Franck-Condon principle.

Expert Solution & Answer

Answer to Problem 14.1E

The rotational spectrum for the rotation of a linear molecule about its linear axis is not observed because when a linear molecule is rotated along its linear axis, the position of dipole remains unchanged.

Explanation of Solution

The rotational spectrum for a molecule is observed when the rotation of molecule changes the position of dipole. When a linear molecule is rotated along its linear axis, the position of dipole remains unchanged. Therefore, the rotational spectrum is not observed for rotation of a linear molecule.

Conclusion

The rotational spectrum for the rotation of a linear molecule about its linear axis is not observed because when a linear molecule is rotated along its linear axis, the position of dipole remains unchanged.

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Answer 3

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Chapter 14, Problem 14.1E

Interpretation Introduction

Interpretation:

The reason as to why rotational spectrum cannot be observed for the rotation of a linear molecule about its linear axis is to be stated.

Concept introduction:

An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant. This is known as the Franck-Condon principle.

Expert Solution & Answer

Answer to Problem 14.1E

The rotational spectrum for the rotation of a linear molecule about its linear axis is not observed because when a linear molecule is rotated along its linear axis, the position of dipole remains unchanged.

Explanation of Solution

The rotational spectrum for a molecule is observed when the rotation of molecule changes the position of dipole. When a linear molecule is rotated along its linear axis, the position of dipole remains unchanged. Therefore, the rotational spectrum is not observed for rotation of a linear molecule.

Conclusion

The rotational spectrum for the rotation of a linear molecule about its linear axis is not observed because when a linear molecule is rotated along its linear axis, the position of dipole remains unchanged.

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Answer 4

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Chapter 14, Problem 14.1E

Interpretation Introduction

Interpretation:

The reason as to why rotational spectrum cannot be observed for the rotation of a linear molecule about its linear axis is to be stated.

Concept introduction:

An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant. This is known as the Franck-Condon principle.

Expert Solution & Answer

Answer to Problem 14.1E

The rotational spectrum for the rotation of a linear molecule about its linear axis is not observed because when a linear molecule is rotated along its linear axis, the position of dipole remains unchanged.

Explanation of Solution

The rotational spectrum for a molecule is observed when the rotation of molecule changes the position of dipole. When a linear molecule is rotated along its linear axis, the position of dipole remains unchanged. Therefore, the rotational spectrum is not observed for rotation of a linear molecule.

Conclusion

The rotational spectrum for the rotation of a linear molecule about its linear axis is not observed because when a linear molecule is rotated along its linear axis, the position of dipole remains unchanged.

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Answer 5

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Answer 6

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Answer 7

Chapter 14, Problem 14.1E

Interpretation Introduction

Interpretation:

The reason as to why rotational spectrum cannot be observed for the rotation of a linear molecule about its linear axis is to be stated.

Concept introduction:

An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant. This is known as the Franck-Condon principle.

Expert Solution & Answer

Answer to Problem 14.1E

The rotational spectrum for the rotation of a linear molecule about its linear axis is not observed because when a linear molecule is rotated along its linear axis, the position of dipole remains unchanged.

Explanation of Solution

The rotational spectrum for a molecule is observed when the rotation of molecule changes the position of dipole. When a linear molecule is rotated along its linear axis, the position of dipole remains unchanged. Therefore, the rotational spectrum is not observed for rotation of a linear molecule.

Conclusion

The rotational spectrum for the rotation of a linear molecule about its linear axis is not observed because when a linear molecule is rotated along its linear axis, the position of dipole remains unchanged.

Answer 8

Chapter 14, Problem 14.1E

Interpretation Introduction

Interpretation:

The reason as to why rotational spectrum cannot be observed for the rotation of a linear molecule about its linear axis is to be stated.

Concept introduction:

An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant. This is known as the Franck-Condon principle.

Expert Solution & Answer

Answer to Problem 14.1E

The rotational spectrum for the rotation of a linear molecule about its linear axis is not observed because when a linear molecule is rotated along its linear axis, the position of dipole remains unchanged.

Explanation of Solution

The rotational spectrum for a molecule is observed when the rotation of molecule changes the position of dipole. When a linear molecule is rotated along its linear axis, the position of dipole remains unchanged. Therefore, the rotational spectrum is not observed for rotation of a linear molecule.

Conclusion

The rotational spectrum for the rotation of a linear molecule about its linear axis is not observed because when a linear molecule is rotated along its linear axis, the position of dipole remains unchanged.

Answer 9

Chapter 14, Problem 14.1E

Interpretation Introduction

Interpretation:

The reason as to why rotational spectrum cannot be observed for the rotation of a linear molecule about its linear axis is to be stated.

Concept introduction:

An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant. This is known as the Franck-Condon principle.

Answer 10

Expert Solution & Answer

Answer to Problem 14.1E

The rotational spectrum for the rotation of a linear molecule about its linear axis is not observed because when a linear molecule is rotated along its linear axis, the position of dipole remains unchanged.

Answer 11

Expert Solution & Answer

Answer 12

Expert Solution & Answer

Answer 13

Explanation of Solution

The rotational spectrum for a molecule is observed when the rotation of molecule changes the position of dipole. When a linear molecule is rotated along its linear axis, the position of dipole remains unchanged. Therefore, the rotational spectrum is not observed for rotation of a linear molecule.

Answer 14

Conclusion

The rotational spectrum for the rotation of a linear molecule about its linear axis is not observed because when a linear molecule is rotated along its linear axis, the position of dipole remains unchanged.

Answer 15

Ch. 14 - Prob. 14.1E Ch. 14 - Determine if the following integrals can be...Ch. 14 - What is the frequency of light having the...Ch. 14 - What is the wavelength of light having the given...Ch. 14 - What is the energy of light having each...Ch. 14 - The Cu(H2O)62+ complex has octahedral symmetry. Is...Ch. 14 - What are the wavelength, speed, and energy of a...Ch. 14 - Prob. 14.8E Ch. 14 - Prob. 14.9E Ch. 14 - Prob. 14.10E

Answer to Problem 14.1E

Explanation of Solution

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Chapter 14 Solutions