Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Question
Chapter 14, Problem 14.58E
Interpretation Introduction
Interpretation:
Arrows, indicating the vibrational modes of
Concept introduction:
Vibrational spectroscopy is observed due to vibrational motion accompanied in a molecule. The mode which is IR active is associated with the change in the dipole moment of the molecule.
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7. Consider the Jablonski diagrams below, where So, S₁, and S2 are all singlet electronic
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E
Diagram #1 - Fluorescence process
S₂
S₁
So
SS5
T₁
Vo
V4
V3
55555
V₂
V₁
V₁
Diagram #2 - Phosphorescence process
E
S₂
S₁
So
55555
Vo
T₁
7.1 Diagram #1: After the absorption shown in the diagram, the molecule fluoresces,
emitting a photon with = 310 nm.
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7.2 Diagram #2: After the absorption…
Chapter 14 Solutions
Physical Chemistry
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Ch. 14 - Prob. 14.11ECh. 14 - Prob. 14.12ECh. 14 - Prob. 14.13ECh. 14 - Prob. 14.14ECh. 14 - Diatomic sulfur, S2, was detected in the tail of...Ch. 14 - Prob. 14.16ECh. 14 - Prob. 14.17ECh. 14 - Prob. 14.18ECh. 14 - Prob. 14.19ECh. 14 - Prob. 14.20ECh. 14 - Prob. 14.21ECh. 14 - Prob. 14.22ECh. 14 - Which of the following molecules should have pure...Ch. 14 - Which of the following molecules should have pure...Ch. 14 - The following are sets of rotational quantum...Ch. 14 - The following are sets of rotational quantum...Ch. 14 - Derive equation 14.21 from the E expression...Ch. 14 - Prob. 14.28ECh. 14 - Prob. 14.29ECh. 14 - Lithium hydride, 7Li1H, is a potential fuel for...Ch. 14 - Prob. 14.31ECh. 14 - Prob. 14.32ECh. 14 - Prob. 14.33ECh. 14 - Prob. 14.34ECh. 14 - Prob. 14.35ECh. 14 - Prob. 14.36ECh. 14 - From the data in Table 14.2, predict B for DCl D...Ch. 14 - A colleague states that the pure rotational...Ch. 14 - Prob. 14.39ECh. 14 - Prob. 14.40ECh. 14 - Prob. 14.41ECh. 14 - Prob. 14.42ECh. 14 - Prob. 14.43ECh. 14 - Determine E for J=20J=21 for HBr assuming it acts...Ch. 14 - Determine the number of total degrees of freedom...Ch. 14 - Determine the number of total degrees of freedom...Ch. 14 - Prob. 14.47ECh. 14 - Prob. 14.48ECh. 14 - Prob. 14.49ECh. 14 - Prob. 14.50ECh. 14 - Prob. 14.51ECh. 14 - Prob. 14.52ECh. 14 - Prob. 14.53ECh. 14 - Prob. 14.54ECh. 14 - Prob. 14.55ECh. 14 - Prob. 14.56ECh. 14 - Prob. 14.57ECh. 14 - Prob. 14.58ECh. 14 - Prob. 14.59ECh. 14 - Prob. 14.60ECh. 14 - Prob. 14.61ECh. 14 - Prob. 14.62ECh. 14 - Prob. 14.63ECh. 14 - Prob. 14.64ECh. 14 - Prob. 14.65ECh. 14 - Prob. 14.66ECh. 14 - Prob. 14.68ECh. 14 - Prob. 14.69ECh. 14 - Prob. 14.70ECh. 14 - Prob. 14.71ECh. 14 - Prob. 14.72ECh. 14 - Prob. 14.73ECh. 14 - Prob. 14.74ECh. 14 - Prob. 14.75ECh. 14 - Prob. 14.76ECh. 14 - Prob. 14.77ECh. 14 - Prob. 14.78ECh. 14 - Prob. 14.79ECh. 14 - Prob. 14.80ECh. 14 - Prob. 14.81ECh. 14 - Prob. 14.82ECh. 14 - Prob. 14.83ECh. 14 - Prob. 14.84ECh. 14 - Prob. 14.85ECh. 14 - Dioctyl sulfide, (C8H17)2S, and hexadecane,...Ch. 14 - Where would you expect vibrations for ethyl...Ch. 14 - Prob. 14.88ECh. 14 - Prob. 14.89ECh. 14 - Prob. 14.90ECh. 14 - Prob. 14.91ECh. 14 - Prob. 14.92ECh. 14 - Prob. 14.93ECh. 14 - Prob. 14.94ECh. 14 - The mutual exclusion rule states that for certain...Ch. 14 - Prob. 14.96ECh. 14 - Prob. 14.97ECh. 14 - Prob. 14.98ECh. 14 - Prob. 14.99ECh. 14 - Construct and compare the energy level diagrams...Ch. 14 - Prob. 14.101E
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