(a) Interpretation: The individual lines detected for J = 0 → J = 1 are to be stated. Concept introduction: The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

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Answer 1

Question

Chapter 14, Problem 14.36E

Interpretation Introduction

(a)

Interpretation:

The individual lines detected for J=0→J=1 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Interpretation Introduction

(b)

Interpretation:

The individual lines detected for J=1→J=2 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Interpretation Introduction

(c)

Interpretation:

The individual lines detected for J=2→J=3 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

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Students have asked these similar questions

An H2 molecule is in its vibrational and rotational ground states. It absorbs a photon of wavelength 2.211 2 μm and makes a transition to the υ = 1, J = 1 energy level. It then drops to the υ = 0, J = 2 energy level while emitting a photon of wavelength 2.405 4 mm. Calculate (a) the moment of inertia of the H2 molecule about an axis through its center of mass and perpendicular to the H–H bond, (b) the vibrational frequency of the H2 molecule, and (c) the equilibrium separation distance for this molecule.

Rotational spectra are affected slightly by the fact that different isotopes have different masses. Suppose a sample of the common isotope 1H35Cl is changed to 1H37Cl. (a) By what fraction is the molecule’s rotational inertia different? (The bond length is 0.127 nm in each case.) (b) What is the change in energy of theℓ = 1 to theℓ = 0 transition if the isotope is changed?

Consider the rotational spectrum of a linear molecule at 298 K with a moment of inertia of 1.23×10−461.23\times10^{-46}1.23×10−46 kg m2 . (a) What is the frequency for the transition from J = 2 to J = 3? (b) What is the most populated rotational level for this molecule? Would the transition in (a) give the most intense signal in the rotational spectrum?

Answer 2

Question

Chapter 14, Problem 14.36E

Interpretation Introduction

(a)

Interpretation:

The individual lines detected for J=0→J=1 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Interpretation Introduction

(b)

Interpretation:

The individual lines detected for J=1→J=2 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Interpretation Introduction

(c)

Interpretation:

The individual lines detected for J=2→J=3 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

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Answer 3

Question

Chapter 14, Problem 14.36E

Interpretation Introduction

(a)

Interpretation:

The individual lines detected for J=0→J=1 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Interpretation Introduction

(b)

Interpretation:

The individual lines detected for J=1→J=2 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Interpretation Introduction

(c)

Interpretation:

The individual lines detected for J=2→J=3 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Expert Solution & Answer

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Answer 4

Question

Chapter 14, Problem 14.36E

Interpretation Introduction

(a)

Interpretation:

The individual lines detected for J=0→J=1 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Interpretation Introduction

(b)

Interpretation:

The individual lines detected for J=1→J=2 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Interpretation Introduction

(c)

Interpretation:

The individual lines detected for J=2→J=3 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Expert Solution & Answer

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Answer 5

Chapter 14, Problem 14.36E

Interpretation Introduction

(a)

Interpretation:

The individual lines detected for J=0→J=1 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Interpretation Introduction

(b)

Interpretation:

The individual lines detected for J=1→J=2 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Interpretation Introduction

(c)

Interpretation:

The individual lines detected for J=2→J=3 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Answer 6

Chapter 14, Problem 14.36E

Interpretation Introduction

(a)

Interpretation:

The individual lines detected for J=0→J=1 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Answer 7

Chapter 14, Problem 14.36E

Interpretation Introduction

(a)

Interpretation:

The individual lines detected for J=0→J=1 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The individual lines detected for J=1→J=2 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The individual lines detected for J=1→J=2 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The individual lines detected for J=2→J=3 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The individual lines detected for J=2→J=3 are to be stated.

Concept introduction:

The shifting and splitting of spectra lines of atoms and molecules when the molecule is subjected under external electric field is known as Stark-effect. The emission and absorption lines are observed in Stark-effect.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 14 - Prob. 14.1E Ch. 14 - Determine if the following integrals can be...Ch. 14 - What is the frequency of light having the...Ch. 14 - What is the wavelength of light having the given...Ch. 14 - What is the energy of light having each...Ch. 14 - The Cu(H2O)62+ complex has octahedral symmetry. Is...Ch. 14 - What are the wavelength, speed, and energy of a...Ch. 14 - Prob. 14.8E Ch. 14 - Prob. 14.9E Ch. 14 - Prob. 14.10E

Solution Summary: The author explains that the number of individual lines for J=0toJ=2 transition is two. The selection rule for the transitions from one state to another is given.

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Chapter 14 Solutions