Foundations of Materials Science and Engineering
6th Edition
ISBN: 9781259696558
Author: SMITH
Publisher: MCG
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Chapter 13.10, Problem 11KCP
(a)
To determine
Describe the oxide theory of metal passivitiy.
(b)
To determine
Describe the adsorption theory of metal passivitiy.
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Chapter 13 Solutions
Foundations of Materials Science and Engineering
Ch. 13.10 - Prob. 1KCPCh. 13.10 - Prob. 2KCPCh. 13.10 - Which is in a lower energy state: (a) elemental...Ch. 13.10 - Give several examples of environmental...Ch. 13.10 - Prob. 5KCPCh. 13.10 - Prob. 6KCPCh. 13.10 - Prob. 7KCPCh. 13.10 - What is an exchange current density? What is the...Ch. 13.10 - Prob. 9KCPCh. 13.10 - Prob. 10KCP
Ch. 13.10 - Prob. 11KCPCh. 13.10 - Prob. 12KCPCh. 13.10 - Prob. 13KCPCh. 13.10 - Prob. 14KCPCh. 13.10 - Prob. 15KCPCh. 13.10 - Prob. 16KCPCh. 13.10 - Prob. 17KCPCh. 13.10 - Prob. 18KCPCh. 13.10 - Prob. 19KCPCh. 13.10 - Describe fretting corrosion.Ch. 13.10 - What is selective leaching of an alloy? Which...Ch. 13.10 - Prob. 22KCPCh. 13.10 - Prob. 23KCPCh. 13.10 - Prob. 24KCPCh. 13.10 - Prob. 25KCPCh. 13.10 - Prob. 26KCPCh. 13.10 - Prob. 27KCPCh. 13.10 - What are Alclad alloys?Ch. 13.10 - Prob. 29AAPCh. 13.10 - Prob. 30AAPCh. 13.10 - Prob. 31AAPCh. 13.10 - Prob. 32AAPCh. 13.10 - Prob. 33AAPCh. 13.10 - The emf of a standard Ni-Cd galvanic cell is...Ch. 13.10 - What is the emf with respect to the standard...Ch. 13.10 - Prob. 36AAPCh. 13.10 - Prob. 37AAPCh. 13.10 - Prob. 38AAPCh. 13.10 - Prob. 39AAPCh. 13.10 - Prob. 40AAPCh. 13.10 - Prob. 41AAPCh. 13.10 - Prob. 42AAPCh. 13.10 - Prob. 43AAPCh. 13.10 - Prob. 44AAPCh. 13.10 - Prob. 45AAPCh. 13.10 - Prob. 46AAPCh. 13.10 - Prob. 47AAPCh. 13.10 - Prob. 48AAPCh. 13.10 - Prob. 49AAPCh. 13.10 - Prob. 50AAPCh. 13.10 - Prob. 51AAPCh. 13.10 - Prob. 52AAPCh. 13.10 - Prob. 53AAPCh. 13.10 - Prob. 54AAPCh. 13.10 - A galvanized (zinc-coaled) steel sheet is found to...Ch. 13.10 - Prob. 56AAPCh. 13.10 - Prob. 57AAPCh. 13.10 - Prob. 58AAPCh. 13.10 - Prob. 59AAPCh. 13.10 - Prob. 60AAPCh. 13.10 - Prob. 61AAPCh. 13.10 - Prob. 62AAPCh. 13.10 - Prob. 63AAPCh. 13.10 - Prob. 64AAPCh. 13.10 - Prob. 65AAPCh. 13.10 - Prob. 66AAPCh. 13.10 - Prob. 67AAPCh. 13.10 - Prob. 68AAPCh. 13.10 - Prob. 69AAPCh. 13.10 - Prob. 70AAPCh. 13.10 - Prob. 71AAPCh. 13.10 - Prob. 72AAPCh. 13.10 - Prob. 73AAPCh. 13.10 - Prob. 74AAPCh. 13.10 - Prob. 75AAPCh. 13.10 - Prob. 76SEPCh. 13.10 - Prob. 77SEPCh. 13.10 - Prob. 78SEPCh. 13.10 - Prob. 79SEPCh. 13.10 - Prob. 80SEPCh. 13.10 - Prob. 81SEPCh. 13.10 - Prob. 82SEPCh. 13.10 - Prob. 83SEPCh. 13.10 - Prob. 84SEPCh. 13.10 - Corrosion is observed at the root of threads on...Ch. 13.10 - Prob. 86SEPCh. 13.10 - Prob. 87SEPCh. 13.10 - Prob. 88SEPCh. 13.10 - Prob. 89SEPCh. 13.10 - Prob. 90SEPCh. 13.10 - Prob. 91SEPCh. 13.10 - Prob. 92SEPCh. 13.10 - Prob. 93SEPCh. 13.10 - Prob. 94SEPCh. 13.10 - Prob. 95SEPCh. 13.10 - Prob. 96SEPCh. 13.10 - Prob. 97SEPCh. 13.10 - Prob. 98SEP
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- 1 Plastic Deformation Occurs Through Dislocation Motion... ...so in order to make a material stronger, we should prevent dislocations from moving. For each of the following alloys, identify the strengthening mechanism and explain how it impedes dislocation motion: A. An aluminum alloy "inoculated" with TiB2 during solidification, producing a large number of small grains. B. Monel, a corrosion-resistant solid solution of Ni and Cu. C. An aluminum-lithium aerospace alloy containing precipitates of Al3Li. D. Wrought iron, which is often worked into complex shapes such as railings or furniture.arrow_forwardIn preventing corrosion of iron, a stronger reducing agent called sacrificial anode such as zinc is used to coat iron. Select one: True Falsearrow_forwardQuestion 3: : Estimate the corrosion rate (g/cm².s), penetration rate (mm/yr), and Ecorr (V) for a zinc tank containing oxygen free solution (pH =0). Assume the anodic reaction is under activation control and cathodic reactions is under activation and concentration control with the limiting current density for hy- drogen reduction on Zn is 5×10-5 A/cm?. [Zn**] = 1M at 298 K. The atomic weight of zinc is 65.4 g/mol. Density of zinc is 7.13 g/cm³. io, Zn = 1×10-7 A/cm², ßa= 0.09 V/decade io, H= 1×10-10 A/cm?, Bc= -0.08 V/decade icorr = 1.2×10-4 A/cm2arrow_forward
- QUESTION 2: Consider 2 kg of a (30 wt % Sn – 70 wt % Pb) solder alloy. The phase diagram of the lead-tin alloy (Pb – Sn) is shown in the figure below. (a) Calculate the amount of each phase present in the alloy at 300 °C. (b) Calculate the amount of each phase present in the alloy at 150 °C. (c) Calculate the amount of each phase present in the alloy at 100 °C. 327°C 600 300 Liquid 500 232°C a + L 200 183°C B +L 400 18.3 61.9 97.8 300 100 a + B 200 |100 40 60 80 100 (Pb) Composition (wt% Sn) (Sn) Temperature (°C) 20 Temperature ("F)arrow_forwardWhich of the following alloys would form a complete substitutional solid solution? O Metal 1 is HCP, metal 2 is FCC, and atomic radius difference is less than 15%. O Metal 1 is BCC, metal 2 is BCC, and atomic radius difference is at least 15%. O Metal 1 is FCC, metal 2 is FCC, and atomic radius difference is 12%. O Metal 1 is BCC, metal 2 is FCC, and atomic radius difference is 12%. O Metal 1 is FCC, metal 2 is FCC, and atomic radius difference is 15%.arrow_forward5 During decommissioning work, in order to determine the number of radionuclides deposited in a section of iron pipe, you grind up a small section of the pipe into a fine powder to carry out a reaction at 400 0C. Preliminary analysis shows that the predominant iron species are FeO and Fe2O3 Is it safe to use an aluminum crucible for heating your sample? What about a graphite crucible? Provide a short but detailed explanation referencing Ellingham diagrams, calculating Gibbs Free Energy, as well as provide any relevant reactions.arrow_forward
- Consider two types of thermal barrier coatings made of Zirconia. The first A is pure Zirconia and the second B has a small % of yttrium added to it. Upon cooling a coating of either type from high temperature to room temperature, what of the following is the most likely outcome? Select one: a. A: stays stable; B: stays stable b. A: stays stable; B: experiences high stress, phase transformation and undergoes cracking; c. A: experiences high stress, phase transformation and undergoes cracking; B: stays stable d. A: experiences high stress, phase transformation and undergoes cracking; B: undergoes cracking and distortionarrow_forwardCalculate the number of vacancies per m 3 for gold at 900 C. The energy for vacancyformation is 0.86 eV/atom.arrow_forward(b) Figure 1 shows a schematic diagram of the corrosion mechanism which involved steel structure. air Na 0, Na OH он shield FelOH), H' H Fe e passive film steel Figure 1: Corrosion mechanism (i) Identify the type of corrosion according to the schematic diagram shown in Figure 1. Justify your answer by explaining the corrosion mechanism. (ii) Suggest the methods to prevent the corrosion shown in Figure 1.arrow_forward
- I need the answer as soon as possiblearrow_forwardConsider two types of thermal barrier coatings made of Zirconia. The first A is pure Zirconia and the second B has a small % of yttrium added to it. Upon cooling a coating of either type from high temperature to room temperature, what of the following is the most likely outcome? Select one: b. A: stays stable; B: experiences high stress, phase transformation and undergoes cracking; A: stays stable; B: stays stable O c. A: experiences high stress, phase transformation and undergoes cracking; B: undergoes cracking and distortion d. A: experiences high stress, phase transformation and undergoes cracking; B: stays stablearrow_forwardDiscussion: 1- Define the corrosion and mention its types? 2- What is the effect of solution aeration on corrosion rate? 3- Compare corrosion rate for a metallic sample immersed in acidic solution with that immersed in a salt solution. 4- What is the effect of the exposure period on the corrosion rate? 5- Discuss the relationship between weight loss and time.arrow_forward
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