General, Organic, and Biological Chemistry - 4th edition
General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Chapter 11, Problem 25P
Interpretation Introduction

(a)

Interpretation:

The shape around the indicated atoms in the following compound should be determined and the lone pairs should be added to the heteroatoms:

  General, Organic, and Biological Chemistry - 4th edition, Chapter 11, Problem 25P , additional homework tip  1

Concept Introduction:

To add lone pair to an atom, first find the valence electron of the particular atom. After that find how many electrons are used in bond formation and then put the remaining valence electron on that particular atom.

The following table should be used while determining the shape around a carbon atom.

Number of groups Number of atomsNumber of lone pairsShapeBond angle
220Linear

  180°C

330Trigonal planar

  120°C

440Tetrahedral

  109.5°C

431Trigonal pyramidal

  109.5°C

422Bent

  109.5°C

Interpretation Introduction

(b)

Interpretation:

The shape around the indicated atoms in the following compound should be determined and the lone pairs should be added to the heteroatoms:

  General, Organic, and Biological Chemistry - 4th edition, Chapter 11, Problem 25P , additional homework tip  2

Concept Introduction:

To add lone pair to an atom, first find the valence electron of the particular atom. After that find how many electrons are used in bond formation and then put the remaining valence electron on that particular atom.

The following table should be used while determining the shape around a carbon atom.

Number of groups Number of atomsNumber of lone pairsShapeBond angle
220Linear

  180°C

330Trigonal planar

  120°C

440Tetrahedral

  109.5°C

431Trigonal pyramidal

  109.5°C

422Bent

  109.5°C

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Chapter 11 Solutions

General, Organic, and Biological Chemistry - 4th edition

Ch. 11.4 - Prob. 11.5PCh. 11.4 - How many H’s are bonded to each indicated carbon...Ch. 11.4 - Using the skeletal structure, determine the...Ch. 11.5 - Prob. 11.7PCh. 11.5 - Prob. 11.8PCh. 11.5 - For each compound. [1] Identify the functional...Ch. 11.5 - How do a carboxylic acid and an alcohol differ?...Ch. 11.5 - Label each of the following condensed structures...Ch. 11.5 - Prob. 11.11PCh. 11.5 - Prob. 11.12PCh. 11.5 - Identify all of the functional groups in atenolol,...Ch. 11.5 - Prob. 11.13PCh. 11.5 - Prob. 11.10PPCh. 11.5 - Prob. 11.14PCh. 11.6 - Indicate the polar bonds in each compound. Label...Ch. 11.6 - Prob. 11.11PPCh. 11.6 - Prob. 11.16PCh. 11.6 - Predict the water solubility of each compound.Ch. 11.6 - Prob. 11.17PCh. 11.7 - Prob. 11.18PCh. 11.7 - Prob. 11.19PCh. 11.7 - Prob. 11.20PCh. 11 - Prob. 21PCh. 11 - Prob. 22PCh. 11 - Complete each structure by filling in all H’s and...Ch. 11 - Complete the structure of mepivacaine by filling...Ch. 11 - Prob. 25PCh. 11 - Prob. 26PCh. 11 - Prob. 27PCh. 11 - Prob. 28PCh. 11 - “Ecstasy” is a widely used illegal stimulant....Ch. 11 - Prob. 30PCh. 11 - Explain why each C—C—C bond angle in benzene...Ch. 11 - Prob. 32PCh. 11 - Convert each compound to a condensed structure.Ch. 11 - Convert each compound to a condensed structure.Ch. 11 - Convert each compound to a skeletal structure.Ch. 11 - Convert each compound to a skeletal structure.Ch. 11 - Convert each shorthand structure to a complete...Ch. 11 - Convert each shorthand structure to a complete...Ch. 11 - Convert each skeletal structure to a complete...Ch. 11 - Convert each skeletal structure to a complete...Ch. 11 - A and B are ball-and-stick models of two compounds...Ch. 11 - Prob. 42PCh. 11 - What is wrong in each of the following shorthand...Ch. 11 - Prob. 44PCh. 11 - Prob. 45PCh. 11 - Albuterol (trade names Proventil and Ventolin) is...Ch. 11 - Prob. 47PCh. 11 - Prob. 48PCh. 11 - Prob. 49PCh. 11 - (a) Identify the functional groups in donepezil,...Ch. 11 - Prob. 51PCh. 11 - GHB is an addictive, illegal recreational drug...Ch. 11 - Prob. 53PCh. 11 - Prob. 54PCh. 11 - Prob. 55PCh. 11 - Prob. 56PCh. 11 - Prob. 57PCh. 11 - (a) Identify the functional groups in venlafaxine,...Ch. 11 - You are given two unlabeled bottles of solids, one...Ch. 11 - State how potassium iodide (KI) and pentane...Ch. 11 - The given beaker contains 100 mL of the organic...Ch. 11 - Prob. 62PCh. 11 - Why do we need to know the shape of a molecule...Ch. 11 - 1,1-Dichloroethylene (CH2=CCl2) is a starting...Ch. 11 - Indicate the polar bonds in each molecule. Label...Ch. 11 - Indicate the polar bonds in each molecule. Label...Ch. 11 - Classify each molecule as polar or nonpolar.Ch. 11 - Classify each molecule as polar or nonpolar. a....Ch. 11 - Which molecule is more water soluble? Explain.Ch. 11 - Explain why pantothenic acid, vitamin B5, is water...Ch. 11 - Prob. 71PCh. 11 - Prob. 72PCh. 11 - Explain why regularly taking a large excess of a...Ch. 11 - You can obtain the minimum daily requirement of...Ch. 11 - Prob. 75PCh. 11 - Vitamin B6 is obtained by eating a diet that...Ch. 11 - Prob. 77PCh. 11 - Can an oxygen-containing organic compound, have...Ch. 11 - Prob. 79PCh. 11 - Prob. 80PCh. 11 - Benzocaine is the active ingredient in topical...Ch. 11 - Methyl salicylate is responsible for the...Ch. 11 - Answer the following questions about aldosterone,...Ch. 11 - Answer the following questions about...Ch. 11 - Prob. 85PCh. 11 - Skin moisturizers come in two types, (a) One type...Ch. 11 - THC is the active component in marijuana (Section...Ch. 11 - Cocaine is a widely abused, addicting drug....
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