Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Chapter 8, Problem 53QP
Interpretation Introduction
Interpretation:
The incorrect bonds in the given skeletal structure of acetic acid are to be identified and the correct Lewis structure is to be drawn.
Concept introduction:
The electron dot structure is known as the Lewis structure. The bonding thatexists between lone pairs of electrons and atoms of a molecule is shown through a Lewis structure.
Acetic acid is a colorless liquid, which is also known as ethanoic acid. It has a pungent and strong smell. The chemical formula of acetic acid is
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A resident expert on electronegativity comes up to visit with you. He makes two claims (seen below) about electronegativity with relation to covalent bonding. Is the expert correct or can you refute him with your knowledge of electronegativity?
(a) If a diatomic molecule is made up of atoms X and Y, which have different electronegativities, the molecule must be polar.
(b) The farther two atoms are apart in a bond, the larger the dipole moment will be.
Consider the formate ion, HCO2", which is the anion
formed when formic acid loses an H* ion. The H and
the two O atoms are bonded to the central C atom.
(a) Draw the best Lewis structure(s) for this ion.
(b) Are resonance structures needed to describe the
structure? Explain briefly
(c) Would you predict that the C-O bond lengths in
the formate ion would be longer or shorter relative to
those in CO2? Explain briefly
(1) What is the total number of valence electrons in the Lewis structure of SF2?
electrons
(2) Draw a Lewis structure for SF2
Chapter 8 Solutions
Chemistry
Ch. 8.1 - Practice ProblemATTEMPT Write Lewis dot symbols...Ch. 8.1 - Practice Problem BUILD
Indicate the charge on...Ch. 8.1 - Practice ProblemCONCEPTUALIZE For each of the...Ch. 8.1 - 8.1.1 Using only a periodic table, determine the...Ch. 8.1 - 8.1.2 Using only a periodic table, determine the...Ch. 8.1 - To which group does element X belong if its Lewis...Ch. 8.1 - Prob. 4CPCh. 8.2 - Prob. 1PPACh. 8.2 - Practice ProblemBUILD Arrange the compounds NaF,...Ch. 8.2 - Practice ProblemCONCEPTUALIZE Common ions of four...
Ch. 8.2 - 8.2.1 Will the lattice energy of KF be larger or...Ch. 8.2 - 8.2.2 Using the following data, calculate the...Ch. 8.2 - 8.2.3 Lattice energies are graphed for three...Ch. 8.3 - Practice ProblemATTEMPT Using data from Figures...Ch. 8.3 - Prob. 1PPBCh. 8.3 - Prob. 1PPCCh. 8.4 - Practice Problem ATTEMPT Classify the following...Ch. 8.4 - Prob. 1PPBCh. 8.4 - Prob. 1PPCCh. 8.4 - In which of the following molecules are the bonds...Ch. 8.4 - Using data from Table 8.5, calculate the magnitude...Ch. 8.4 - Prob. 3CPCh. 8.4 - Prob. 4CPCh. 8.5 - Prob. 1PPACh. 8.5 - Prob. 1PPBCh. 8.5 - Prob. 1PPCCh. 8.5 - Identify the correct Lewis structure for formic...Ch. 8.5 - Identity the correct Lewis structure for hydrogen...Ch. 8.6 - Prob. 1PPACh. 8.6 - Prob. 1PPBCh. 8.6 - Prob. 1PPCCh. 8.6 - Determine the formal charges on H, C, and N,...Ch. 8.6 - 8.6.2 Which of the Lewis structures shown is most...Ch. 8.7 - Prob. 1PPACh. 8.7 - Practice ProblemBUILD Draw the Lewis structure for...Ch. 8.7 - Practice Problem CONCEPTUALIZE
Of the three Lewis...Ch. 8.7 - Indicate which of the following are resonance...Ch. 8.7 - 8.7.2 How many resonance structures can be drawn...Ch. 8.8 - Prob. 1PPACh. 8.8 - Prob. 1PPBCh. 8.8 - Practice Problem CONCEPTUALIZE
The hypothetical...Ch. 8.8 - In which of the following species does the central...Ch. 8.8 - Prob. 2CPCh. 8.8 - In which species does the central atom obey the...Ch. 8.8 - 8.8.4 How many lone pairs are there on the central...Ch. 8.9 - Prob. 1PPACh. 8.9 - Practice ProblemBUILD Use Lewis structures and...Ch. 8.9 - Prob. 1PPCCh. 8.9 - 8.9.1 Use data from Table 8.6 to estimate for the...Ch. 8.9 - Use data from Table 8.6 to estimate Δ H rxn for...Ch. 8.9 - Use bond enthalpies to determine Δ H rxn for the...Ch. 8.9 - Prob. 4CPCh. 8.10 - Practice ProblemATTEMPT Draw all possible...Ch. 8.10 - Prob. 1PPBCh. 8.10 - Practice ProblemCONCEPTUALIZE The Lewis structure...Ch. 8.11 - Prob. 1PPACh. 8.11 - Prob. 1PPBCh. 8.11 - Prob. 1PPCCh. 8.12 - Prob. 1PPACh. 8.12 - Prob. 1PPBCh. 8.12 - Prob. 1PPCCh. 8.13 - Prob. 1PPACh. 8.13 - Practice Problem BUILD
Using the following...Ch. 8.13 - Prob. 1PPCCh. 8 - 8.1
Which of the following atoms must always obey...Ch. 8 - Prob. 2KSPCh. 8 - Prob. 3KSPCh. 8 - Prob. 4KSPCh. 8 - What is a Lewis dot symbol? What elements do we...Ch. 8 - Use the second member of each group from Group 1A...Ch. 8 - Prob. 3QPCh. 8 - 8.4 Write Lewis dot symbols for the following...Ch. 8 - Write Lewis dot symbols for the following atoms...Ch. 8 - Prob. 6QPCh. 8 - Prob. 7QPCh. 8 - Name five metals and five nonmetals that are very...Ch. 8 - Prob. 9QPCh. 8 - Prob. 10QPCh. 8 - Prob. 11QPCh. 8 - The term molar mass was introduced in Chapter 3....Ch. 8 - Prob. 13QPCh. 8 - Prob. 14QPCh. 8 - Prob. 15QPCh. 8 - Explain how the lattice energy of an ionic...Ch. 8 - Prob. 17QPCh. 8 - Prob. 18QPCh. 8 - 8.19 Use the Born-Haber cycle outlined in Section...Ch. 8 - Calculate the lattice energy of CaCl 2 . Use data...Ch. 8 - An ionic bond is formed between a cation A + and...Ch. 8 - Prob. 22QPCh. 8 - Use Lewis dot symbols to show the transfer of...Ch. 8 - Write the Lewis dot symbols of the reactants and...Ch. 8 - 8.25 Describe Lewis’s contribution to our...Ch. 8 - Prob. 26QPCh. 8 - Prob. 27QPCh. 8 - Prob. 28QPCh. 8 - Prob. 29QPCh. 8 - Prob. 30QPCh. 8 - Prob. 31QPCh. 8 - Prob. 32QPCh. 8 - Prob. 33QPCh. 8 - Define electronegativity, and explain the...Ch. 8 - Prob. 35QPCh. 8 - Prob. 36QPCh. 8 - Prob. 37QPCh. 8 - Using information in Table 8.5. calculate the...Ch. 8 - List the following bonds in order of increasing...Ch. 8 - Classify the following bonds as covalent, polar...Ch. 8 - 8.41 Classify the following bonds as covalent,...Ch. 8 - 8.42 List the following bonds in order of...Ch. 8 - Prob. 43QPCh. 8 - Prob. 44QPCh. 8 - Prob. 45QPCh. 8 - Prob. 46QPCh. 8 - Draw Lewis structures for the following molecules...Ch. 8 - Draw Lewis structures for the following molecules:...Ch. 8 - Prob. 49QPCh. 8 - Prob. 50QPCh. 8 - 8.51 Draw Lewis structures for the following ions:...Ch. 8 - Draw Lewis structures for the following ions: (a)...Ch. 8 - Prob. 53QPCh. 8 - Prob. 54QPCh. 8 - Prob. 55QPCh. 8 - Prob. 56QPCh. 8 - Prob. 57QPCh. 8 - 8.58 Draw three resonance structures for the...Ch. 8 - Prob. 59QPCh. 8 - Prob. 60QPCh. 8 - Draw three reasonable resonance structures for the...Ch. 8 - Draw three resonance structures for the molecule N...Ch. 8 - Prob. 63QPCh. 8 - Prob. 64QPCh. 8 - Prob. 65QPCh. 8 - Prob. 66QPCh. 8 - Prob. 67QPCh. 8 - Prob. 68QPCh. 8 - Prob. 69QPCh. 8 - The AlI 3 molecule has an incomplete octet around...Ch. 8 - Prob. 71QPCh. 8 - Prob. 72QPCh. 8 - 8.73 Write a Lewis structure for Does this...Ch. 8 - Prob. 74QPCh. 8 - Prob. 75QPCh. 8 - 8.76 Draw two resonance structures for the bromate...Ch. 8 - Prob. 77QPCh. 8 - What is bond enthalpy? Bond enthalpies of...Ch. 8 - Prob. 79QPCh. 8 - Prob. 80QPCh. 8 - Prob. 81QPCh. 8 - Prob. 82QPCh. 8 - For the reaction 2 C 2 H 6 ( g ) + 7 O 2 ( g ) → 4...Ch. 8 - Prob. 84QPCh. 8 - 8.85. Use average bond enthalpies from Table 8.6...Ch. 8 - Prob. 86APCh. 8 - Prob. 87APCh. 8 - Prob. 88APCh. 8 - Prob. 89APCh. 8 - Prob. 90APCh. 8 - 8.91 Describe some characteristics of an ionic...Ch. 8 - Prob. 92APCh. 8 - Prob. 93APCh. 8 - Prob. 94APCh. 8 - Prob. 95APCh. 8 - Prob. 96APCh. 8 - Prob. 97APCh. 8 - Prob. 98APCh. 8 - Prob. 99APCh. 8 - Prob. 100APCh. 8 - Prob. 101APCh. 8 - Prob. 102APCh. 8 - Prob. 103APCh. 8 - Prob. 104APCh. 8 - Which of the following species are isoelectronic:...Ch. 8 - Prob. 106APCh. 8 - 8.107 Draw two resonance structures for each...Ch. 8 - The following species have been detected in...Ch. 8 - The amide ion ( NH 2 − ) is a Brø�nsted base. Use...Ch. 8 - Prob. 110QPCh. 8 - The triiodide ion ( I 3 − ) in which the I atoms...Ch. 8 - Prob. 112APCh. 8 - In 1999, an unusual cation containing only...Ch. 8 - Prob. 114APCh. 8 - Prob. 115APCh. 8 - Prob. 116APCh. 8 - In the gas phase, aluminum chloride exists as a...Ch. 8 - Prob. 118APCh. 8 - Calculate Δ H º for the reaction H 2 ( g ) + I 2 (...Ch. 8 - Draw Lewis structures for the following organic...Ch. 8 - Prob. 121APCh. 8 - Prob. 122APCh. 8 - Prob. 123APCh. 8 - Write three resonance structures for (a) the...Ch. 8 - Prob. 125APCh. 8 - Prob. 126APCh. 8 - Prob. 127APCh. 8 - Prob. 128APCh. 8 - Prob. 129APCh. 8 - Prob. 130APCh. 8 - Prob. 131APCh. 8 - Among the common inhaled anesthetics are:...Ch. 8 - Prob. 133QPCh. 8 - Prob. 134QPCh. 8 - Prob. 135QPCh. 8 - 8.136 Using this and data from Appendix 2,...Ch. 8 - Prob. 137QPCh. 8 - Prob. 138APCh. 8 - Prob. 139APCh. 8 - Prob. 140APCh. 8 - Prob. 141APCh. 8 - Prob. 142APCh. 8 - Prob. 143APCh. 8 - Although nitrogen dioxide ( NO 2 ) is a stable...Ch. 8 - 8.145 The chlorine nitrate molecule is believed...Ch. 8 - The hydroxyl radical ( OH ) plays an important...Ch. 8 - Prob. 147APCh. 8 - Prob. 148APCh. 8 - Prob. 1SEPPCh. 8 - 2. Use formal charges to choose the best of the...Ch. 8 - Prob. 3SEPPCh. 8 - Prob. 4SEPP
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