CHEMISTRY-TEXT
8th Edition
ISBN: 9780134856230
Author: Robinson
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Textbook Question
Chapter 6, Problem 6.101MP
Heating elemental cesium and platinum together for two day sat 973 K gives a dark red ionic compound that is 57.67% Csand 42.33% Pt.
(a) What is the empirical formula of the compound?
(b) What are the charge and electron configuration of the cesiumion?
(c) What are the charge and electron configuration of the platinum ion?
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Q1.
This question is about atomic structure.
(a) Write the full electron configuration for each of the following species.
CH
Fe2+
(b) Write an equation, including state symbols, to represent the process that occurs
when the third ionisation energy of manganese is measured.
(c)
State which of the elements magnesium and aluminium has the lower first ionisation
energy
Explain your answer.
(d) A sample of nickel was analysed in a time of flight (TOF) mass spectrometer. The
sample was ionised by electron impact ionisation. The spectrum produced showed
three peaks with abundances as set out in the table.
m/z
Abundance /%
58
61.0
60
29.1
61
9.9
Give the symbol, including mass number, of the ion that would reach the detector
first in the sample.
Calculate the relative atomic mass of the nickel in the sample.
Give your answer to one decimal place.
Page 2 of 12
Symbol of ion
Relative atomic mass
5. The atoms and ions Ne, N³-, F, Mg2+, and Si4+ are part of an
isoelectronic series.
(a) Which of these will have the smallest effective nuclear
charge acting on the outermost electron?
(b) Which one possess the greatest effective nuclear charge?
(c) Which ion will be the largest in size? Explain why.
The orbital diagram that follows shows the valence electronsfor a 2+ ion of an element. (a) What is the element?(b) What is the electron configuration of an atom of this element?
Chapter 6 Solutions
CHEMISTRY-TEXT
Ch. 6 - Prob. 6.1PCh. 6 - APPLY 6.2 Which of the following sets of ions are...Ch. 6 - Which atom or ion has the largest radius:...Ch. 6 - Conceptual APPLY 6.4 Which of the following...Ch. 6 - Use the periodic table to order the elements from...Ch. 6 - Given the orbital filling diagrams for the valence...Ch. 6 - Which has the largest third ionization energy: Be,...Ch. 6 - Conceptual APPLY 6.8 The figure on the right...Ch. 6 - Order the following elements from least to most...Ch. 6 - Conceptual APPLY 6.10 Which of the indicated three...
Ch. 6 - What electron configuration does the strontium...Ch. 6 - Prob. 6.12ACh. 6 - Prob. 6.13PCh. 6 - APPLY 6.14 Calculate the energy of electrostatic...Ch. 6 - Which substance has the largest lattice energy:...Ch. 6 - One of the following pictures represents NaCl and...Ch. 6 - Prob. 6.17PCh. 6 - What structural features do ionic liquids havethat...Ch. 6 - PROBLEM 6.18 Compare the following two ionic...Ch. 6 - PROBLEM 6.19 An ionic liquid consisting of a bulky...Ch. 6 - Where on the periodic table would you find the...Ch. 6 - Which of the following spheres is likely to...Ch. 6 - Circle the approximate part or parts of the...Ch. 6 - Prob. 6.24CPCh. 6 - This figure represents the successive ionization...Ch. 6 - In the following drawings, red spheres represent...Ch. 6 - Which of the following drawings is more likely to...Ch. 6 - Prob. 6.28CPCh. 6 - Which of the following alkali metal halides has...Ch. 6 - Which of the following alkali metal halides has...Ch. 6 - Three binary compounds are represented on the...Ch. 6 - Prob. 6.32CPCh. 6 - Prob. 6.33CPCh. 6 - What is the difference between a covalent bond and...Ch. 6 - Prob. 6.35SPCh. 6 - What is the difference between a molecule and an...Ch. 6 - Prob. 6.37SPCh. 6 - How many protons and electrons are in each of the...Ch. 6 - What is the identity of the element X in the...Ch. 6 - Prob. 6.40SPCh. 6 - Prob. 6.41SPCh. 6 - Prob. 6.42SPCh. 6 - Prob. 6.43SPCh. 6 - What doubly positive ion has the following...Ch. 6 - Prob. 6.45SPCh. 6 - Prob. 6.46SPCh. 6 - Which element in the transition-metal series Sc...Ch. 6 - Prob. 6.48SPCh. 6 - Prob. 6.49SPCh. 6 - Order the following ions from smallest to largest:...Ch. 6 - Order the following ions from smallest to largest:...Ch. 6 - Which ion has a larger atomic radius, Cu+ or Cu2+...Ch. 6 - Which ion hasa larger atomic radius, Fe2+ or Fe3+...Ch. 6 - The following ions all have the same number of...Ch. 6 - Which of the ions Se2,F,O2 and Rb+ has the largest...Ch. 6 - Which group of elements in the periodic table has...Ch. 6 - Prob. 6.57SPCh. 6 - Which element in each of the following sets has...Ch. 6 - Order the elements in each set from the smallest...Ch. 6 - (a) Which has the smaller second ionization...Ch. 6 - (a) Which has the smaller fourth ionization...Ch. 6 - Three atoms have the following electron...Ch. 6 - Three atoms have the following electron...Ch. 6 - The first four ionization energies in kJ/mol of a...Ch. 6 - The first four ionization energies in kJ/mol of a...Ch. 6 - Prob. 6.66SPCh. 6 - Prob. 6.67SPCh. 6 - Prob. 6.68SPCh. 6 - Prob. 6.69SPCh. 6 - Why is energy usually released when an electron is...Ch. 6 - Why does ionization energy increase regularly...Ch. 6 - No element has a negative second electron...Ch. 6 - Why does phosphorus have a less negative electron...Ch. 6 - Prob. 6.74SPCh. 6 - What noble-gas configurations and charge are the...Ch. 6 - Each of the following pairs of elements will react...Ch. 6 - Each of the following pairs of elements will react...Ch. 6 - Element X reacts with element Y to give a product...Ch. 6 - Element X reacts with element Y to give a product...Ch. 6 - Calculate the energy change in kilojoules per mole...Ch. 6 - Prob. 6.81SPCh. 6 - Find the lattice energy of LiBr(s) in Table 6.3,...Ch. 6 - Look up the lattice energies in Table 6.3, and...Ch. 6 - Born-4-Iaber cycles, such as those shown in...Ch. 6 - Calculate a lattice energy for CaH2(s) in...Ch. 6 - Calculate the overall energy change in kilojoules...Ch. 6 - The estimated lattice energy for CsF2(s) is +2347...Ch. 6 - Calculate the overall energy change in kilojoules...Ch. 6 - Use the data in Problem 6.88 to calculate an...Ch. 6 - Use the data and the result in Problem 6.84 to...Ch. 6 - Prob. 6.91SPCh. 6 - Calculate overall energy changes in kilojoules per...Ch. 6 - Prob. 6.93SPCh. 6 - We saw in Section 6.7 that the reaction of solid...Ch. 6 - Draw a Born—Haber cycle for the reaction of sodium...Ch. 6 - Use the following information plus the data given...Ch. 6 - Prob. 6.97SPCh. 6 - Prob. 6.98SPCh. 6 - Order the following compounds according to their...Ch. 6 - Prob. 6.100MPCh. 6 - Heating elemental cesium and platinum together for...Ch. 6 - Given the following information, construct a...Ch. 6 - Consider the electronic structure of the element...Ch. 6 - Prob. 6.104MPCh. 6 - The ionization energy of an atom can be measured...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Which of the four atoms Na, P, Cl, or K (a) has the largest atomic radius? (b) has the highest ionization energy? (c) is the most electronegative?arrow_forwardBoron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively.(a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B? (b) Drawthe orbital diagram for an atom of 11B. Which electrons are the valence electrons? (c) Indicate three ways in which the 1s electrons inboron differ from its 2s electrons. (d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation forthe reaction of solid boron with fluorine gas. (e) ΔHf° for BF31g2 is -1135.6 kJ>mol. Calculate the standard enthalpy change in thereaction of boron with fluorine. (f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?arrow_forwardUsing complete subshell notation (1s^22s^22p^6, and so forth), predict the electron configurations of the following ions. (a) N3– (b) Ca2+ (c) S– (d) Cs2+ (e) Cr2+ (f) Gd3+arrow_forward
- Identify the true statements concerning the atoms andions of the group 6A elements. (a) The ionic radii are larger than the atomic radii becausethe ions have more electrons than their correspondingatoms.(b) Atomic radii increase going down the group because ofincreasing nuclear charge.(c) The ionic radii increase going down the group becauseof the increase in the principal quantum number ofoutermost electrons.(d) Of these ions, Se2- is the strongest base in water becauseit is largest.arrow_forwardUse electron confi gurations to explain(a) why arsenic can acquire charges of 23 and 13but not 12(b) the 12 charge on the lead(II) ion(c) the 11 charge of the silver ionarrow_forwardConsider these ground-state ionization energies of one-electron species:H=1.31X10³kJ/mol ,He⁺=5.24X10³kJ/mol Li²⁺=1.41X10⁴kJ/mol (a) Write a general expression for the ionization energy of anyone-electron species. (b) Use your expression to calculate theionization energy of B⁴⁺. (c) What is the minimum wavelengthrequired to remove the electron from the n=3 level of He⁺?(d) What is the minimum wavelength required to remove the electron from the n=2 level of Be³⁺?arrow_forward
- la) For each of the following pairs indicate which element you would expect to have the larger First Ionization Energy and which one would have the larger radius: (a) Ca and Cl; (b) Sn and Tl; (c) Ba and Bi (d) Fr and Cs b) For each pair indicate which Ion you would expect to have the largest Radius: (a) 0²- and O; (b) N³ and Mg²+ (c) Al3* and Al ne Elearrow_forwardWrite the ground-state electron configurations of the following ions. (a) Li+ (b) N3− (c) In3+ (Use the noble gas core electron configuration in your answer.) (d) Tl+ (Use the noble gas core electron configuration in your answer.)arrow_forward2.(a) Write the full electron configuration for each of Ge and Ge3-2.(b) Write the noble gas configuration, and valence configuration of Ge 2.(c) Write the orbital diagram for the Ge3-2.(d) For the unpaired electron in the orbital diagram for the Ge3-ion, give its four quantum numbersn,l,ml,ms 2.(e) Is Ge3+ diamagnetic or paramagnetic?arrow_forward
- choose three . What are the characteristerses of a metal like element? (a) they try to get additional electrons (b) they are melleable. (c) they are lightly to give away or share electrons. (d) they are good conductors of electricityarrow_forward7. Which element has the smallest first ionization energy? (a) Cs (b) Ga (c) K (d) Bi (e) As 8. Which element has the smallest second ionization energy? (a) Mg (b) Li (c) S (d) O (e) Ca 9. Which of the following sets contain all linear molecules? (a) H2S, HCN, CO2. (b) HCN, O2, CO2 (c) H2O, CO, Cl2. (d) H2S, CO, CO2. (e) BF3, Cl2, O2 10. The molecular geometry of SnCl3-ion is: (a) trigonal planar (b) T-shaped. (c) trigonal pyramidal. (d) Tetrahedral (e) see-saw 11. The geometry of the molecule SPC13 is best described as: (a) square planar (b) trigonal pyramidal (c) trigonal bipyramidal. (d) octahedral (e) tetrahedral 12. The O-S-Cl bond angles in O2SCl2 are expected to be approximately: (a) 90° (b) 109.5° (c) 120° (d)180 ° (e) 90° and 120°arrow_forwardBoron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively. (a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B? (b) Draw the orbital diagram for an atom of 11B. Which electrons are the valence electrons? (c) Indicate three ways in which the 1s electrons in boron differ from its 2s electrons. (d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation for the reaction of solid boron with fluorine gas. (e) ΔHf° for BF3(g) is -1135.6 kj/mol. Calculate the standard enthalpy change in the reaction of boron with fluorine. (f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningIntroductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
- Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Periodic Properties of Elements | Chemistry | IIT-JEE | NEET | CBSE | Misostudy; Author: Misostudy;https://www.youtube.com/watch?v=L26rRWz4_AI;License: Standard YouTube License, CC-BY
Periodic Trends: Electronegativity, Ionization Energy, Atomic Radius - TUTOR HOTLINE; Author: Melissa Maribel;https://www.youtube.com/watch?v=0h8q1GIQ-H4;License: Standard YouTube License, CC-BY