Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Textbook Question
Chapter 4.4, Problem 9P
Give the structure corresponding to each IUPAC name.
a.
b.
c.
d.
e.
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Give the structure corresponding to each IUPAC name. a. 3-methylhexane c. 3,5,5-trimethyloctane b. 3,3-dimethylpentane d. 3-ethyl-4-methylhexane
Give the structure corresponding to each IUPAC name.
a. 3-methylhexane
b. 3,3-dimethylpentane
c. 3,5,5-trimethyloctane
d. 3-ethyl-4-methylhexane
e. 3-ethyl-5-isobutylnonane
What is the IUPAC name of the
following compound?
O A. 3,4,4-Triethyl-2,2,5-trimethylhexane
B. 3-Ethyl-3-isopropyl-4-tertbutylhexane
O c. 3,3,4-Triethyl-2,5,5-trimethylhexane
D. 3,4-Diethyl-4-isopropyl-2,2-
dimethylhexane.
Chapter 4 Solutions
Organic Chemistry (6th Edition)
Ch. 4.1 - Prob. 1PCh. 4.1 - Problem 4.2 Which of the following is not another...Ch. 4.1 - Problem 4.3 Draw the five constitutional isomers...Ch. 4.1 - Prob. 4PCh. 4.1 - Prob. 5PCh. 4.2 - Draw the five constitutional isomers that have...Ch. 4.4 - Problem 4.7 Give the IUPAC name for each...Ch. 4.4 - Give the IUPAC name for each compound. a....Ch. 4.4 - Problem 4.9 Give the structure corresponding to...Ch. 4.4 - Prob. 10P
Ch. 4.5 - Give the IUPAC name for each compound.Ch. 4.5 - Give the structure corresponding to each IUPAC...Ch. 4.8 - Arrange the following compounds in order of...Ch. 4.9 - Problem 4.14 Draw the staggered and eclipsed...Ch. 4.9 - Prob. 15PCh. 4.9 - Prob. 16PCh. 4.10 - Problem 4.17 a. Draw the three staggered and...Ch. 4.10 - Problem 4.18 Rank the following conformations in...Ch. 4.10 - Problem 4.19 Consider rotation around the...Ch. 4.10 - Calculate the destabilization present in each...Ch. 4.12 - Problem 4.21 Classify the ring carbons as up or...Ch. 4.12 - Problem 4.22 Using the cyclohexane with the C’s...Ch. 4.13 - Draw a second chair conformation for each...Ch. 4.13 - Problem 4.24 Draw both conformations for and...Ch. 4.13 - Problem 4.25 Draw the structure for each compound...Ch. 4.13 - Prob. 26PCh. 4.14 - Prob. 31PCh. 4.14 - Prob. 32PCh. 4.15 - Prob. 33PCh. 4 - Name each alkane using the ball-and-stick model,...Ch. 4 -
4.40 Draw the structure corresponding to each...Ch. 4 - 4.42 Give the IUPAC name for each compound.
a....Ch. 4 - Prob. 42PCh. 4 - 4.46 Considering rotation around the bond...Ch. 4 - 4.50 Calculate the barrier to rotation for each...Ch. 4 - 4.51 The eclipsed conformation of is less...Ch. 4 - (a) Draw the anti and gauche conformations for...Ch. 4 - For each compound drawn below: a.Label each OH,Br...Ch. 4 - Draw the two possible chair conformations for...Ch. 4 - For each compound drawn below: a. Draw...Ch. 4 - Classify each pair of compounds as constitutional...Ch. 4 - Prob. 66PCh. 4 - 4.64 Draw the products of combustion of each...Ch. 4 - 4.65 Hydrocarbons like benzene are metabolized in...Ch. 4 - Prob. 69PCh. 4 - Prob. 70PCh. 4 - Cyclopropane and cyclobutane have similar strain...Ch. 4 - Prob. 72PCh. 4 - Haloethanes (CH3CH2X,X=Cl,Br,I) have similar...Ch. 4 - Prob. 74PCh. 4 - Prob. 75PCh. 4 - Consider the tricyclic structure B (a) Label each...Ch. 4 - Read Appendix B on naming branched alkyl...Ch. 4 - Read Appendix B on naming bicyclic compounds. Then...
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- 2. Draw structures corresponding to the following IUPAC names. a. 2-Methyl-1,5-hexadiene b. 3-Ethyl-2,2-dimethyl-3-heptene c. 2,3,3-Trimethyl-1,4,6-octatriene d. 3,4-Diisopropyl-2,5-dimethyl-3-hexene e. 3-methyl-1-pentyne f. (Z)-3-methylhex-2-en-4-ynearrow_forwardThe correct IUPAC name for the following compound is CH2 H2 H3C. CH3 H2 H3C CH3 a. 2,3,3-trimethyl-1-hexene b. 2,3,3-trimethylhexane c. 4,4,5-trimethylhexane d. 3,4,4-trimethyl-2-hexenearrow_forwardWhat is the IUPAC name of this compound ? A. 3-ethyl-2,7,8-trimethylnonane B. 2,6-diisopropyloctane C. 6-ethyl-2-isopropyl-7-methyloctane D. 7-ethyl-2,3,8-trimethylnonane E. 7-isopropyl-2,3-dimethylnonanearrow_forward
- Match the following IUPAC Name to its appropriate stucture. A. 1,1,2,2,N,N-hexamethylpentane B. 5,6,6-trimethyl-1-heptyne C. 3,3,4,4,5,5-hexamethylpentane D. 2,2,3,3,4,4-hexamethylpentane E. 2,2,3-trimethyl-6-heptyne F. 3-methylbuta-1,2-diene G. 3-methylhexa-1,2-diene H. 3-methylpenta-1,2-dienearrow_forwardEach of the following IUPAC names is incorrect. Explain why it is incorrect and give the correct IUPAC name. a. 4-methylpentane b. 2,3,3-trimethylbutane c. 1,3-dimethylpentane d. 3-methyl-5-ethylhexane e. 2-ethyl-2-methylcycloheptane f. 1,6-diethylcyclohexanearrow_forwardEach of the following IUPAC names is incorrect. Explain why it is incorrect and give the correct IUPAC name. a. 2,2-dimethyl-4-ethylheptane b. 5-ethyl-2-methylhexane c. 2-methyl-2-isopropylheptane d. 1,5-dimethylcyclohexane e. 1-ethyl-2,6-dimethylcycloheptane f. 5,5,6-trimethyloctane g. 3-butyl-2,2-dimethylhexane h. 1,3-dimethylbutanearrow_forward
- Draw the structure of each alkane and cycloalkane from the given incorrect name. Then, give the IUPAC name for each compound. a. 7-ethyl-3,6-dimethylnonane b. 4-ethyl-3-isopropylheptane c.3-ethyl-1,4-dimethylcycloheptane d. 1-ethyl-3-methyl-5-isopropylcyclohexanearrow_forwardExplain why each of the following is an incorrect IUPAC name. Write the correct IUPAC name for the compound. a. 1,3-Dimethylbutane b. 4-Methylpentane c. 2,2-Diethylbutane d. 2-Ethyl-3-methylpentane e. 2-Propylpentane f. 2,2-Diethylheptane g. 2,2-Dimethylcyclopropane h. l-Ethyl-5-methylcyclohexanearrow_forwardWhat is the correct IUPAC name for 6-isobutyl-3-heptyne? a. 1,5-dimethyl-7-decyne b. 2-isobutyl-4-heptyne c. 6,8-dimethyl-3-nonyne d. 6,9-dimethyl-3-decynearrow_forward
- It has been suggested that the following compound was incorrectly named trans-3,5-dimethyl-4- propylnon-3-ene. What is the correct IUPAC name for the compound? A. cis-3,5-dimethyl-4-propylnon-3-ene trans-4(2-hexane)3methylhept-3-ene B. C. trans-4-propyl 3,5-dimethylnon-3-ene D. cis-4(2-hexane)3methylhept-3-ene E. trans-3,5-dimethyl-4-propylnon-3-enearrow_forwardWhat is the IUPAC name for the following compound? O A. 2-isopropyl-3-pentyne O B. 4-isopropyl-2-pentyne OC 4,5-dimethyl-2-hexyne O D.2,3-dimethyl-4-hexynearrow_forwardIdentify the two compounds that display stereoisomerism and draw their structures. a. 3-methyl-3-pentanol b. 2-methyl-2-pentanol c. 3-methyl-2-pentanol d. 2-methyl-3-pentanol e. 2,4-dimethyl-3-pentanolarrow_forward
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