Organic Chemistry (6th Edition)
Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 4, Problem 68P

Hydrocarbons like benzene are metabolized in the body to arene oxides, which rearrange to form

phenols. This is an example of a general process in the body, in which an unwanted compound

(benzene) is converted to a more water-soluble derivative called a metabolite, so that it can be

excreted more readily from the body.

Chapter 4, Problem 68P, 4.65 	Hydrocarbons like benzene are metabolized in the body to arene oxides, which rearrange to form

a. Classify each of these reactions as oxidation, reduction, or neither.

b. Explain why phenol is more water soluble than benzene. This means that phenol dissolves in urine, which is largely water, to a greater extent than benzene.

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Hydrocarbons like benzene are metabolized in the body to arene oxides, which rearrange to form phenols. This is an example of a general process in the body, in which an unwanted compound (benzene) is converted to a more watersoluble derivative called a metabolite, so that it can be excreted more readily from the body.a. Classify each of these reactions as oxidation, reduction, or neither.b. Explain why phenol is more water soluble than benzene. This means that phenol dissolves in urine, which is largelywater, to a greater extent than benzene.
Butane is typically used as fuel for cigarette lighters and portable stoves.A. Balanced chemical equation for the complete combustion of butane:
lonic compounds and organic compounds usually undergo spontaneous chemical reactions, depending on the nature of the reaction. Among organic compounds, what energy barrier prevents chemical reactivity to manifest? a. Chemical energy b. Activation energy c. Endothermic reaction d. Exothermic reaction Among covalent bonds in organic compounds, which type of bond requires the greatest energy to be disrupted? a. Ionic bond b. Single bond c. Double bond d. Triple bond Based on chemical reactivity, organic molecules which have free pi bonds are classified as a. Positive b. Negative c. Electrophiles  d. Nucleophiles

Chapter 4 Solutions

Organic Chemistry (6th Edition)

Ch. 4.5 - Give the IUPAC name for each compound.Ch. 4.5 - Give the structure corresponding to each IUPAC...Ch. 4.8 - Arrange the following compounds in order of...Ch. 4.9 - Problem 4.14 Draw the staggered and eclipsed...Ch. 4.9 - Prob. 15PCh. 4.9 - Prob. 16PCh. 4.10 - Problem 4.17 a. Draw the three staggered and...Ch. 4.10 - Problem 4.18 Rank the following conformations in...Ch. 4.10 - Problem 4.19 Consider rotation around the...Ch. 4.10 - Calculate the destabilization present in each...Ch. 4.12 - Problem 4.21 Classify the ring carbons as up or...Ch. 4.12 - Problem 4.22 Using the cyclohexane with the C’s...Ch. 4.13 - Draw a second chair conformation for each...Ch. 4.13 - Problem 4.24 Draw both conformations for and...Ch. 4.13 - Problem 4.25 Draw the structure for each compound...Ch. 4.13 - Prob. 26PCh. 4.14 - Prob. 31PCh. 4.14 - Prob. 32PCh. 4.15 - Prob. 33PCh. 4 - Name each alkane using the ball-and-stick model,...Ch. 4 - 4.40 Draw the structure corresponding to each...Ch. 4 - 4.42 Give the IUPAC name for each compound. a....Ch. 4 - Prob. 42PCh. 4 - 4.46 Considering rotation around the bond...Ch. 4 - 4.50 Calculate the barrier to rotation for each...Ch. 4 - 4.51 The eclipsed conformation of is less...Ch. 4 - (a) Draw the anti and gauche conformations for...Ch. 4 - For each compound drawn below: a.Label each OH,Br...Ch. 4 - Draw the two possible chair conformations for...Ch. 4 - For each compound drawn below: a. Draw...Ch. 4 - Classify each pair of compounds as constitutional...Ch. 4 - Prob. 66PCh. 4 - 4.64 Draw the products of combustion of each...Ch. 4 - 4.65 Hydrocarbons like benzene are metabolized in...Ch. 4 - Prob. 69PCh. 4 - Prob. 70PCh. 4 - Cyclopropane and cyclobutane have similar strain...Ch. 4 - Prob. 72PCh. 4 - Haloethanes (CH3CH2X,X=Cl,Br,I) have similar...Ch. 4 - Prob. 74PCh. 4 - Prob. 75PCh. 4 - Consider the tricyclic structure B (a) Label each...Ch. 4 - Read Appendix B on naming branched alkyl...Ch. 4 - Read Appendix B on naming bicyclic compounds. Then...
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