EBK PHYSICS FOR SCIENTISTS & ENGINEERS
EBK PHYSICS FOR SCIENTISTS & ENGINEERS
5th Edition
ISBN: 9780134296074
Author: GIANCOLI
Publisher: VST
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Chapter 40, Problem 3Q

Does the H2 molecule have a permanent dipole moment? Does O2? Does H2O? Explain.

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3. Show that in an ideal hexagonal-close-packed (hcp) structure, where the atomic spheres touch each other, the ratio c/a is given by :-()* ( 8 \ 1/2 = 1.633. (The hep structure is discussed in Section 7.) 4 The packing ratio is defined as the fraction of the total volume of the cell that is filled by atoms. Determine the maximum values of this ratio for equal spheres located at the points of simple-cubic, body-centered-cubic, and face-centered-cubic crystals.
(4) Predict the structure of CsCl. Given: radius of Cs+= 0.160 nm, radius of Cl-=0.181nm. Calculate the radius ratio between Cs+ and Cl- and derive the coordination number (CN) based on the table below. Rcation/Ranion CN 0-0.155 2 3 0.155-0.225 0.225-0.414 0.414-0.732 0.732-1 1 4 6 8 12
(e) Using the characteristic function, show that a(N) (N²). = k„T (f) Show that fluctuations in the number of adsorbed particles satisfy (N*), (N)? 1-f Nf
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