Inorganic Chemistry
5th Edition
ISBN: 9781292134147
Author: Housecroft, Catherine E.
Publisher: Pearson,
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Chapter 3, Problem 5P
The structure of
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Chapter 3 Solutions
Inorganic Chemistry
Ch. 3 - 3.1 Give the structures of the following...Ch. 3 - 3.2 In the group theory, what is meant by the...Ch. 3 - For each of the following 2-dimensional shapes,...Ch. 3 - Draw the structure of SO2 and identify its...Ch. 3 - 3.5 The structure of was shown in Fig. 2.1. Apart...Ch. 3 - By drawing appropriate diagrams, illustrate the...Ch. 3 - Using the answer to problem 3.6 to help you,...Ch. 3 - 3.8 Which of the following species or ions contain...Ch. 3 - Which of the following species contain C4 axis and...Ch. 3 - 3.10 How many mirror planes each do each of the...
Ch. 3 - (a) What structure would you expect Si2H6 to...Ch. 3 - Prob. 12PCh. 3 - Explain what is meant by an -fold axis of...Ch. 3 - 3.14 To which point group to does belong?
Ch. 3 - 3.15 The point group of is . What shape is this...Ch. 3 - 3.16 Determine the point group of .
Ch. 3 - 3.17 The point group of is . Draw the structure...Ch. 3 - 3.18 In worked example 2.7, the structure of the ...Ch. 3 - 3.19 Assign a point group to each member in the...Ch. 3 - (a) Deduce the point group of SF4. (b) Is SOF4 in...Ch. 3 - 3.21 Which of the point groups possess the highest...Ch. 3 - Prob. 22PCh. 3 - Prob. 23PCh. 3 - Prob. 24PCh. 3 - 3.25 By considering the effect of each symmetry...Ch. 3 - To what point group does CBr4 belong? Using the...Ch. 3 - Prob. 27PCh. 3 - Al2Cl6 belongs to the D2h point group: How many...Ch. 3 - Prob. 29PCh. 3 - Determine how many CO stretching modes are...Ch. 3 - 3.31 In 1993, the ion was reported for the first...Ch. 3 - Prob. 32PCh. 3 - (a) To which point group does a trigonal...Ch. 3 - Prob. 34PCh. 3 - Confirm the symmetry operations of (a) inversion...Ch. 3 - Prob. 42PCh. 3 - Prob. 43P
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- The Cu(H2O)62+ complex has octahedral symmetry. Is a transition from a T2g state to an Eg state allowed if the transition moment operator has a T1u symmetry label?arrow_forwardIdentify the symmetry elements present in the following objects. a The Eiffel Tower. You may have to look up a picture of it if you dont remember its shape b Any book ignore the printing. c An octagonal wood block. d A jack from the set of jacks pictured here: Note that some of the points end differently.arrow_forwardIn your own words, explain why an object that has more symmetry elements is said to have higher symmetry than an object with fewer symmetry elements.arrow_forward
- Determine which single symmetry operation of the following point groups is equivalent to the given combination of multiple symmetry operations. a In C2v, C2v=? b In C2h, iC2=? c In D6h, C6h=? d In D2d, C2C2=? e In Oh, iS4=?arrow_forwarda In the Td point group, an S41 improper rotation is equivalent to what other improper rotation? b In the D6h point group, the symmetry operation labeled C21 is equivalent to what other symmetry operation?arrow_forwardAssume that x- polarized light can be assigned an E symmetry species in a system that has C4v symmetry. Can a transition from E state to a B2 state occur? Why or why not?arrow_forward
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- Apply the symmetry operations of the point group to the B-Cl bond vector v1 to generate R(v1) for each symmetry operation of the group. Use the order and definition of the symmetry operations of the point group given in the table and the mutally perpendicular views of the B₂Cl4 molecule indicating the B-Cl bond vectors shown below to determine your answer. O v1 v4 v3 v2 v4 v3 v1 v2 O v1 v4 v3 v2 v3 v1 v4 v2 O v1 v3 v4 v2 v3 v4 v1 v2 O v1 v3 v2 v4 v3 v2 v1 v4 E clockwi santicloc kwise X SA se v4 CB- J=<+436 vl S4, C₂ y CH v3 B-B C₂ v2 C2 (1) C2 (2) od(xz) X Z C₂ (2) od(yz) Cl v3 v4 Cl-Cl C₂'(1) v2arrow_forward(c) Determine the results of the following multiplications of symmetry operations for the anthracene molecule (chemical structure shown below, C2 represents the main axis). [5 (i) C2. Oh (ii) i C₂ (iii) E-ov O 500arrow_forward1. List all the symmetry operations of the following two molecules. K F T-arrow_forward
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