Inorganic Chemistry
5th Edition
ISBN: 9781292134147
Author: Housecroft, Catherine E.
Publisher: Pearson,
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Chapter 3, Problem 30P
Determine how many CO stretching modes are possible for trans-
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Using group theory and the stretching mode of CO, predict how many IR active vibrational modes you should have for
A. Mo(CO)6 and
B. (1,3,5-C6H3(CH3)3)Mo(CO)3
Using infrared spectroscopy, how could you experimentally determine that you have the trans isomer rather than the cis one?
a )Find the representation of the C2v point group to which a px orbital belongs.
b)The four symmetry-adapted linear combinations (SALCs) built from the Cl 3s orbitals in the square planar (D4h) [PtCl4]2– anion have symmetry A1g, B1g, and Eu. List all expected Pt – SALC orbital combinations.
and What information does the extended 1D2 term symbol provide about a given atom?
Chapter 3 Solutions
Inorganic Chemistry
Ch. 3 - 3.1 Give the structures of the following...Ch. 3 - 3.2 In the group theory, what is meant by the...Ch. 3 - For each of the following 2-dimensional shapes,...Ch. 3 - Draw the structure of SO2 and identify its...Ch. 3 - 3.5 The structure of was shown in Fig. 2.1. Apart...Ch. 3 - By drawing appropriate diagrams, illustrate the...Ch. 3 - Using the answer to problem 3.6 to help you,...Ch. 3 - 3.8 Which of the following species or ions contain...Ch. 3 - Which of the following species contain C4 axis and...Ch. 3 - 3.10 How many mirror planes each do each of the...
Ch. 3 - (a) What structure would you expect Si2H6 to...Ch. 3 - Prob. 12PCh. 3 - Explain what is meant by an -fold axis of...Ch. 3 - 3.14 To which point group to does belong?
Ch. 3 - 3.15 The point group of is . What shape is this...Ch. 3 - 3.16 Determine the point group of .
Ch. 3 - 3.17 The point group of is . Draw the structure...Ch. 3 - 3.18 In worked example 2.7, the structure of the ...Ch. 3 - 3.19 Assign a point group to each member in the...Ch. 3 - (a) Deduce the point group of SF4. (b) Is SOF4 in...Ch. 3 - 3.21 Which of the point groups possess the highest...Ch. 3 - Prob. 22PCh. 3 - Prob. 23PCh. 3 - Prob. 24PCh. 3 - 3.25 By considering the effect of each symmetry...Ch. 3 - To what point group does CBr4 belong? Using the...Ch. 3 - Prob. 27PCh. 3 - Al2Cl6 belongs to the D2h point group: How many...Ch. 3 - Prob. 29PCh. 3 - Determine how many CO stretching modes are...Ch. 3 - 3.31 In 1993, the ion was reported for the first...Ch. 3 - Prob. 32PCh. 3 - (a) To which point group does a trigonal...Ch. 3 - Prob. 34PCh. 3 - Confirm the symmetry operations of (a) inversion...Ch. 3 - Prob. 42PCh. 3 - Prob. 43P
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Practice Problem ATTEMPT
Write the rate expressions for each of the following reactions:
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Chemistry
Draw a Lewis structure for each covalent molecule. a. HBr b. CH3F c. H2O2 d. N2H4 e. C2H6 f. CH2Cl2
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- 1) Predict the wavelength (in nm) of the lowest-energy electronic transition in the following polymethine ion, (CH3)2N+=CH-CH=CH-CH=CH-N(CH3)2. Assume C-N and C-C conjugated bond lengths to be equal to1.4Å. Please explain how you determine electron count, length, and homo/lomo for n valuesarrow_forwardDeduce the symmetry of the vibrational modes of the molecule XeCl4. It would be possible identify the geometry of this compound (planar square or tetrahedral) using the vibrational spectroscopy technique? Explain using the concept of group theory.arrow_forwardThe tetrahedral borohydride anion (BH4) has Ta symmetry and is commonly used as a reductant in organic chemistry. a) Using the Ta character table, identify the labels for the 2s and 2p orbitals of the B atom. b) Based upon the tetrahedral symmetry of the BH4 anion give a reducible representation for the combination of the four Is orbitals of the H atoms.arrow_forward
- Consider a trigonal bipyramidal molecule Fe(CO)5. please answer all thank you with all your reasinings from the basics (ii) How many normal modes and how many CO stretching vibrations belong this molecule possesses including which point group does it belong to? (iii) Determine the irreducible representations of CO stretching vibrations of a Fe(CO)5 molecule. Clearly show all your work. (iv) Which of the stretching vibrations of a Fe(CO)5 molecule are active in IR and which in Raman spectra? Justify your choice.arrow_forwardidentify the symmetry elements for each isomer of Ma3b2.arrow_forwardIdentify the point group to which each of the possible isomers of dichloroanthracene belong.arrow_forward
- 5. Using diagrams with numbered atoms, illustrate the symmetry operations of the three-fold proper axis of rotation, three two-fold axes of rotation, and four mirror planes that are present in BF3 molecule.arrow_forwardThe ClO2 molecule (which belongs to the group C2v) was trapped in a solid. Its ground state is known to be B1. Light polarized parallel to the y-axis (parallel to the OO separation) excited the molecule to an upper state. What is the symmetry species of that state?arrow_forward5. Use the character table of the Cav point group to assign the nine "s", "p", and d" orbitals to their corresponding symmetry species (irreducible representation).arrow_forward
- What can you conclude about the symmetry of the C3H5+ ion as it actually exists, as regards the bond lengths and the distribution of the positive charge?arrow_forward6. Which symmetry elements are lost on going from (a) BC13 to BCl2F and (b) BC12F to BBRCIF. Which symmetry elements are common to all these molecules?arrow_forwardBuild MOs of Co(CO)4C12 for only sigma bonds with D4h isomer. Then, find one mode of vibration that is IR active. CS Scanned with CamScannerarrow_forward
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