Organic Chemistry
5th Edition
ISBN: 9780078021558
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 3, Problem 3.31P
For each
hydrogen atom as
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2.) Draw 1 isomer of the compounds in item no. 3, and state the type of isomerism.
Example: 2-hydroxy-pentanal
OH
Structure:
Isomer:
он
Type of isomerism: Functional Isomerism
(a) Enter the IUPAC name for this alcohol:
CH,CH,CHCH,
ОН
Classify it as a primary, secondary, or tertiary alcohol:
(b) Enter the IUPAC name for this alcohol:
CH,CHCH,CH,CHOH
CH,
ČH,
Classify it as a primary, secondary, or tertiary alcohol:
(a) Classify the carbon atoms in each compound as 1°, 2°, 3°, or 4°. (b) Classify the hydrogen atoms in each compound as 1°, 2°, or 3°.
Chapter 3 Solutions
Organic Chemistry
Ch. 3 - Prob. 3.1PCh. 3 - (a) Classify the carbon atoms in each compound as...Ch. 3 - Problem 3.3 Classify a carbon atom by the number...Ch. 3 - Classify each alkyl halide and alcohol as , or...Ch. 3 - Prob. 3.5PCh. 3 - Prob. 3.6PCh. 3 - Draw the structure of a compound of molecular...Ch. 3 - Prob. 3.8PCh. 3 - Prob. 3.9PCh. 3 - Draw the structure of a compound fitting each...
Ch. 3 - Draw structures that fit each description and name...Ch. 3 - What types of intermolecular forces are present in...Ch. 3 - Which compound in each pair has the higher boiling...Ch. 3 - Explain why the boiling point of propanamide, is...Ch. 3 - Predict which compound in each pair has the higher...Ch. 3 - Prob. 3.16PCh. 3 - Which compounds are water soluble? a. b. c.Ch. 3 - a Label the hydrophobic and hydrophilic portions...Ch. 3 - Prob. 3.19PCh. 3 - Prob. 3.20PCh. 3 - Prob. 3.21PCh. 3 - Prob. 3.22PCh. 3 - Problem 3.23 (a) What types of intermolecular...Ch. 3 - Prob. 3.24PCh. 3 - Prob. 3.25PCh. 3 - Problem 3.26 Label the electrophilic and...Ch. 3 - Problem 3.27 Considering only electron density,...Ch. 3 - Prob. 3.28PCh. 3 - 3.29
Identify the functional groups in the...Ch. 3 - Prob. 3.30PCh. 3 - 3.31 For each alkane: (a) classify each carbon...Ch. 3 - 3.32 Identify the functional groups in each...Ch. 3 - 3.33 Identify each functional group located in the...Ch. 3 - 3.34 (a)Identify the functional groups in...Ch. 3 - Draw seven constitutional isomers with molecular...Ch. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Intramolecular force of attraction are often...Ch. 3 - 3.40 (a) Draw four compounds with molecular...Ch. 3 - 3.41 Rank the compounds in each group in order of...Ch. 3 - Explain why CH3CH2NHCH3 has higher boiling point...Ch. 3 - Prob. 3.43PCh. 3 - 3.44 Rank the following compounds in order of...Ch. 3 - Prob. 3.45PCh. 3 - 3.46 Rank the following compounds in order of...Ch. 3 - 3.47 Which of the following molecules can hydrogen...Ch. 3 - 3.48 Explain why diethylether and have similar...Ch. 3 - Prob. 3.49PCh. 3 - 3.50 Predict the solubility of each of the...Ch. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - 3.53 THC is the active component in marijuana, and...Ch. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - 3.56 Label the electrophilic and nucleophilic...Ch. 3 - 3.57 By using only electron density arguments,...Ch. 3 - 3.58 The composition of a cell membrane is not...Ch. 3 - Prob. 3.59PCh. 3 - 3.60 Quinapril (trade name Accupril) is a drug...Ch. 3 - 3.61 Answer each question about oxycodone, a...Ch. 3 - Prob. 3.62PCh. 3 - Prob. 3.63PCh. 3 - 3.64 Explain why A is less water soluble than B,...Ch. 3 - 3.65 Recall from section 1.10B that there is...
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- 1: Give at least five (5) uses of Alcohol and Phenol Name Functional Group R-OH Alcohols LOH Phenols Based on the illustration above. What is the difference between alcohol and phenol? Can Phenol react with alcohol?arrow_forwardEthanol (CH3CH2OH) and dimethyl ether (CH3OCH3) are constitutional isomers. (a) Predict which of the two has the higher boiling point. (b) Predict which of the two is more soluble in water.arrow_forward(a) Draw the four isomers of C₅H₁₀O that can be oxidizedto an aldehyde. (b) Draw the three isomers of C₅H₁₀O that canbe oxidized to a ketone. (c) Draw the isomers of C₅H₁₀O that cannot be easily oxidized to an aldehyde or ketone. (d) Name any isomer that is an alcohol.arrow_forward
- Indicate whether each statement is true or false. (a) Alkanesdo not contain any carbon–carbon multiple bonds.(b) Cyclobutane contains a four-membered ring. (c) Alkenescontain carbon–carbon triple bonds. (d) Alkynes containcarbon–carbon double bonds. (e) Pentane is a saturatedhydrocarbon but 1-pentene is an unsaturated hydrocarbon.(f) Cyclohexane is an aromatic hydrocarbon. (g) The methylgroup contains one less hydrogen atom than methane.arrow_forward1. (a) Draw the structures of the eight isomeric pentyl alcohols, C3H11OH. (b) Name each by the IUPAC system and by the carbinol system. (c) Label each as primary, secondary, or tertiary, (d) Which one is isopentyl alcohol? tert-Pentyl alcohol? (e) Give the structure of a primary, a secondary, and a tertiary alcohol of the formula C,H13OH.arrow_forwardnt Answer true or false. (a) The functional group of an alcohol is the -OH (hydroxyl) group. 1 (b) The parent name of an alcohol is the name of the longest carbon chain that contains the -OH group. (c) 1°, 2°, and 3° refer to the number of carbon groups bonded to the carbon bearing the -OH group. (d) In the IUPAC system, the presence of three -OH groups is shown by the ending -triol. (e) Glycols are diols where the two hydroxyl groups are bonded to two adjacent carbons. (f) Because of the presence of an -OH group, all alcohols are polar compounds. (g) The boiling points of alcohols decrease with increasing molecular weight. Q $ 0 % [References] L MacBook Pro Cengage Learning Cengage Technical Support Œ (arrow_forward
- Draw a structural formula for each alcohol. (a) 2-Methyl-2-propyl-1,3-propanediol (b) 1-Octanol (c) 3,3-Dimethylcyclohexanolarrow_forwardOH Amide H-C-0 H 100 (C) (a)arrow_forward1: Give at least five (5) uses of Etherin medicine. CH3 CH,-0-C-CH, CH, common name: methyl-t-butyl ether (MTBE) IUPAC name: 2-methoxy-2-methylpropane diphenyl ether or phenyl ether phenoxybenzene Analyze the given ether. Then describe the structural formula.arrow_forward
- 2. Complete each of the following reactions by supplying the missing portion indicated with a question mark. (a) Give the IUPAC name of the reactants. (b) Draw the structure and give the IUPAC name of the products. Acid ОН HOarrow_forwardGive the IUPAC name of each of the following compounds. (a) CH3CH2CH2-----OH (b) CH3---CH2---C----H || O (c) CH3CH2CH2CH2---C--CH3 || O (d) CH3---CH2----CH2----C---OH || Oarrow_forwarda) Draw the four isomers of C5H12O that can be oxidized to an aldehyde. (b) Draw the three isomers of C5H12O that can be oxidized to a ketone. (c) Draw the isomers of C5H12O that cannot be easily oxidized to an aldehyde or ketone. (d) Name any isomer that is an alcohol.arrow_forward
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Chapter 4 Alkanes and Cycloalkanes Lesson 2; Author: Linda Hanson;https://www.youtube.com/watch?v=AL_CM_Btef4;License: Standard YouTube License, CC-BY
Chapter 4 Alkanes and Cycloalkanes Lesson 1; Author: Linda Hanson;https://www.youtube.com/watch?v=PPIa6EHJMJw;License: Standard Youtube License