Organic Chemistry
5th Edition
ISBN: 9780078021558
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 3, Problem 3.40P
(a) Draw four compounds with molecular formula
one different
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Many naturally occurring compounds contain more than one functional group. Identify the functional groups in the following compounds:(a) Penicillin G is a naturally occurring antibiotic.(b) Dopamine is the neurotransmitter that is deficient in Parkinson’s disease.(c) Capsaicin gives the fiery taste to chili peppers.(d) Thyroxine is the principal thyroid hormone.(e) Testosterone is a male sex hormone.
1. (a) Draw the structures of the eight isomeric pentyl
alcohols, C3H11OH. (b) Name each by the IUPAC system and by the carbinol
system.
(c) Label each as primary, secondary, or tertiary, (d) Which one is isopentyl
alcohol? tert-Pentyl alcohol? (e) Give the structure of a primary, a secondary, and
a tertiary alcohol of the formula C,H13OH.
TRUE OR FALSE
(a) There are three amines with the molecular formula C3H9N.
(b) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group.
(c) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid.
(d) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°.
(e) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O.
(f) The molecular formula of the smallest carboxylic acid is C2H4O2.
Chapter 3 Solutions
Organic Chemistry
Ch. 3 - Prob. 3.1PCh. 3 - (a) Classify the carbon atoms in each compound as...Ch. 3 - Problem 3.3 Classify a carbon atom by the number...Ch. 3 - Classify each alkyl halide and alcohol as , or...Ch. 3 - Prob. 3.5PCh. 3 - Prob. 3.6PCh. 3 - Draw the structure of a compound of molecular...Ch. 3 - Prob. 3.8PCh. 3 - Prob. 3.9PCh. 3 - Draw the structure of a compound fitting each...
Ch. 3 - Draw structures that fit each description and name...Ch. 3 - What types of intermolecular forces are present in...Ch. 3 - Which compound in each pair has the higher boiling...Ch. 3 - Explain why the boiling point of propanamide, is...Ch. 3 - Predict which compound in each pair has the higher...Ch. 3 - Prob. 3.16PCh. 3 - Which compounds are water soluble? a. b. c.Ch. 3 - a Label the hydrophobic and hydrophilic portions...Ch. 3 - Prob. 3.19PCh. 3 - Prob. 3.20PCh. 3 - Prob. 3.21PCh. 3 - Prob. 3.22PCh. 3 - Problem 3.23 (a) What types of intermolecular...Ch. 3 - Prob. 3.24PCh. 3 - Prob. 3.25PCh. 3 - Problem 3.26 Label the electrophilic and...Ch. 3 - Problem 3.27 Considering only electron density,...Ch. 3 - Prob. 3.28PCh. 3 - 3.29
Identify the functional groups in the...Ch. 3 - Prob. 3.30PCh. 3 - 3.31 For each alkane: (a) classify each carbon...Ch. 3 - 3.32 Identify the functional groups in each...Ch. 3 - 3.33 Identify each functional group located in the...Ch. 3 - 3.34 (a)Identify the functional groups in...Ch. 3 - Draw seven constitutional isomers with molecular...Ch. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Intramolecular force of attraction are often...Ch. 3 - 3.40 (a) Draw four compounds with molecular...Ch. 3 - 3.41 Rank the compounds in each group in order of...Ch. 3 - Explain why CH3CH2NHCH3 has higher boiling point...Ch. 3 - Prob. 3.43PCh. 3 - 3.44 Rank the following compounds in order of...Ch. 3 - Prob. 3.45PCh. 3 - 3.46 Rank the following compounds in order of...Ch. 3 - 3.47 Which of the following molecules can hydrogen...Ch. 3 - 3.48 Explain why diethylether and have similar...Ch. 3 - Prob. 3.49PCh. 3 - 3.50 Predict the solubility of each of the...Ch. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - 3.53 THC is the active component in marijuana, and...Ch. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - 3.56 Label the electrophilic and nucleophilic...Ch. 3 - 3.57 By using only electron density arguments,...Ch. 3 - 3.58 The composition of a cell membrane is not...Ch. 3 - Prob. 3.59PCh. 3 - 3.60 Quinapril (trade name Accupril) is a drug...Ch. 3 - 3.61 Answer each question about oxycodone, a...Ch. 3 - Prob. 3.62PCh. 3 - Prob. 3.63PCh. 3 - 3.64 Explain why A is less water soluble than B,...Ch. 3 - 3.65 Recall from section 1.10B that there is...
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- (i) Write the name and draw the structure of a saturated hydrocarbon with four carbon atoms.arrow_forward(a) What structural feature is associated with each type of hydrocarbon: alkane, cycloalkane, alkene, and alkyne?(b) Give the general formula for each type.(c) Which hydrocarbons are considered saturated?arrow_forwardThere are two different butanoic acids with the formula C5H10O2. Draw and name them.arrow_forward
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