Dotted lines to show π bond can form between the two white p orbitals should be added. Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds. A single bond has one σ bond; double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond. For instance, pi bond formation that involves lateral overlap of dumble bell lobes of p orbital as in case of a triple bond are illustrated as follows:

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Answer 1

Question

Chapter 3, Problem 15CTQ

(a)

Interpretation Introduction

Interpretation: Dotted lines to show π bond can form between the two white p orbitals should be added.

Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

A single bond has one σ bond; double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond. For instance, pi bond formation that involves lateral overlap of dumble bell lobes of p orbital as in case of a triple bond are illustrated as follows:

(b)

Interpretation Introduction

Interpretation: Dotted lines to show σ bond that can form between the two white p orbitals should be labeled.

Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

A single bond has one σ bond; double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond. There are two possible overlaps by s orbital that results in head to head overlap and sigma bond formation. These are illustrated as follows:

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a) Draw the Lewis structure for CF3. Show this in your work for credit. b) What is the shape or geometry at the center atom? c) What is the bond angle at the center atom? Enter a plain number, but include a "<" sign in front if needed. d) What is the hybridization at the center atom? Enter without superscripts. For instance, if it were sp°, you would type "sp3". e) Is the molecule polar or nonpolar overall? Type "polar" or "nonpolar".

b) Now draw those atomic orbitals you obtained in part (a), and then overlap them to (1 form the C-F bonds (you only have to draw ONE C-F bond) and bonds of the C=O. Feel free to draw as many drawings as you need. Make them clear. Label the atomic orbitals of all atoms and also label the resulting bonds as σ or TT. NO EXPLANATIONS ON THIS PAGE - JUST THE ORBITALS (LOBES)

a) Draw the Lewis structure for CF3. Show this in your work for credit. b) What is the shape or geometry at the center atom? pyramidal c) What is the bond angle at the center atom? Enter a plain number, but include a "<" sign in front if needed. d) What is the hybridization at the center atom? Enter without superscripts. For instance, if it were sp°, you would type "sp3". sp3 e) Is the molecule polar or nonpolar overall? Type "polar" or "nonpolar". polar

Answer 2

Question

Chapter 3, Problem 15CTQ

(a)

Interpretation Introduction

Interpretation: Dotted lines to show π bond can form between the two white p orbitals should be added.

Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

A single bond has one σ bond; double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond. For instance, pi bond formation that involves lateral overlap of dumble bell lobes of p orbital as in case of a triple bond are illustrated as follows:

(b)

Interpretation Introduction

Interpretation: Dotted lines to show σ bond that can form between the two white p orbitals should be labeled.

Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

A single bond has one σ bond; double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond. There are two possible overlaps by s orbital that results in head to head overlap and sigma bond formation. These are illustrated as follows:

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Answer 3

Question

Chapter 3, Problem 15CTQ

(a)

Interpretation Introduction

Interpretation: Dotted lines to show π bond can form between the two white p orbitals should be added.

Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

A single bond has one σ bond; double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond. For instance, pi bond formation that involves lateral overlap of dumble bell lobes of p orbital as in case of a triple bond are illustrated as follows:

(b)

Interpretation Introduction

Interpretation: Dotted lines to show σ bond that can form between the two white p orbitals should be labeled.

Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

A single bond has one σ bond; double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond. There are two possible overlaps by s orbital that results in head to head overlap and sigma bond formation. These are illustrated as follows:

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Answer 4

Question

Chapter 3, Problem 15CTQ

(a)

Interpretation Introduction

Interpretation: Dotted lines to show π bond can form between the two white p orbitals should be added.

Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

A single bond has one σ bond; double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond. For instance, pi bond formation that involves lateral overlap of dumble bell lobes of p orbital as in case of a triple bond are illustrated as follows:

(b)

Interpretation Introduction

Interpretation: Dotted lines to show σ bond that can form between the two white p orbitals should be labeled.

Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

A single bond has one σ bond; double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond. There are two possible overlaps by s orbital that results in head to head overlap and sigma bond formation. These are illustrated as follows:

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Answer 5

Chapter 3, Problem 15CTQ

(a)

Interpretation Introduction

Interpretation: Dotted lines to show π bond can form between the two white p orbitals should be added.

Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

A single bond has one σ bond; double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond. For instance, pi bond formation that involves lateral overlap of dumble bell lobes of p orbital as in case of a triple bond are illustrated as follows:

(b)

Interpretation Introduction

Interpretation: Dotted lines to show σ bond that can form between the two white p orbitals should be labeled.

Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

A single bond has one σ bond; double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond. There are two possible overlaps by s orbital that results in head to head overlap and sigma bond formation. These are illustrated as follows:

Answer 6

Chapter 3, Problem 15CTQ

(a)

Interpretation Introduction

Interpretation: Dotted lines to show π bond can form between the two white p orbitals should be added.

Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

A single bond has one σ bond; double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond. For instance, pi bond formation that involves lateral overlap of dumble bell lobes of p orbital as in case of a triple bond are illustrated as follows:

Answer 7

Chapter 3, Problem 15CTQ

(a)

Interpretation Introduction

Interpretation: Dotted lines to show π bond can form between the two white p orbitals should be added.

Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

A single bond has one σ bond; double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond. For instance, pi bond formation that involves lateral overlap of dumble bell lobes of p orbital as in case of a triple bond are illustrated as follows:

Answer 8

(b)

Interpretation Introduction

Interpretation: Dotted lines to show σ bond that can form between the two white p orbitals should be labeled.

Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

A single bond has one σ bond; double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond. There are two possible overlaps by s orbital that results in head to head overlap and sigma bond formation. These are illustrated as follows:

Answer 9

(b)

Interpretation Introduction

Interpretation: Dotted lines to show σ bond that can form between the two white p orbitals should be labeled.

Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

A single bond has one σ bond; double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond. There are two possible overlaps by s orbital that results in head to head overlap and sigma bond formation. These are illustrated as follows:

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 3 - Prob. 1CTQ Ch. 3 - What neutral atom is represented by the electron...Ch. 3 - Prob. 3CTQ Ch. 3 - Consider any one of the four identical hybrid...Ch. 3 - Prob. 5CTQ Ch. 3 - Prob. 6CTQ Ch. 3 - Prob. 7CTQ Ch. 3 - Prob. 8CTQ Ch. 3 - Prob. 9CTQ Ch. 3 - Prob. 10CTQ

Solution Summary: The author explains that bonds formed due to head-to-head overlap are termed sigma bonds and pi-bonds.

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Chapter 3 Solutions