Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 29.6, Problem CQ
Interpretation Introduction
Interpretation:
The propagation step involving chain
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Which of these is a requirement of monomers in order to undergo addition polymerization?
a. The presence of an oxygen atom.
b. The presence of a carbon to carbon double bond.
c. The presence of a carbon to carbon triple bond.
d. The presence of a lone pair.
7. When asymmetric alkenes polymerize (such as chloroethene to produce PVC), the pendant group like
chlorine can be arranged in different ways. An arrangement in which the -Cl groups are arranged on
the same side of the polymer chain is called a(n) ,
a. Atactic
b. Isotactic
arrangement.
c. Syndiotactic
d. Sporadic
8. Kevlar is a type of polymer which has a great resistance to tear. Its application includes its use in making
bulletproof vests and radial tires. The two monomers used to make Kevlar are the following:
H
H
H-O-
c-0-H
H-N-
-N-H
Monomer One
Monomer Two
When these two monomers join
a. A molecule of CO2 will be eliminated and an ester linkage will form
b. Nothing will be eliminated and the two monomers will be linked through a hydrogen to hydrogen
bond
c. A water molecule will be eliminated and a peptide linkage will be formed
d. Nothing will be eliminated. The two monomers will be linked by a carbon-carbon bond.
They tend to strengthen a material (such as a plastic) made from this polymer. They also make the polymer harder and more difficult to melt.
a. crosslinks
b. Thermoplastics
c. pendant groups
d. backbone
Chapter 29 Solutions
Organic Chemistry
Ch. 29.2 - Prob. 29.1PCh. 29.5 - Prob. 29.2PCh. 29.6 - Prob. AQCh. 29.6 - Prob. BQCh. 29.6 - Prob. CQCh. 29.6 - Prob. DQCh. 29.6 - Prob. EQCh. 29.6 - Prob. FQCh. 29.6 - Prob. 29.3PCh. 29.6 - Prob. 29.4P
Ch. 29 - Prob. 29.5PCh. 29 - Prob. 29.6PCh. 29 - Prob. 29.7PCh. 29 - Prob. 29.8PCh. 29 - Prob. 29.9PCh. 29 - Prob. 29.10PCh. 29 - Prob. 29.11PCh. 29 - Prob. 29.12PCh. 29 - Prob. 29.13PCh. 29 - Prob. 29.14PCh. 29 - Prob. 29.15PCh. 29 - Prob. 29.16PCh. 29 - Polycarbonates (Section 29.5C) are also formed by...Ch. 29 - Prob. 29.18PCh. 29 - Prob. 29.19PCh. 29 - Prob. 29.20PCh. 29 - Prob. 29.21PCh. 29 - Draw a structural formula of the polymer resulting...Ch. 29 - Prob. 29.23PCh. 29 - Prob. 29.24PCh. 29 - Prob. 29.25PCh. 29 - Select the monomer in each pair that is more...Ch. 29 - Prob. 29.27PCh. 29 - Prob. 29.28PCh. 29 - Prob. 29.29PCh. 29 - Prob. 29.30PCh. 29 - Prob. 29.31PCh. 29 - Prob. 29.32PCh. 29 - Prob. 29.33PCh. 29 - Radical polymerization of styrene gives a linear...Ch. 29 - Prob. 29.35PCh. 29 - Prob. 29.36PCh. 29 - Prob. 29.37PCh. 29 - Prob. 29.38P
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- 8. Deformation behavior of a thermoplastic plastic above glass transition temperature a. viscous fluid b. brittle C. leathery and then rubbery d. glassy a. Polymer b. Monomer c. plastic d. synthetic 10. Stages involve in addition polymerization EXCEPT a. Propagation b. Catalyst C. termination d. initiation abioe onarrow_forward6. Polymers formed via addition polymerization are often used as plastics. The atoms/groups which make up the monomers determine the properties of the plastic. An example of this is "vinyl". Which monomers join together to form vinyl? c. Propanol a. Ethene b. Chloroethene d. Phenylethenearrow_forwardWhich function group/s is/are present in monomers that undergo cationic polymerization. A. electron donating B. electron withdrawing C. both a and b D. none of the given choicesarrow_forward
- Teflon is the polymer used to create non-stick surfaces on cookware. The monomer for Teflon is tetrafluoroethene. a. Draw tetrafluoroethene. b. What type of polymerization reaction would be used to create Teflon? c. Show the repeat unit of Teflon. d. Explain based on the molecular structure of Teflon why it would have the non-stick and chemically resistant properties that make it suitable for use in pots and pans.arrow_forward1. What is polymer? a. A large molecule made by twisted chains. b. A small molecule made of one atom. c. A large molecule made by human. d. A large molecule made by monomers.arrow_forwardWhich of the following monomers is suitable for condensation polymerization? A. Diacid and Diamine B. Vinyl chloride C. Ethane D. Propenearrow_forward
- a. Condensation monomers: Fill in the missing reactants or polymer products for the condensation polymer reactions below. b. For the second reaction above, show the full mechanism (3 steps) for one addition of the two monomers (3 steps).arrow_forwardWhat monomer is needed to form attached polymer?arrow_forward.Explain the term polymerization with two examples.arrow_forward
- This polymer is composed of 2 monomer units: an acid chloride and an amine. In the box below, draw the structure of both monomers. flands (CH₂)6- -85 I.. H ChemDoodle • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate structures with + signs from the drop-down menu. -CH₂ On Sn [F < ZI 22 Sarrow_forwardConsider a polymer made from tetrachloroethylene.A. Draw a portion of a polymer chain.B. What is the molar mass of the polymer if it contains 3.2x10³ tetrachloroethylene molecules?arrow_forward5. There are two main types of polymerization, the first being addition. Which of these is a requirement of mon omers in order to undergo addition polymerization ? The presence of a carbon to carbon double bond. The presence of a carbon to carbon triple bond. The presence of a lone pair. The presence of an oxygen atom. а. b. C. d.arrow_forward
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