Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 29, Problem 29.12P
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Macromolecules can also be formed from cyclic monomers such as cyclic hydrocarbons, ethers, esters, amides, siloxanes, and sulfur (eight-membered ring). Thus, ring-opening polymerization is of particular interest, since macromolecules of almost any chemical structure can be prepared. Choose two of the above type polymers to explain the mechanism and chemical reaction of polymerization process.
Provide the mechanism for the step-growth polymerization of citric acid and ethylene glycol to form poly (ethylene glycol)-citrate. Show all steps.
Explain with more details, how you can prepare poly(propylene oxide) by using Anionic and Cationic polymerizations?
Chapter 29 Solutions
Organic Chemistry
Ch. 29.2 - Prob. 29.1PCh. 29.5 - Prob. 29.2PCh. 29.6 - Prob. AQCh. 29.6 - Prob. BQCh. 29.6 - Prob. CQCh. 29.6 - Prob. DQCh. 29.6 - Prob. EQCh. 29.6 - Prob. FQCh. 29.6 - Prob. 29.3PCh. 29.6 - Prob. 29.4P
Ch. 29 - Prob. 29.5PCh. 29 - Prob. 29.6PCh. 29 - Prob. 29.7PCh. 29 - Prob. 29.8PCh. 29 - Prob. 29.9PCh. 29 - Prob. 29.10PCh. 29 - Prob. 29.11PCh. 29 - Prob. 29.12PCh. 29 - Prob. 29.13PCh. 29 - Prob. 29.14PCh. 29 - Prob. 29.15PCh. 29 - Prob. 29.16PCh. 29 - Polycarbonates (Section 29.5C) are also formed by...Ch. 29 - Prob. 29.18PCh. 29 - Prob. 29.19PCh. 29 - Prob. 29.20PCh. 29 - Prob. 29.21PCh. 29 - Draw a structural formula of the polymer resulting...Ch. 29 - Prob. 29.23PCh. 29 - Prob. 29.24PCh. 29 - Prob. 29.25PCh. 29 - Select the monomer in each pair that is more...Ch. 29 - Prob. 29.27PCh. 29 - Prob. 29.28PCh. 29 - Prob. 29.29PCh. 29 - Prob. 29.30PCh. 29 - Prob. 29.31PCh. 29 - Prob. 29.32PCh. 29 - Prob. 29.33PCh. 29 - Radical polymerization of styrene gives a linear...Ch. 29 - Prob. 29.35PCh. 29 - Prob. 29.36PCh. 29 - Prob. 29.37PCh. 29 - Prob. 29.38P
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- Use resonance structures to explain the stabilization of the intermediate formed in the cationic polymerization of styrene to form polystyrene.arrow_forwardNylon 6,10 is prepared by polymerization of a diamine and a diacid chloride. Draw a structural formula for each reactant and for the repeat unit in this polymer.arrow_forwardShow the differences between the chain-growth and step-growth mechanisms of polymerization.arrow_forward
- The structure of propylene is shown. This alkene undergoes addition polymerization to form polypropylene, a thermoplastic polymer with many different applications.arrow_forwardDraw the structure for the polymer produced from the monomer vinylidene chloride (CH2=CCl2).arrow_forwardPolybutadiene-b-polystyrene-b-polybutadiene can be grown from the "outside in" or inside out" processes. Explain what each of these processes would entail, using chemical structures and words. Use anionic polymerization to polymerize each of the blocks.arrow_forward
- Draw (by hand) the monomers used to synthesize poly(ethyl cyanoacrylate) and poly(octyl cyanoacrylate), and chemical structure of the repeat units of each when polymerized.arrow_forwardCan you explain condensation polymerization and give an example with structure of one with 2 carboxylic acid groups and 2 OH groups.arrow_forwardPoly(ethylene terephthalate) is a linear polyester that can be synthesized from the condensation polymerization between terephthalic acid and ethylene glycol, as shown previously in Equation 26-27. What alcohol would you react with terephthalic acid to produce a branched polyester? Draw a portion of the resulting polymer that shows a main chain and one branching point.arrow_forward
- certain polymers can be broken down by the body. Resorbable sutures can be made using polycaprolactone. Polycaprolactone is made by a ring-opening polymerization of caprolactone (shown below) using an alkoxide such as sodium ethoxide. Given the monomer and alkoxide shown below, draw a dimer (two repeat units) of the growing polymer chain with the correct end groups.arrow_forwardBriefly explain each of the polymers. Indicate either the polymer is produced by condensation or addition polymerization. - Nylon - Polystyrene - Polyester - Poly (Vinyl Acetate) - Poly (Vinylidene Chloride)arrow_forwardDraw the structure of the polymer that results from anionic polymerization of p-trichloromethylstyrene (CCl,CgH,CH=CH2) using ethylene oxide as the electrophile to terminate the chain.arrow_forward
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