Organic Chemistry
Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 29, Problem 29.31P
Interpretation Introduction

Interpretation:

The intramolecular chain transfer during radical polymerization of styrene has to be compared.

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When polyethylene is made by free radical polymerization, the resulting polymer has a significant amount of branching, resulting in low-density polyethylene (see Section 26.9a). When styrene undergoes free radical polymerization, on the other hand, very little branching occurs. Explain this phenomenon.
Explain why styrene (CH2=CHPh) can be polymerized to polystyrene by all three methods of chain-growth polymerization.
A polymerization reaction in which monomers react to form a polymer chain without net loss of atoms substitution reduction (c) cross-linking hybridization E) addition
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