Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 24, Problem 48DSP
Interpretation Introduction
Interpretation:
Correct structures for the hexose that gives the same aldaric acid as
Concept introduction:
The stereoisomers that are not mirror images are diastereomers.
They differ in absolute configuration at only one chirality center.
The aldaric acids have two
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The following are representations of two forms of glucose. The six-membered ring is known to exist in a chair conformation in each form. Draw clear representations of the most stable conformation of each. Are they two different conformations of the same molecule, or are they stereoisomers that cannot be interconverted by rotation about single bonds? Which substituents (if any) occupy axial sites?
True or False:
1. The eclipsed conformation of a linear alkane IS called cis, while the anti conformation of an alkane IS called trans.
2. In the conversion of open-chain D-glucose to the ring form, the aldehyde carbon (carbon #1) bonds to the oxygen on carbon number 5 to form a ring that is both PYRANOSE and UNLOCKED.
4. - Determine the structural relationship between the compounds in each of the pairs
that follow. They may be unrelated, identical (the same compound), constitutional
isomers, diastereoisomers, enantiomers?
- Identify the optically active (chiral) compounds and any meso compounds.
- Assign a configuration (R or S) to all stereocenters.
- Name all compounds so that the name reflects the structure unambiguously.
a)
b)
c)
d)
e)
f)
H-
HO-
CHO
H3C
-NH₂ H-
-H
H-
CH2OH
H CH3
CH3
H
Ph
H CH3 H H
CI Ph
H
H
CI
CH3
CH₂OH
-OH
-NH₂
CI
H
H
CI
& t
OH
CHO
H3C H
OH
O-CH3
oma
O-CH3
H3C
OH
Chapter 24 Solutions
Organic Chemistry - Standalone book
Ch. 24.2 - Prob. 1PCh. 24.3 - Problem 24.2 Which aldotetrose in the structure...Ch. 24.4 - Prob. 3PCh. 24.4 - Prob. 4PCh. 24.6 - Prob. 5PCh. 24.6 - Prob. 6PCh. 24.7 - Prob. 7PCh. 24.8 - Prob. 8PCh. 24.8 - Prob. 9PCh. 24.9 - Prob. 10P
Ch. 24.10 - Prob. 11PCh. 24.10 - Prob. 12PCh. 24.11 - Prob. 13PCh. 24.12 - Prob. 14PCh. 24.14 - Prob. 15PCh. 24.14 - Prob. 16PCh. 24.14 - Prob. 17PCh. 24.14 - Using Mechanism 24.2 as a guide, write a stepwise...Ch. 24.15 - Prob. 19PCh. 24.17 - Prob. 20PCh. 24.17 - Prob. 21PCh. 24.18 - Prob. 22PCh. 24.18 - Prob. 23PCh. 24.18 - Prob. 24PCh. 24.20 - Prob. 25PCh. 24 - Prob. 26PCh. 24 - Prob. 27PCh. 24 - Prob. 28PCh. 24 - Prob. 29PCh. 24 - Prob. 30PCh. 24 - Prob. 31PCh. 24 - Prob. 32PCh. 24 - Prob. 33PCh. 24 - Prob. 34PCh. 24 - Prob. 35PCh. 24 - Methyl glycosides of 2-deoxy sugars have been...Ch. 24 - Prob. 37PCh. 24 - Prob. 38PCh. 24 - Prob. 39PCh. 24 - Prob. 40PCh. 24 - Treatment of d-mannose with methanol in the...Ch. 24 - Prob. 42PCh. 24 - Prob. 43PCh. 24 - Prob. 44PCh. 24 - Prob. 45DSPCh. 24 - Prob. 46DSPCh. 24 - Prob. 47DSPCh. 24 - Prob. 48DSPCh. 24 - Prob. 49DSP
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