General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Question
Chapter 23.4, Problem 23.6P
Interpretation Introduction
Interpretation:
The reagent among FAD and FADH2 which will carry out the given reaction is to be determined.
Concept introduction:
A biochemical reaction refers to a
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Is
FAD + 2H=FADH2
an oxidation or reduction reaction?
S
What type of reaction is this?
COO™
H—C—H
HC H
COO-
FAD
FADH₂
1
OOC
4
O Oxidation of succinate to fumarate
Reduction of succinate by succinate dehydrogenase
Oxidation of FAD to FADH₂
O Oxidation of fumarate to succinate
COO™
- 4 W
If you discover a mutant yeast whose glycolytic pathway was shorter
because of the presence of a new enzyme catalyzing the reaction as shown
below:
NAD* NADH + H*
Glyceraldehyde 3-phosphate + H,
3-phosphoglycerate
Would shortening the glycolytic pathway in this way benefit the cell?
Explain.
Chapter 23 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 23.2 - Prob. 23.1PCh. 23.3 - Prob. 23.2PCh. 23.3 - The phosphorylation of glucose to glucose...Ch. 23.3 - Prob. 23.3PCh. 23.3 - Use the values for the hydrolysis of creatine...Ch. 23.4 - Prob. 23.2PPCh. 23.4 - Prob. 23.5PCh. 23.4 - Prob. 23.6PCh. 23.4 - Prob. 23.7PCh. 23.4 - Prob. 23.8P
Ch. 23.5 - Prob. 23.3PPCh. 23.5 - Prob. 23.9PCh. 23.5 - Prob. 23.10PCh. 23.5 - Prob. 23.11PCh. 23.6 - Prob. 23.12PCh. 23.6 - At several points in the electron transport chain,...Ch. 23.6 - In which region of the mitochondrion-the matrix or...Ch. 23 - Prob. 15PCh. 23 - Explain why mitochondria are called the...Ch. 23 - Prob. 17PCh. 23 - Prob. 18PCh. 23 - Prob. 19PCh. 23 - Prob. 20PCh. 23 - What are coupled reactions and why does coupling...Ch. 23 - Prob. 22PCh. 23 - Prob. 23PCh. 23 - Prob. 24PCh. 23 - Prob. 25PCh. 23 - Prob. 26PCh. 23 - Prob. 27PCh. 23 - Prob. 28PCh. 23 - Prob. 29PCh. 23 - Prob. 30PCh. 23 - Prob. 31PCh. 23 - Prob. 32PCh. 23 - (a) Draw the structure of the high-energy...Ch. 23 - Prob. 34PCh. 23 - Classify each substance as an oxidizing agent, a...Ch. 23 - Classify each substance as an oxidizing agent, a...Ch. 23 - When a substrate is oxidized, is NAD+ oxidized or...Ch. 23 - When a substrate is reduced, is FADH2 oxidized or...Ch. 23 - Prob. 39PCh. 23 - Prob. 40PCh. 23 - Prob. 41PCh. 23 - Prob. 42PCh. 23 - Prob. 43PCh. 23 - Prob. 44PCh. 23 - Prob. 45PCh. 23 - Prob. 46PCh. 23 - The conversion of isocitrate to ketoglutarate in...Ch. 23 - Prob. 48PCh. 23 - Prob. 49PCh. 23 - Prob. 50PCh. 23 - Prob. 51PCh. 23 - What is the role of each of the following in the...Ch. 23 - What is the role of each of the following in the...Ch. 23 - Prob. 54PCh. 23 - Prob. 55PCh. 23 - Prob. 56PCh. 23 - Prob. 57PCh. 23 - Prob. 58PCh. 23 - Prob. 59PCh. 23 - Prob. 60PCh. 23 - Prob. 61PCh. 23 - Prob. 62PCh. 23 - Prob. 63PCh. 23 - Prob. 64PCh. 23 - Prob. 65PCh. 23 - Prob. 66PCh. 23 - Prob. 67PCh. 23 - Prob. 68PCh. 23 - Prob. 69PCh. 23 - Prob. 70PCh. 23 - Prob. 71PCh. 23 - Prob. 72PCh. 23 - Prob. 73PCh. 23 - Prob. 74PCh. 23 - Prob. 75CPCh. 23 - Prob. 76CP
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- NAD+ and FAD+ are?arrow_forwardFAD is covalently bound to succinate dehydrogenase (the enzyme whose mechanism was shown on the previous page) as a result of a base removing a proton from the C-8 methyl group and an acid donating a proton to N-1. Then a histidine side chain of the enzyme adds to the methylene carbon at C-8 and a proton adds to N-5. Draw the mechanism for these two steps using B: _ and HB for the base and acid, respectively.arrow_forwardChoose the appropriate species for boxes A and B in the following reaction: OA: FAD B: FADH₂ OA: FADH2 B: FAD OA: NADH + H+ B: NAD+ OA: NAD B: NADH + H+ Barrow_forward
- The rate-limiting step is a metabolic pathway is the slowest step which determines the overall rate of the other reactions in the pathway. In glycolysis, the rate limiting step is a phosphorylation reaction where phosphofructokinase (PFK-1) catalyzes the reaction fructose-6-bisphosphate -> fructose-1,6-bisphosphate, the same step in gluconeogenesis. Select one: The statement is FALSE. The statement is TRUE.arrow_forwardThe enzyme that catalyzes reaction below can be classified as: NAD* NADH + H* Но- H-Ć- Н—с—н H- malate dehydrogenase Oxaloacetate Malatearrow_forwardNAD+ has two ribose units in its structure; FAD has a ribose and a ribitol. What is the relationship between these molecules?arrow_forward
- Draw each of the following types of block diagrams for FAD. a. Three-subunit diagram b. Six-subunit diagramarrow_forwardЗосім. A- Using the reaction shown above, which activated carrier molecule is needed for this type of reaction? OH НО OH OH OH A = FAD; B = FADH2 O A = ATP; B = ADP 0 A= FADH2; ; B = FAD+ O A = CoA; B = acetyl CoA O A= NADH; ; B = NAD+ O A= NAD+; ; B = FADH2 O A = NAD+; B= NADH + OH НО OH 'OH вarrow_forward
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