General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Textbook Question
Chapter 22, Problem 89IAE
The text mentions that ammonium perchlorate is an explosion hazard. Assuming that
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There are two steps in the usual industrial preparation of acrylic acid, the immediate precursor of several useful plastics. In the first step, calcium carbide and
water react to form acetylene and calcium hydroxide:
CaC₂(s) + 2 H₂O(g) → C₂H₂(g) + Ca(OH)₂(s)
-
In the second step, acetylene, carbon dioxide and water react to form acrylic acid:
6C₂H₂(g) + 3 CO₂(g) + 4H₂O(g) → 5 CH₂CHCO₂(g)
ΔΗ = 132. kJ
Calculate the net change in enthalpy for the formation of one mole of acrylic acid from calcium carbide, water and carbon dioxide from these reactions.
Round your answer to the nearest kJ.
KJ
X
Ś
AH-414. kJ
Part 1
A student carried out an investigation to observe the effect of changing
concentration of sulfuric acid on the breakdown of calcium carbonate
(marble) chips. They changed the concentration of the acid between
each test but kept the size of the marble chips constant. The full equation
for the reaction and a graph of the overall results can be seen below.
CaCO3(s) + H₂SO4(aq) → CaSO4(aq) + CO2(g) + H₂O (1)
a)
b)
Rate of Reaction
*
Concentration of Acid (mol dm³)
Explain, using collision theory, why the student obtained
these results, and state what they could conclude about the
effect of changing concentration of acid on the rate of reaction
between calcium carbonate and sulfuric acid.
If the student had ground up the calcium carbonate chips into
a powder and run the tests again, what would you expect to
happen to the rate of reaction? Briefly explain why by
applying collision theory.
Part 2
The student ran the same experiment, but this time changed the
temperature, increasing it…
The breaking of the O-O bond in peroxydisulfuryl
difluoride (FO,SOOSO,F) gives FO,SO:
(FO2SO)2 2 2 FO2SO
The compound on the left of this equation is a colorless
liquid that boils at 67.1°C. Its vapor, when heated to
about 100°C, turns brown as the product of the reaction
forms. Suppose that, in a sample of the vapor, the intensity
of the brown color doubles between 100°C and 110°C
and that the total pressure increases only by the 2.7%
predicted for an ideal gas. Estimate AH° for the preceding
reaction.
Chapter 22 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
Ch. 22 - Give the formula of the stable fluride by Li, Be,...Ch. 22 - Fluorine is able to stabilize element’s in very...Ch. 22 - Prob. 3ECh. 22 - Prob. 4ECh. 22 - Prob. 5ECh. 22 - Prob. 6ECh. 22 - Prob. 7ECh. 22 - Use VSEPR theory to predict the probable geometric...Ch. 22 - Prob. 9ECh. 22 - Prob. 10E
Ch. 22 - Prob. 11ECh. 22 - Prob. 12ECh. 22 - Prob. 13ECh. 22 - Prob. 14ECh. 22 - Make a general prediction about which of the...Ch. 22 - The following properties of astatine have been...Ch. 22 - Prob. 17ECh. 22 - Prob. 18ECh. 22 - Prob. 19ECh. 22 - Prob. 20ECh. 22 - Prob. 21ECh. 22 - Prob. 22ECh. 22 - Prob. 23ECh. 22 - Prob. 24ECh. 22 - Each of the following compounds decomposes to...Ch. 22 - Ozone is a power oxidizing agent. Using ozone as...Ch. 22 - Prob. 27ECh. 22 - Prob. 28ECh. 22 - Prob. 29ECh. 22 - Prob. 30ECh. 22 - Prob. 31ECh. 22 - Prob. 32ECh. 22 - Prob. 33ECh. 22 - In water, O2(aq) is a strong base. If 100.0 mg of...Ch. 22 - The conversion of O2(g) to O2(g) can be...Ch. 22 - Prob. 36ECh. 22 - Prob. 37ECh. 22 - Prob. 38ECh. 22 - Prob. 39ECh. 22 - Prob. 40ECh. 22 - Prob. 41ECh. 22 - Joseph Priestley, e British chemist, was credited...Ch. 22 - Give an appropriate name to each of theb following...Ch. 22 - Prob. 44ECh. 22 - Give a specific example of a chemical equation...Ch. 22 - Prob. 46ECh. 22 - Prob. 47ECh. 22 - Prob. 48ECh. 22 - Prob. 49ECh. 22 - Prob. 50ECh. 22 - Prob. 51ECh. 22 - Prob. 52ECh. 22 - Prob. 53ECh. 22 - Prob. 54ECh. 22 - Prob. 55ECh. 22 - Prob. 56ECh. 22 - Prob. 57ECh. 22 - Prob. 58ECh. 22 - Prob. 59ECh. 22 - One reaction that competes with reaction (22.41),...Ch. 22 - Prob. 61ECh. 22 - Prob. 62ECh. 22 - Draw plausible Lewis structures for a....Ch. 22 - Both nitramide and hyponitrous acid have the...Ch. 22 - Prob. 65ECh. 22 - Prob. 66ECh. 22 - Prob. 67ECh. 22 - Prob. 68ECh. 22 - Prob. 69ECh. 22 - Prob. 70ECh. 22 - Use data from Table 7.2 (page 273) to calculate...Ch. 22 - Prob. 72ECh. 22 - Prob. 73ECh. 22 - Prob. 74ECh. 22 - Prob. 75ECh. 22 - What volume of H2(g) at 25C and 752 mmHg is...Ch. 22 - Prob. 77ECh. 22 - How many grams of CaH2(s) are required to generate...Ch. 22 - Prob. 79ECh. 22 - On the basis of molecular orbital theory, would...Ch. 22 - Prob. 81IAECh. 22 - Prob. 82IAECh. 22 - Prob. 83IAECh. 22 - The photograph was taken after a few drops of a...Ch. 22 - Prob. 85IAECh. 22 - Prob. 86IAECh. 22 - Prob. 87IAECh. 22 - Despite the fact that it has the higher molecular...Ch. 22 - The text mentions that ammonium perchlorate is an...Ch. 22 - Prob. 90IAECh. 22 - Prob. 91IAECh. 22 - Prob. 92IAECh. 22 - Refer to Figure 11-25 to arrange the following...Ch. 22 - Prob. 94IAECh. 22 - Prob. 95IAECh. 22 - Estimate the percent dissociation of CI2(g) into...Ch. 22 - Prob. 97IAECh. 22 - The structure of N(SiH2)2 involves a planar...Ch. 22 - Prob. 99IAECh. 22 - Refer to the Integrative Example on page 1082....Ch. 22 - The bond energies of CIz and 159kJmol1 are 243 and...Ch. 22 - Prob. 102IAECh. 22 - Prob. 103IAECh. 22 - Prob. 104IAECh. 22 - Prob. 105IAECh. 22 - The heavier halogens (CI, Br, and I) form...Ch. 22 - Prob. 107IAECh. 22 - Chemists have successfully synthesized the ionic...Ch. 22 - Prob. 109IAECh. 22 - Various thermochemical cycles are being explored...Ch. 22 - The decomposition of aqueous hydrogen peroxide is...Ch. 22 - Both in this chapter and in Chapter 19, we have...Ch. 22 - Prob. 113FPCh. 22 - The so-called pyroanions, X2O7n+ , form a series...Ch. 22 - A description of bonding in XeF2 based on the...Ch. 22 - Prob. 116FPCh. 22 - Prob. 117SAECh. 22 - Prob. 118SAECh. 22 - Prob. 119SAECh. 22 - Which of the following can oxidize Br to Br2 in...Ch. 22 - Prob. 121SAECh. 22 - Prob. 122SAECh. 22 - Prob. 123SAECh. 22 - Prob. 124SAECh. 22 - Prob. 125SAECh. 22 - Prob. 126SAECh. 22 - Prob. 127SAECh. 22 - Give a practical laboratory method that you might...Ch. 22 - Prob. 129SAECh. 22 - Prob. 130SAECh. 22 - Prob. 131SAECh. 22 - Prob. 132SAECh. 22 - Prob. 133SAECh. 22 - Prob. 134SAECh. 22 - Prob. 135SAE
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- V There are two steps in the usual industrial preparation of acrylic acid, the immediate precursor of several useful plastics. In the first step, calcium carbide water react to form acetylene and calcium hydroxide: CaC₂(s) + 2 H₂O(g) → C₂H₂(9) + Ca(OH)₂(s) In the second step, acetylene, carbon dioxide and water react to form acrylic acid: 6C₂H₂(g) + 3 CO₂(g) + 4H₂O(g) → 5 CH₂CHCO₂(g) Calculate the net change in enthalpy for the formation of one mole of acrylic acid from calcium carbide, water and carbon dioxide from these reactions. Round your answer to the nearest kJ. 0 kJ esc Explar Explanation Check X ΔΗ= -414. kJ > Costa ΔΗ=132. kJ MacBook Pro © 2022 McGraw Hill LLC. All Rights Reserved. You Terms of Use | Privacy Center |arrow_forwardReview Chemical reactions and Balancing Equations Complete and balanced the following reactions and state the type of reaction. (a) sodium + water → (b) magnesium chloride + ammonium hydroxide → (c) carbon + oxygen → (d) zinc + iron (II) sulfate → (e) sulfuric acid + calcium carbonate → (f) gold + copper (1I) chloride → (g) ammonium chloride + barium hydroxide → (h) butane + oxygen → (i) sodium sulfite + nitric acid → G) potassium carbonate → (k) beryllium chlorate → (1) magnesium + sulfuric acid > (m) lead (II) nitrate + potassium iodide → (n) sodium hydroxide + nitric acid →arrow_forwardThere are two steps in the usual industrial preparation of acrylic acid, the immediate precursor of several useful plastics. In the first step, calcium carbide and water react to form acetylene and calcium hydroxide: CaC₂(s) + 2 H₂O(g) → C₂H₂(g) + Ca(OH)₂(s) In the second step, acetylene, carbon dioxide and water react to form acrylic acid: 6C₂H₂(g) + 3 CO₂(g) + 4H₂O(g) → 5 CH₂CHCO,H(g) Explanation Taipy Check Calculate the net change in enthalpy for the formation of one mole of acrylic acid from calcium carbide, water and carbon dioxide from these reactions. Round your answer to the nearest kJ. X ΔΗ= -414. kJ S ΔΗ= 132. kJ MacBook Air + © 2023 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Aarrow_forward
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