Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 21, Problem 33PS
Interpretation Introduction

Interpretation: To predict the calcium compound among the following that does not dissolve in hydrochloric acid.

Concept introduction: Calcium is one of the most abundant elements found on earth. It is an alkaline earth metal and belongs to group 2A of the periodic table. Its compounds have high melting point. Calcium occurs in various minerals that are found on earth’s surface. Some common minerals are limestone, dolomite, slaked lime, gypsum and chalk.

Calcium Oxide is quick lime and is a white, amorphous solid. Calcium hydroxide is known as slaked lime. Both are slightly soluble in water and dissolve in acids. Calcium carbonate is present in limestone and chalk. The hydrated calcium sulfate is known as gypsum. Cement also contains calcium. Hydroxyapatite is also a type of calcium compound found in tooth enamel.

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Name the products formed in each case when(a) hydrochloric acid reacts with caustic soda.(b) granulated zinc reacts with caustic soda.(c) carbon dioxide is passed into lime water.
Uranium can be isolated from its ores by dissolving it as UO2(NO3)2, then separating it as solid UO2(C2O4)·3H2O. Addition of 0.4031 g of sodium oxalate, Na2C2O4, to a solution containing 1.481 g of uranyl nitrate, UO2(NO3)2, yields 1.073 g of solid UO2(C2O4)·3H2O. Na2C2O4 + UO2(NO3)2 + 3H2O ⟶ UO2(C2O4)·3H2O + 2NaNO3 Determine the limiting reactant and the percent yield of this reaction.
b. (i) (ii) A green solid has the empirical formula FeBr3·5NH3 H₂O. Upon reaction with an excess of aqueous AgNO3 it is found that 1 mole of the solid precipitates 3 moles of AgBr. Heating the green solid leads to loss of 1 mole of H₂O to yield a blue solid with the same ratio of Fe:Br:NH3 as found in the green solid. The reaction of 1 mole of the blue solid with excess of aqueous AgNO3 produces 2 moles of AgBr. Draw and name the octahedral green and blue complexes. An octahedral complex having the formula [M(dien)(NH3)(OH₂)F] has a total of 15 isomers. In the sum formula "dien" represents the tridentate diethylenetriamine ligand, which can adopt meridional or facial coordination modes. Draw structures of 8 possible isomers, clearly showing any pairs of enantiomers. The tridentante ligand may be abbreviated as below for simplicity. H₂N : = ΝΗ NH :NH2 N diethylenetriamine (dien) N N

Chapter 21 Solutions

Chemistry & Chemical Reactivity

Ch. 21.11 - The best catalysts used to accelerate the...Ch. 21.11 - Prob. 2.5ACPCh. 21 - Which of the following formulas is incorrect? (a)...Ch. 21 - The reaction of elemental phosphorus and excess...Ch. 21 - Like sulfur, selenium forms compounds in several...Ch. 21 - Prob. 4PSCh. 21 - Give examples of two basic oxides. Write equations...Ch. 21 - Prob. 6PSCh. 21 - Prob. 7PSCh. 21 - Prob. 8PSCh. 21 - Prob. 9PSCh. 21 - Prob. 10PSCh. 21 - For the product of the reaction you selected in...Ch. 21 - For the product of the reaction you selected in...Ch. 21 - Prob. 13PSCh. 21 - Prob. 14PSCh. 21 - Place the following oxides in order of increasing...Ch. 21 - Place the following oxides in order of increasing...Ch. 21 - Prob. 17PSCh. 21 - Prob. 18PSCh. 21 - Prob. 19PSCh. 21 - Prob. 20PSCh. 21 - Prob. 21PSCh. 21 - Prob. 22PSCh. 21 - Prob. 23PSCh. 21 - Prob. 24PSCh. 21 - Prob. 25PSCh. 21 - Prob. 26PSCh. 21 - Prob. 27PSCh. 21 - The compound Na2O2 consists of (a) two Na+ ions...Ch. 21 - Prob. 29PSCh. 21 - Write balanced equations for the reaction of...Ch. 21 - Prob. 31PSCh. 21 - (a) Write equations for the half-reactions that...Ch. 21 - Prob. 33PSCh. 21 - Prob. 34PSCh. 21 - When magnesium bums in air, it forms both an oxide...Ch. 21 - Prob. 36PSCh. 21 - Prob. 37PSCh. 21 - Prob. 38PSCh. 21 - Calcium oxide, CaO, is used to remove SO2 from...Ch. 21 - Prob. 40PSCh. 21 - Prob. 41PSCh. 21 - The element below aluminum in Group 3A is gallium,...Ch. 21 - Prob. 43PSCh. 21 - The boron trihalides (except BF3) hydrolyze...Ch. 21 - When boron hydrides burn in air, the reactions are...Ch. 21 - Prob. 46PSCh. 21 - Write balanced equations for the reactions of...Ch. 21 - Prob. 48PSCh. 21 - Prob. 49PSCh. 21 - Alumina, Al2O3, is amphoteric. Among examples of...Ch. 21 - Prob. 51PSCh. 21 - Prob. 52PSCh. 21 - Prob. 53PSCh. 21 - Silicon and oxygen form a six-membered ring in the...Ch. 21 - Describe the structure of pyroxenes (see page...Ch. 21 - Describe how ultrapure silicon can be produced...Ch. 21 - Prob. 57PSCh. 21 - Prob. 58PSCh. 21 - Prob. 59PSCh. 21 - Prob. 60PSCh. 21 - Prob. 61PSCh. 21 - Prob. 62PSCh. 21 - Prob. 63PSCh. 21 - The overall reaction involved in the industrial...Ch. 21 - Prob. 65PSCh. 21 - Prob. 66PSCh. 21 - Prob. 67PSCh. 21 - Prob. 68PSCh. 21 - Prob. 69PSCh. 21 - Which statement about oxygen is not true? (a)...Ch. 21 - Prob. 71PSCh. 21 - Prob. 72PSCh. 21 - Prob. 73PSCh. 21 - Sulfur forms a range of compounds with fluorine....Ch. 21 - Prob. 75PSCh. 21 - Which of the following statements is not correct?...Ch. 21 - The halogen oxides and oxoanions are good...Ch. 21 - Prob. 78PSCh. 21 - Bromine is obtained from brine wells. The process...Ch. 21 - Prob. 80PSCh. 21 - Prob. 81PSCh. 21 - Halogens combine with one another to produce...Ch. 21 - Prob. 83PSCh. 21 - Prob. 84PSCh. 21 - The standard enthalpy of formation of XeF4 is 218...Ch. 21 - Draw the Lewis electron dot structure for XeO3F2....Ch. 21 - Prob. 87PSCh. 21 - Prob. 88PSCh. 21 - Prob. 89GQCh. 21 - Prob. 90GQCh. 21 - Consider the chemistries of the elements...Ch. 21 - When BCl3 gas is passed through an electric...Ch. 21 - Prob. 93GQCh. 21 - Prob. 94GQCh. 21 - Prob. 95GQCh. 21 - Prob. 96GQCh. 21 - Prob. 97GQCh. 21 - Prob. 98GQCh. 21 - Prob. 99GQCh. 21 - Prob. 100GQCh. 21 - Prob. 101GQCh. 21 - Prob. 102GQCh. 21 - Prob. 103GQCh. 21 - Prob. 105GQCh. 21 - Prob. 106GQCh. 21 - A Boron and hydrogen form an extensive family of...Ch. 21 - In 1774, C. Scheele obtained a gas by reacting...Ch. 21 - The chemistry of gallium: (a) Gallium hydroxide,...Ch. 21 - Prob. 111GQCh. 21 - Prob. 112GQCh. 21 - Prob. 113GQCh. 21 - Prob. 114GQCh. 21 - Prob. 115ILCh. 21 - Prob. 116ILCh. 21 - Prob. 117ILCh. 21 - Prob. 118ILCh. 21 - Prob. 119ILCh. 21 - Prob. 120ILCh. 21 - Prob. 121SCQCh. 21 - Prob. 122SCQCh. 21 - Prob. 123SCQCh. 21 - Prob. 124SCQCh. 21 - Prob. 125SCQCh. 21 - Prob. 126SCQCh. 21 - Prob. 127SCQCh. 21 - Prob. 128SCQCh. 21 - Comparing the chemistry of carbon and silicon. (a)...Ch. 21 - Prob. 130SCQCh. 21 - Xenon trioxide, XeO3, reacts with aqueous base to...
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