Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 21, Problem 111GQ
Interpretation Introduction
Interpretation: To draw the structure of anion
Concept introduction: The anion is
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Part A)
Draw the Lewis dot structure for SiO44−. Use square brackets to denote the overall charge.
Part B)
Draw the Lewis dot structures for two connected SiO4 tetrahedra. (Hint: Look at it as O3Si−O−SiO3^6−.)
Which of the following statements are true?(a) Both nitrogen and phosphorus can form a pentafluoridecompound.(b) Although CO is a well-known compound, SiO does notexist under ordinary conditions.(c) Cl2 is easier to oxidize than I2.(d) At room temperature, the stable form of oxygen is O2,whereas that of sulfur is S8.
Nitrogen is found in nature as N2(g). Would you expect phosphorus to be found innature as P2(g)? Explain.
Chapter 21 Solutions
Chemistry & Chemical Reactivity
Ch. 21.2 - Prob. 21.1CYUCh. 21.2 - Write the formula for each of the following (a)...Ch. 21.2 - Prob. 21.3CYUCh. 21.2 - Prob. 21.4CYUCh. 21.11 - Prob. 1.1ACPCh. 21.11 - Prob. 1.2ACPCh. 21.11 - Prob. 1.3ACPCh. 21.11 - Draw the Lewis structure of ammonia borane. What...Ch. 21.11 - Calculate the mass of hydrogen in 1.00 kg of...Ch. 21.11 - What is the hydrogen density (mass H2 per liter)...
Ch. 21.11 - The best catalysts used to accelerate the...Ch. 21.11 - Prob. 2.5ACPCh. 21 - Which of the following formulas is incorrect? (a)...Ch. 21 - The reaction of elemental phosphorus and excess...Ch. 21 - Like sulfur, selenium forms compounds in several...Ch. 21 - Prob. 4PSCh. 21 - Give examples of two basic oxides. Write equations...Ch. 21 - Prob. 6PSCh. 21 - Prob. 7PSCh. 21 - Prob. 8PSCh. 21 - Prob. 9PSCh. 21 - Prob. 10PSCh. 21 - For the product of the reaction you selected in...Ch. 21 - For the product of the reaction you selected in...Ch. 21 - Prob. 13PSCh. 21 - Prob. 14PSCh. 21 - Place the following oxides in order of increasing...Ch. 21 - Place the following oxides in order of increasing...Ch. 21 - Prob. 17PSCh. 21 - Prob. 18PSCh. 21 - Prob. 19PSCh. 21 - Prob. 20PSCh. 21 - Prob. 21PSCh. 21 - Prob. 22PSCh. 21 - Prob. 23PSCh. 21 - Prob. 24PSCh. 21 - Prob. 25PSCh. 21 - Prob. 26PSCh. 21 - Prob. 27PSCh. 21 - The compound Na2O2 consists of (a) two Na+ ions...Ch. 21 - Prob. 29PSCh. 21 - Write balanced equations for the reaction of...Ch. 21 - Prob. 31PSCh. 21 - (a) Write equations for the half-reactions that...Ch. 21 - Prob. 33PSCh. 21 - Prob. 34PSCh. 21 - When magnesium bums in air, it forms both an oxide...Ch. 21 - Prob. 36PSCh. 21 - Prob. 37PSCh. 21 - Prob. 38PSCh. 21 - Calcium oxide, CaO, is used to remove SO2 from...Ch. 21 - Prob. 40PSCh. 21 - Prob. 41PSCh. 21 - The element below aluminum in Group 3A is gallium,...Ch. 21 - Prob. 43PSCh. 21 - The boron trihalides (except BF3) hydrolyze...Ch. 21 - When boron hydrides burn in air, the reactions are...Ch. 21 - Prob. 46PSCh. 21 - Write balanced equations for the reactions of...Ch. 21 - Prob. 48PSCh. 21 - Prob. 49PSCh. 21 - Alumina, Al2O3, is amphoteric. Among examples of...Ch. 21 - Prob. 51PSCh. 21 - Prob. 52PSCh. 21 - Prob. 53PSCh. 21 - Silicon and oxygen form a six-membered ring in the...Ch. 21 - Describe the structure of pyroxenes (see page...Ch. 21 - Describe how ultrapure silicon can be produced...Ch. 21 - Prob. 57PSCh. 21 - Prob. 58PSCh. 21 - Prob. 59PSCh. 21 - Prob. 60PSCh. 21 - Prob. 61PSCh. 21 - Prob. 62PSCh. 21 - Prob. 63PSCh. 21 - The overall reaction involved in the industrial...Ch. 21 - Prob. 65PSCh. 21 - Prob. 66PSCh. 21 - Prob. 67PSCh. 21 - Prob. 68PSCh. 21 - Prob. 69PSCh. 21 - Which statement about oxygen is not true? (a)...Ch. 21 - Prob. 71PSCh. 21 - Prob. 72PSCh. 21 - Prob. 73PSCh. 21 - Sulfur forms a range of compounds with fluorine....Ch. 21 - Prob. 75PSCh. 21 - Which of the following statements is not correct?...Ch. 21 - The halogen oxides and oxoanions are good...Ch. 21 - Prob. 78PSCh. 21 - Bromine is obtained from brine wells. The process...Ch. 21 - Prob. 80PSCh. 21 - Prob. 81PSCh. 21 - Halogens combine with one another to produce...Ch. 21 - Prob. 83PSCh. 21 - Prob. 84PSCh. 21 - The standard enthalpy of formation of XeF4 is 218...Ch. 21 - Draw the Lewis electron dot structure for XeO3F2....Ch. 21 - Prob. 87PSCh. 21 - Prob. 88PSCh. 21 - Prob. 89GQCh. 21 - Prob. 90GQCh. 21 - Consider the chemistries of the elements...Ch. 21 - When BCl3 gas is passed through an electric...Ch. 21 - Prob. 93GQCh. 21 - Prob. 94GQCh. 21 - Prob. 95GQCh. 21 - Prob. 96GQCh. 21 - Prob. 97GQCh. 21 - Prob. 98GQCh. 21 - Prob. 99GQCh. 21 - Prob. 100GQCh. 21 - Prob. 101GQCh. 21 - Prob. 102GQCh. 21 - Prob. 103GQCh. 21 - Prob. 105GQCh. 21 - Prob. 106GQCh. 21 - A Boron and hydrogen form an extensive family of...Ch. 21 - In 1774, C. Scheele obtained a gas by reacting...Ch. 21 - The chemistry of gallium: (a) Gallium hydroxide,...Ch. 21 - Prob. 111GQCh. 21 - Prob. 112GQCh. 21 - Prob. 113GQCh. 21 - Prob. 114GQCh. 21 - Prob. 115ILCh. 21 - Prob. 116ILCh. 21 - Prob. 117ILCh. 21 - Prob. 118ILCh. 21 - Prob. 119ILCh. 21 - Prob. 120ILCh. 21 - Prob. 121SCQCh. 21 - Prob. 122SCQCh. 21 - Prob. 123SCQCh. 21 - Prob. 124SCQCh. 21 - Prob. 125SCQCh. 21 - Prob. 126SCQCh. 21 - Prob. 127SCQCh. 21 - Prob. 128SCQCh. 21 - Comparing the chemistry of carbon and silicon. (a)...Ch. 21 - Prob. 130SCQCh. 21 - Xenon trioxide, XeO3, reacts with aqueous base to...
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- Sodium perchlorate, NaClO4, is produced by electrolysis of sodium chlorate, NaClO3. If a current of 2.50 103 A passes through an electrolytic cell, how many kilograms of sodium perchlorate are produced per hour?arrow_forwardAlumina, Al2O3, is amphoteric. Among examples of its amphoteric character are the reactions that occur when Al2O3 is heated strongly or fused with acidic oxides and basic oxides. (a) Write a balanced equation for the reaction of alumina with silica, an acidic oxide, to give aluminum metasilicate, Al2(SiO3)3. (b) Write a balanced equation for the reaction of alumina with the basic oxide CaO to give calcium aluminate, Ca(AlO2)2.arrow_forward4.48 Elemental phosphorous is used in the semiconductor industry. It can be obtained from an ore called fluoroapatite via reaction with SiO2 and C: 4Ca5( PO4)3F+18SiO2+30C3P4+30CO+18CaSiO3+2CaF2 Suppose a particular semiconductor production plant requires 1500 kg of P4. If the recovery of P4 from this reaction is 73% efficient, what mass of fluoroapatite is needed?arrow_forward
- The amount of sodium hypochlorite in a bleach solution can be determined by using a given volume of bleach to oxidize excess iodide ion to iodine, because the reaction goes to completion. The amount of iodine produced is then determined by titration with sodium thiosulfate, Na2S2O3, which is oxidized to sodium tetrathionate, Na2S4O6. Potassium iodide was added in excess to 5.00 mL of bleach (density = 1.00 g/mL). This solution, containing the iodine released in the reaction, was titrated with 0.100 M Na2S2O3. If 34.6 mL of sodium thiosulfate was required to reach the endpoint (detected by disappearance of the blue color of the starch iodine complex), what was the mass percentage of NaClO in the bleach?arrow_forwardWhy does white phosphorus consist of tetrahedral P4 molecules while nitrogen consists of diatomic N2 molecules?arrow_forwardThe amount of sodium hypochlorite in a bleach solution can be determined by using a given volume of bleach to oxidize excess iodide ion to iodine; ClO- is reduced to Cl-. The amount of iodine produced by the redox reaction is determined by titration with sodium thiosulfate, Na2S2O3; I2 is reduced to I-. The sodium thiosulfate is oxidized to sodium tetrathionate, Na2S4O6. In this analysis, potassium iodide was added in excess to 5.00 mL of bleach (d=1.00g/cm3) . If 25.00 mL of 0.0700 M Na2S2O3 was required to reduce all the iodine produced by the bleach back to iodide, what is the mass percent of NaClO in the bleach?arrow_forward
- Silicon and oxygen form a six-membered ring in the silicate anion [Si3O9]6. What is the oxidation state of silicon in this anion? (The rare blue mineral benitoite, the California state gemstone, has the formula BaTiSi3O9.) (a) 0 (b) +2 (c) +4 (d) 4arrow_forwardWrite Lewis structures for NF3 and PP5. On the basis of hybrid orbitals, explain the fact that NF3, PP3, and PP5 are stable molecules, but NP5 does not exist.arrow_forwardDefine the term silicates?arrow_forward
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