A bottle at 325 K contains an ideal gas at a pressure of
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Thermodynamics, Statistical Thermodynamics, & Kinetics
- Which of the following quantities can be taken to be independent of temperature? independent of pressure? (a) H for a reaction (b) S for a reaction (c) G for a reaction (d) S for a substancearrow_forwardFor the reaction BaCO3(s) BaO(s) + CO2(g), rG = +219.7 kJ/mol-rxn. Using this value and other data available in Appendix L, calculate the value of fG for BaCO3(s).arrow_forwardUse the two appropriate values of R to determine a conversion between L. atm and J.arrow_forward
- What are the two ways that a final chemical state of a system can be more probable than its initial state?arrow_forwardBenzoic acid, C6H5COOH, is a common standard used in bomb calorimeters, which maintain a constant volume. If 1.20 g of benzoic acid gives off 31, 723 J of energy when burned in the presence of excess oxygen and in a water bath having a temperature of 24.6 C, calculate q, w, H, and U for the reaction.arrow_forwardUse the data in Table 2.2 to determine Hp T for Ar at 0C and 1atm. Make any reasonable assumptions necessary.arrow_forward
- Consider 2.00 moles of an ideal gas that are taken from state A (PA = 2.00 atm, vA = 10.0 L) to state B (PB = 1.00 attn, VB = 30.0 L) by two different pathways: These pathways are summarized on the following graph of P versus V: Calculate the work (in units of J) associated with the two pathways. Is work a state function? Explain.arrow_forwardCalculate the work for the isothermal, reversible compressionof 0.245 moleof an idealgas going from 1.000L to 1.00 mL if the temperature were 95.0C.arrow_forwardWhy is equation2.37 written interms of CV and Cp and not c-v and c-p ?arrow_forward
- Consider a 5 L sample of CO₂(g) in a container with a movable piston at a temperature of 25 °C and 5.0 atm pressure. The gas is expanded reversibly by decreasing the pressure to 2.0 atm. Compare the final volume and temperature of the gas if the process were carried out (a) adiabatically or (b) isothermally. A) Vf(adiabatic) = Vf(isothermal); Tf(adiabatic) = Tf(isothermal) B) Vf(adiabatic) > Vf(isothermal); Tf(adiabatic) > Tf(isothermal) C) Vf(adiabatic) Vf(isothermal); Tf(adiabatic) Tf(isothermal)arrow_forward5. One mole of a monatomic ideal gas is compressed adiabatically in a single stage with a constant opposing pressure equal to 10 atm. Initially the gas is at 27 °C and 1 atm pressure, the final pressure is 10 atm. How would the various quantities be affected if n moles were used instead of one mole? For a monatomic ideal gas. C₂ = Cv R. 2arrow_forward1. A chemical reaction takes place in a container fitted with a piston of cross-sectional area 75.0 cm2 . As a result of the reaction, the piston is pushed out through 25.0 cm against an external pressure of 150 kPa. Calculate the work done by the system.arrow_forward
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