Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 15, Problem 15.48AP
What hydrolysis products are formed when each wax is treated with aqueous sulfuric acid?
- a. CH3(CH2)18COO(CH2)29CH3
- b. CH3(CH2)24COO(CH2)23CH3
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Draw the products formed when α-D-gulose is treated with each reagent.
a. CH3I, Ag2O
b. CH3OH, HCl
c. Ac2O, pyridine
d. The product in (a), then H3O+
e. The product in (b), then Ac2O, pyridine
f. The product in (d), then C6H5CH2Cl, Ag2O
Draw the product formed when pentanal (CH3CH2CH2CH2CHO) is treated with each reagent. With some reagents, no reaction occurs.
Determine the product formed when butanone (CH3CH,COCH3) Is treated with each reagent. If no reaction occurs, label the reaction
with "no reaction".
PCC
H2
Pd-C
HO OH
NazCr,O,
H,SO.H,O
[1] LIAIH,
[2] H,O
no reaction
Ag20
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CH;OH
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Chapter 15 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 15.1 - In which solvents or solutions will a lipid be...Ch. 15.2 - (a) Draw a skeletal structure for each fatty acid....Ch. 15.2 - Prob. 15.3PCh. 15.2 - Prob. 15.4PCh. 15.3 - Draw the structure of a wax formed from stearic...Ch. 15.3 - One component of jojoba oil is a wax formed from...Ch. 15.3 - What hydrolysis products are formed when cetyl...Ch. 15.4 - Draw the structure of a triacylglycerol that...Ch. 15.4 - Prob. 15.9PCh. 15.4 - Draw the structure of a triacylglycerol that fits...
Ch. 15.5 - Draw the products formed from hydrolysis of each...Ch. 15.5 - Prob. 15.12PCh. 15.6 - Draw the structure of two different cephalins...Ch. 15.6 - Classify each lipid as a triacylglycerol,...Ch. 15.7 - Why are phospholipids rather than triacylglycerols...Ch. 15.7 - Prob. 15.16PCh. 15.8 - Prob. 15.17PCh. 15.8 - Prob. 15.18PCh. 15.9 - Prob. 15.19PCh. 15.9 - Prob. 15.20PCh. 15.10 - Why is it much easier to overdose on a fat-soluble...Ch. 15.10 - Prob. 15.22PCh. 15 - Prob. 15.23UKCCh. 15 - Prob. 15.24UKCCh. 15 - Prob. 15.25UKCCh. 15 - What hydrolysis products are formed when the wax...Ch. 15 - Prob. 15.27UKCCh. 15 - Prob. 15.28UKCCh. 15 - Draw the products formed when the given...Ch. 15 - Prob. 15.30UKCCh. 15 - Prob. 15.31UKCCh. 15 - Prob. 15.32UKCCh. 15 - Prob. 15.33APCh. 15 - Label each compound as a hydrolyzable or...Ch. 15 - Prob. 15.35APCh. 15 - Prob. 15.36APCh. 15 - Prob. 15.37APCh. 15 - How does each of the following affect the melting...Ch. 15 - Rank the fatty acids in order of increasing...Ch. 15 - How would you expect the melting points of the...Ch. 15 - Prob. 15.41APCh. 15 - Why are soaps water soluble, but the fatty acids...Ch. 15 - Draw the structure of a wax formed from palmitic...Ch. 15 - Prob. 15.44APCh. 15 - Prob. 15.45APCh. 15 - Prob. 15.46APCh. 15 - Prob. 15.47APCh. 15 - What hydrolysis products are formed when each wax...Ch. 15 - Draw a triacylglycerol that fits each description:...Ch. 15 - Draw a triacylglycerol that fits each description:...Ch. 15 - Prob. 15.51APCh. 15 - Prob. 15.52APCh. 15 - Prob. 15.53APCh. 15 - Prob. 15.54APCh. 15 - Prob. 15.55APCh. 15 - Draw the products formed when the given...Ch. 15 - Prob. 15.57APCh. 15 - Prob. 15.58APCh. 15 - Prob. 15.59APCh. 15 - Prob. 15.60APCh. 15 - Prob. 15.61APCh. 15 - Why are LDLs soluble in the blood?Ch. 15 - Describe the role of HDLs and LDLs in cholesterol...Ch. 15 - Prob. 15.64APCh. 15 - Prob. 15.65APCh. 15 - Prob. 15.66APCh. 15 - Answer each question with regards to vitamins A...Ch. 15 - Answer each question in Problem 15.67 for vitamins...Ch. 15 - Prob. 15.69APCh. 15 - Prob. 15.70APCh. 15 - Prob. 15.71APCh. 15 - How are soaps and phosphoacylglycerols similar in...Ch. 15 - Some fish oils contain triacylglycerols formed...Ch. 15 - Some marine plankton contain triacylglycerols...Ch. 15 - Prob. 15.75APCh. 15 - Prob. 15.76APCh. 15 - Prob. 15.77APCh. 15 - Prob. 15.78APCh. 15 - Prob. 15.79CPCh. 15 - Prob. 15.80CP
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Draw the products formed when a-D-gulose is treated with each reagent. a. CH3I, Ag,0 b. CH,OH, HCI c. CeHsCH2CI, Ag20 d. CgHsCH2OH, HCI e. Ac20, pyridine f. CeHsCOCI, pyridine g. The product in (a), then H3O* h. The product in (b), then Ac,0, pyridine i. The product in (g), then CeHsCH2CI, Ag20 j. The product in (d), then CH3I, Ag20 но OH но OH OH D-gulosearrow_forwardWhat product is formed when D-Gulose is treated with a. CH3I, Ag2O b. The product in (a), then H3O+ c. The product in (b), then C6H5CH2Cl, Ag2Oarrow_forward1. Draw the product formed when 2-heptanone (CH3COCH2CH2CH2CH2CH3) is treated with each reagent:arrow_forward
- 6. Draw the structures of the products A, B, C and D. OH N2OH TSCI (S,2) B Pyridine (R)-2-Butanol TSCI LICI D Pyridine *OHarrow_forwardReactions of Triglycerides 12, CI4 CH2-0-C-(CH2)7-CH=CH(CH2),CH3 На, Pt ou CH-O-C-(CH2)16CH3 3 NaOH CH2-0-C-(CH2)14CH3 H30*arrow_forwardDraw the product formed when pentanal (CH3 CH₂ CH₂ CH₂ CHO) is treated with each reagent. With some reagents, no reaction occurs. a. NaBH4, CH3OH b. [1] LiAiH4: [2] H₂O c. H₂, Pd-C d. PCC e. Na₂Cr₂O7, H₂SO4, H₂O f. Ag₂O, NH4OH g. [1] CH3 MgBr; [2] H₂O h. [1] C6H5 Li: [2] H₂O i. [1] (CH3)2 CuLi; [2] H₂O J. [1] HC=CNa; [2] H₂O k. [1] CH 3 C=CLI; [2] H₂O 1. The product in (a), then TBDMS-CI, imidazolearrow_forward
- Identify and label hemiacetal, acetal, hemiketal and ketal functional groups in the following molecules HO но. H. он он ÓH H. ÓH он но. CH2 .C H H. C OH ÓH но, CH2 OH OH HO, ÓHarrow_forward4. Number these in order of ease of hydrolysis. 1 = easiest to hydrolyze, 4 = hardest to hydrolyze. C.H.&CI C6H5CNHC(CH3)3 CH₂C=NCHCOCHarrow_forwardDraw the product formed when pentanal (CH;CH,CH2CH;CHO) is treated with each reagent. With some reagents, no reaction occurs. a. NaBH4, CH,OH b. [1] LIAIH4; (2] H20 c. H2, Pd-C d. PCC e. NazCr,07, H2SO4, H2O f. Ag,0, NH,OH g. [1) CH,MgBr; (2] H2O h. [1] CęH,Li; [2] H20 i. [1] (CH3),CuLi; (2] H2O j. [1] HC=CNa; [2] H2O k. [1] CH;C=CLi; [2] H2O I. The product in (a), then TBDMS-CI, imidazolearrow_forward
- 18. Identify each of the following compounds as hemiacetal or он a. CH3 acetal: b. EXCH₂ CH3 C- FOCH OCHS d. QH CH3 CH₂CCH3 OCH₂CH3arrow_forwardMacmillan Learning Name each compound. A. CH₂CH3 CH₂CH3arrow_forward11. What reagent can be used to convert 2-methylbutan-1-ol into 2-methylbutanal? A) Bleach B) LIAIH4 C) DMSO, (COCI)2, TEA D) Na,Cr₂O, H₂SO. E) 0₂arrow_forward
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