Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 12.2, Problem 2P
Write the steps for formation of tetrachloromethane (CCl4) from the reaction of methane with Cl2 + hv.
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Write the steps for formation of tetrachloromethane (CCl4) from the reaction of methane with Cl2 + hn.
Write the steps for formation of tetrachloromethane (CCl4) from the reaction of methane with Cl2 + hv.
Write a balanced chemical reaction for the incomplete combustion of pentane, C5H12C5H12 in oxygen gas to form carbon monoxide gas as one of the products.
Chapter 12 Solutions
Organic Chemistry (8th Edition)
Ch. 12.2 - Prob. 1PCh. 12.2 - Write the steps for formation of...Ch. 12.3 - Prob. 3PCh. 12.4 - How many alkyl chlorides are obtained from...Ch. 12.4 - Prob. 6PCh. 12.5 - Prob. 8PCh. 12.5 - a. Would chlorination or bromination produce a...Ch. 12.5 - Show how the following compounds could be prepared...Ch. 12.6 - Prob. 12PCh. 12.7 - Prob. 13P
Ch. 12.7 - Prob. 14PCh. 12.8 - Prob. 15PCh. 12.8 - Draw the stereoisomers of the major...Ch. 12.9 - Prob. 18PCh. 12.9 - How many allylic substituted bromoalkenes are...Ch. 12.9 - a. How many stereoisomers are formed from the...Ch. 12.9 - Prob. 21PCh. 12.9 - Prob. 22PCh. 12.10 - Prob. 23PCh. 12.11 - How many atoms share the unpaired electrons in...Ch. 12.11 - Prob. 25PCh. 12 - Prob. 26PCh. 12 - Prob. 27PCh. 12 - Prob. 28PCh. 12 - Prob. 29PCh. 12 - Prob. 30PCh. 12 - Prob. 31PCh. 12 - Prob. 32PCh. 12 - Prob. 33PCh. 12 - Prob. 34PCh. 12 - Prob. 35PCh. 12 - Prob. 36PCh. 12 - Prob. 37PCh. 12 - a. What five-carbon alkene forms the same product...Ch. 12 - Prob. 39PCh. 12 - Starting with cyclohexane, how could the following...Ch. 12 - a. Propose a mechanism for the following reaction:...Ch. 12 - What stereoisomers are obtained from the following...Ch. 12 - Prob. 43PCh. 12 - Prob. 44PCh. 12 - Prob. 45PCh. 12 - Draw the products of the following reactions,...Ch. 12 - Prob. 47PCh. 12 - Prob. 48PCh. 12 - Prob. 49PCh. 12 - Explain why the rate of bromination of methane...Ch. 12 - Prob. 51PCh. 12 - Prob. 1PCh. 12 - Prob. 2PCh. 12 - Prob. 3PCh. 12 - Prob. 4P
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- Write a balanced chemical equation for the reaction of ethene with oxygen. O a. C2H4(g) + 302(g) → 2CO2(g) + 2H2O(g) O b. 2C2H2(g) + 502(g) → 4CO2(g) + 2H2O(g) O c. CH4(g) + 2O2(g) → CO2(g) + 2H2O(g) O d. C2H4(g) + 202(g) → 2CO2(g) + 2H2(g) O e. 2C2H6(g) + 702(g) →> 4CO2(g) + 6H2O(g)arrow_forwardPropane, C3H8, is a hydrocarbon that is commonly used as a fuel.(a) Write a balanced equation for the complete combustion of propane gas.(b) Calculate the volume of air at 25 °C and 1.00 atmosphere that is needed to completely combust 25.0 grams of propane. Assume that air is 21.0 percent O2 by volume. (Hint:use the information that 1.00 L of air at 25 °C and 1.00 atm contains 0.275 g of O2 per liter.)(c) The heat of combustion of propane is −2,219.2 kJ/mol. Calculate the heat of formation, ΔH°f of propane given that ΔH°f of H2O(l) = −285.8 kJ/mol and ΔH°f of CO2(g) = −393.5 kJ/mol. (d) Assuming that all of the heat released in burning 25.0 grams of propane is transferred to 4.00 kilograms of water, calculate the increase in temperature of the water.arrow_forwardA student adds bromine solution to a test tube containing an isomer of C3H6. After shaking the sample and exposing it to UV light, the student observes that the colour of the bromine solution changes from orange to clear. Provide a hypothesis for what happened in the test tube. What do you believe to be the structure of the original isomer, and what was the final product, if a reaction occurred?arrow_forward
- Ethanol, C₂H60, is most often blended with gasoline - usually as a 10 percent mix - to create a fuel called gasohol. Ethanol is a renewable resource and ethanol-blended fuels, like gasohol, appear to burn more efficiently in combustion engines. The combustion of one mole of ethanol releases 326.7 kcal of energy. The combustion of one mole of 2-methylheptane, C8H18, releases 1.306 × 10³ kcal of energy. How much energy is released during the complete combustion of 405 grams of 2- methylheptane? kcal Assuming the same efficiency, would 405 grams of ethanol provide more, less, or the same amount of energy as 405 grams of 2-methylheptane? more less the same amount Retry Entire Group 9 more group attempts remainingarrow_forwardWrite the equation for the oxidation of pentane (C5H12). What is the sum of the coefficients for the reactants and products?arrow_forwardExplain the reaction between Methyl Salicylate with acetyl chloride (CH3COCl). Gives your answer in detail from the name of the reaction until the formation of the product. You are advised to give an illustration of the reaction.arrow_forward
- How many kilograms of CO2 are produced by the complete combustion of 3.8 kg of n-octane?arrow_forwardWrite a balanced chemical equation, including states of matter, for the combustion of ethylene gas, C2H4.arrow_forwardConsider the hydrotreating of this organic substance:H2NCH2CSCH2COOH +___ H2(g) → (a) Complete a balanced chemical equation to producethe most common hydrogen compounds of N, S, andO and a saturated hydrocarbon.(b) Why is more hydrotreating needed after coking thanafter hydrocracking?arrow_forward
- Write the balanced equation for the reaction that occurs when methanol, CH3OH(l ), is burned in air.arrow_forwardA 2.250 g sample of a dicarboxylic acid was burned in an excess of oxygen and yielded 4.548 g CO2 and 1.629 g H2O In a separate experiment, the molecular mass of the acid was found to be 174 g/mol. From these data, what is the structural formula of this acid?arrow_forwardThe combustion of isoctane reaction produces -5099.5 kJ of heat per mole of C8H18 (g) consumed, under standard conditions. The enthalpy of formation (DHf) for CO2(g) and H2O (g) are -393.5 kJ/mol and -241.8 kJ/mol, respectively. Find the standard enthalpy of formation (DHf) of this isomer of C8H18 (g)? (Show work) C8H18 (g) + O2(g) -> 8CO2(g) + 9H2O(g) DHrxn = -5099.5 kJarrow_forward
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