Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 12.2, Problem 2P
Write the steps for formation of tetrachloromethane (CCl4) from the reaction of methane with Cl2 + hv.
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1. Calculate the mass (g, four significant figures) of CO2 generated from the combustion of 200 g ethane
(C2H6), assuming ethane reacts with O2 to form CO2 and H2O.
Write the balanced equation for the combustion of ethane, C2H6
Under certain conditions water reacts with alkenes to form alcohols.Calculate the mass of ethanol (molar mass = 46.0 g/mol) produced when starting with 596.4 g of ethene (molar mass = 28.0 g/mol), assuming that the reaction goes to completion.Give your answer to three significant figures.C2H4 + H2O → CH3CH2OH
Chapter 12 Solutions
Organic Chemistry (8th Edition)
Ch. 12.2 - Prob. 1PCh. 12.2 - Write the steps for formation of...Ch. 12.3 - Prob. 3PCh. 12.4 - How many alkyl chlorides are obtained from...Ch. 12.4 - Prob. 6PCh. 12.5 - Prob. 8PCh. 12.5 - a. Would chlorination or bromination produce a...Ch. 12.5 - Show how the following compounds could be prepared...Ch. 12.6 - Prob. 12PCh. 12.7 - Prob. 13P
Ch. 12.7 - Prob. 14PCh. 12.8 - Prob. 15PCh. 12.8 - Draw the stereoisomers of the major...Ch. 12.9 - Prob. 18PCh. 12.9 - How many allylic substituted bromoalkenes are...Ch. 12.9 - a. How many stereoisomers are formed from the...Ch. 12.9 - Prob. 21PCh. 12.9 - Prob. 22PCh. 12.10 - Prob. 23PCh. 12.11 - How many atoms share the unpaired electrons in...Ch. 12.11 - Prob. 25PCh. 12 - Prob. 26PCh. 12 - Prob. 27PCh. 12 - Prob. 28PCh. 12 - Prob. 29PCh. 12 - Prob. 30PCh. 12 - Prob. 31PCh. 12 - Prob. 32PCh. 12 - Prob. 33PCh. 12 - Prob. 34PCh. 12 - Prob. 35PCh. 12 - Prob. 36PCh. 12 - Prob. 37PCh. 12 - a. What five-carbon alkene forms the same product...Ch. 12 - Prob. 39PCh. 12 - Starting with cyclohexane, how could the following...Ch. 12 - a. Propose a mechanism for the following reaction:...Ch. 12 - What stereoisomers are obtained from the following...Ch. 12 - Prob. 43PCh. 12 - Prob. 44PCh. 12 - Prob. 45PCh. 12 - Draw the products of the following reactions,...Ch. 12 - Prob. 47PCh. 12 - Prob. 48PCh. 12 - Prob. 49PCh. 12 - Explain why the rate of bromination of methane...Ch. 12 - Prob. 51PCh. 12 - Prob. 1PCh. 12 - Prob. 2PCh. 12 - Prob. 3PCh. 12 - Prob. 4P
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- Write a balanced chemical reaction for the incomplete combustion of pentane, C5H12C5H12 in oxygen gas to form carbon monoxide gas as one of the products.arrow_forwardWrite a balanced equation to show the reaction of gaseous ethane with gaseous oxygen to form carbon monoxide gas and water vapor. C2H6(g)+7 O(g) → 2 CO2(g)+3 H2O(g)C2H6(g)+7 O(g) → 2 CO2(g)+3 H2O(g) C2H6(g)+5 O(g) → 2 CO(g)+3 H2O(g)C2H6(g)+5 O(g) → 2 CO(g)+3 H2O(g) 2 C2H6(g)+7 O2(g) → 4 CO2(g)+6 H2O(g)2 C2H6(g)+7 O2(g) → 4 CO2(g)+6 H2O(g) 2 C2H6(g)+5 O2(g) → 4 CO(g)+6 H2O(g)2 C2H6(g)+5 O2(g) → 4 CO(g)+6 H2O(g) 2 CH3(g)+5 O(g) → 2 CO(g)+3 H2O(g)2 CH3(g)+5 O(g) → 2 CO(g)+3 H2O(g)arrow_forward(a) When the metallic element sodium combines with the nonmetallic element bromine, Br2(l), how can you determine the chemical formula of the product? How do you know whether the product is a solid, liquid, or gas at room temperature? Write the balanced chemical equation for the reaction. (b) When a hydrocarbon burns in air, what reactant besides the hydrocarbon is involved in the reaction? What products are formed? Write a balanced chemical equation for the combustion of benzene C6H6(l), in air.arrow_forward
- Propane, C3H8, is a hydrocarbon that is commonly used as a fuel.(a) Write a balanced equation for the complete combustion of propane gas.(b) Calculate the volume of air at 25 °C and 1.00 atmosphere that is needed to completely combust 25.0 grams of propane. Assume that air is 21.0 percent O2 by volume. (Hint:use the information that 1.00 L of air at 25 °C and 1.00 atm contains 0.275 g of O2 per liter.)(c) The heat of combustion of propane is −2,219.2 kJ/mol. Calculate the heat of formation, ΔH°f of propane given that ΔH°f of H2O(l) = −285.8 kJ/mol and ΔH°f of CO2(g) = −393.5 kJ/mol. (d) Assuming that all of the heat released in burning 25.0 grams of propane is transferred to 4.00 kilograms of water, calculate the increase in temperature of the water.arrow_forwardWrite a balanced chemical equation for the reaction of ethene with oxygen. O a. C2H4(g) + 302(g) → 2CO2(g) + 2H2O(g) O b. 2C2H2(g) + 502(g) → 4CO2(g) + 2H2O(g) O c. CH4(g) + 2O2(g) → CO2(g) + 2H2O(g) O d. C2H4(g) + 202(g) → 2CO2(g) + 2H2(g) O e. 2C2H6(g) + 702(g) →> 4CO2(g) + 6H2O(g)arrow_forwardConsider the complete combustion of octane. Calculate the bond energies (in kJ/mol) for the:Combustion of methane CH4(g)+2O2(g)→CO2(g)+2H2O(g)a. bonds brokenb. bonds formedc. overall reactionarrow_forward
- Consider the compound 2,4-dimethyl-3-isopropylpentane. How many unique radical structures can be derived from this hydrocarbon when it undergoes free radical substitution? Write the number of free radicals formed.arrow_forwardA student adds bromine solution to a test tube containing an isomer of C3H6. After shaking the sample and exposing it to UV light, the student observes that the colour of the bromine solution changes from orange to clear. Provide a hypothesis for what happened in the test tube. What do you believe to be the structure of the original isomer, and what was the final product, if a reaction occurred?arrow_forward(a) What is the difference between chlorofluorocarbons and hydrofluorocarbons?arrow_forward
- Write the equation for the oxidation of pentane (C5H12). What is the sum of the coefficients for the reactants and products?arrow_forwardWrite a balanced chemical equation, including states of matter, for the combustion of ethylene gas, C2H4.arrow_forwardAn impure sample of hydrocarbon having a total mass of 50.8g undergoes combustion analysis to generate 72.6g CO2 (g) and 14.8g H2O (g). Assuming that the impurities do not contain carbon or hydrogen what percentage of the initial sample is the pure hydrocarbon?arrow_forward
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