Concept explainers
(a)
Interpretation:
The major product of the reaction of 2-methyl-2-butene with
Concept introduction:
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.
Peroxide is a radical initiator, it has O-O bond in the molecule.
It is used in the radical reaction for the radical initiator.
Markovnikov’s rule:
(b)
Interpretation:
The major product of the reaction of 2-methyl-2-butene with
Concept introduction:
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.
Peroxide is a radical initiator, it has O-O bond in the molecule.
It is used in the radical reaction for the radical initiator.
Markovnikov’s rule:
Alkene undergoes hydrohalogenation using hydrogen halide through breaking of carbon to carbon double bond, followed by the electrophilic addition of a hydrogen atom and halogen. The halide ion will add to the more substituted carbon in the alkene.
(c)
Interpretation:
The major product of the reaction of 2-methyl-2-butene with
Concept introduction:
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.
Peroxide is a radical initiator, it has O-O bond in the molecule.
It is used in the radical reaction for the radical initiator.
Bromination of alkene in presence of peroxide:
(d)
Interpretation:
The major product of the reaction of 2-methyl-2-butene with
Concept introduction:
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.
Peroxide is a radical initiator, it has O-O bond in the molecule.
It is used in the radical reaction for the radical initiator.
Chlorination or iodination of alkene in presence of peroxide:
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Chapter 12 Solutions
Organic Chemistry (8th Edition)
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