Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 12.6, Problem 12P
(a)
Interpretation Introduction
Interpretation:
Among the given ethers, the one which is most apt to form a peroxide has to be given.
Concept introduction:
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.
Peroxide is a radical initiator, it has O-O bond in the molecule.
It is used in the radical reaction for the radical initiator.
(b)
Interpretation Introduction
Interpretation:
Among the given ethers, the one which is least apt to form a peroxide has to be given.
Concept introduction:
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.
Peroxide is a radical initiator, it has O-O bond in the molecule.
It is used in the radical reaction for the radical initiator.
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Synthesize each compound from toluene (CgH,CH3) and any other organic or inorganic reagents.
a. CeHsCH2OC(CHa
O,N
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d. HOOC-
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f.
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CHO
C.
е.
g.
Br
Which alkene cannot be converted into an alkyl bromide with HBr, ROOR, hv, A?
III
IV
A.
B.
C.
D.
E. All react
Which synthetic route is best to give the major product shown below.
?
x
XA
OH
A. 1. BH3; 2. H₂O2, NaOH; 3. HBr; 4. CH3CO₂H
B. 1. Br₂, 2. NaCCH; H₂, Lindlar's; 3. O3; 4. H₂O
C. 1. NBS, hv, A; 2. H₂, Pd; 3. NaO₂CCH3
D. 1. NBS, hv, A; 2. NaCCH; 3. H₂2, Pd; 4. O3; 5. H₂O
E. 1. NBS, hv, A; 2. H₂, Pd; 3. NaCCH; 4. 03; 5. H₂O
Which synthetic route is best for the transformation shown below?
OH
?
OH
A. 1. H₂SO4/heat; 2. HgOAC2, H₂O; 3. NaBH4
B. 1. HBr; 2. NaOH, DMSO
C. 1. TsCl, pyr; 2. NaOH, DMSO
D. 1. TsCl, pyr; 2. KOtBu; 3. BH3-THF; 4. H₂O2, NaOH
E. 1. H₂SO4/heat; 2. BH3-THF; 3. H₂O2, NaOH
=B
4.
Chapter 12 Solutions
Organic Chemistry (8th Edition)
Ch. 12.2 - Prob. 1PCh. 12.2 - Write the steps for formation of...Ch. 12.3 - Prob. 3PCh. 12.4 - How many alkyl chlorides are obtained from...Ch. 12.4 - Prob. 6PCh. 12.5 - Prob. 8PCh. 12.5 - a. Would chlorination or bromination produce a...Ch. 12.5 - Show how the following compounds could be prepared...Ch. 12.6 - Prob. 12PCh. 12.7 - Prob. 13P
Ch. 12.7 - Prob. 14PCh. 12.8 - Prob. 15PCh. 12.8 - Draw the stereoisomers of the major...Ch. 12.9 - Prob. 18PCh. 12.9 - How many allylic substituted bromoalkenes are...Ch. 12.9 - a. How many stereoisomers are formed from the...Ch. 12.9 - Prob. 21PCh. 12.9 - Prob. 22PCh. 12.10 - Prob. 23PCh. 12.11 - How many atoms share the unpaired electrons in...Ch. 12.11 - Prob. 25PCh. 12 - Prob. 26PCh. 12 - Prob. 27PCh. 12 - Prob. 28PCh. 12 - Prob. 29PCh. 12 - Prob. 30PCh. 12 - Prob. 31PCh. 12 - Prob. 32PCh. 12 - Prob. 33PCh. 12 - Prob. 34PCh. 12 - Prob. 35PCh. 12 - Prob. 36PCh. 12 - Prob. 37PCh. 12 - a. What five-carbon alkene forms the same product...Ch. 12 - Prob. 39PCh. 12 - Starting with cyclohexane, how could the following...Ch. 12 - a. Propose a mechanism for the following reaction:...Ch. 12 - What stereoisomers are obtained from the following...Ch. 12 - Prob. 43PCh. 12 - Prob. 44PCh. 12 - Prob. 45PCh. 12 - Draw the products of the following reactions,...Ch. 12 - Prob. 47PCh. 12 - Prob. 48PCh. 12 - Prob. 49PCh. 12 - Explain why the rate of bromination of methane...Ch. 12 - Prob. 51PCh. 12 - Prob. 1PCh. 12 - Prob. 2PCh. 12 - Prob. 3PCh. 12 - Prob. 4P
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