Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
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Chapter D, Problem D.3YT
Interpretation Introduction
Interpretation:
Atomic orbital overlap and MO energy diagram for HO- and HCl is to be constructed. HOMO of HO- and LUMO of HCl is to be determined.
Concept introduction:
The type of hybridization and orbitals contributed by the atoms suggests the type of overlap that will occur between those atoms. This in turn tells about the type of bonding between those atoms. The number of MOs is equal to the number of AOs undergoing mixing.
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ST 9C.2- Calculate the energy (in eV) of an antibonding molecular orbital for the molecule XY
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a (X) = -11.2 eV
a (Y) = -8.8 eV
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1. ionization of Cl2 (Cl2 —> Cl2+ + e-) leads to a shortening of the Cl-Cl distance (199 pm in Cl2, 189 pm in Cl2+), why?
2. why the C-O bond distance is nearly identical in CO (113 pm) and CO+ (112 pm)?
3. Derive the MO diagram of a linear C-H (i.e. one carbon atom bonded to one hydrogen atom). Draw out the MOs for orbitals containing electrons Would you expect C-H to behave as a carbocation, carbanion, or radical? Would removal of one electron from C-H to generate C-H+ increase or decrease the bond length between carbon and hydrogen?
Chapter D Solutions
Organic Chemistry: Principles and Mechanisms (Second Edition)
Ch. D - Prob. D.1PCh. D - Prob. D.2PCh. D - Prob. D.3PCh. D - Prob. D.4PCh. D - Prob. D.5PCh. D - Prob. D.6PCh. D - Prob. D.7PCh. D - Prob. D.8PCh. D - Prob. D.9PCh. D - Prob. D.10P
Ch. D - Prob. D.11PCh. D - Prob. D.1YTCh. D - Prob. D.2YTCh. D - Prob. D.3YTCh. D - Prob. D.4YTCh. D - Prob. D.5YTCh. D - Prob. D.6YTCh. D - Prob. D.7YTCh. D - Prob. D.8YTCh. D - Prob. D.9YTCh. D - Prob. D.10YTCh. D - Prob. D.11YTCh. D - Prob. D.12YTCh. D - Prob. D.13YTCh. D - Prob. D.14YTCh. D - Prob. D.15YTCh. D - Prob. D.16YT
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