Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 9, Problem 9B.2AST
Interpretation Introduction
Interpretation:
The Gibb’s free energy of the reaction has to be given.
Concept Introduction:
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Calculate the standard enthalpy of formation of NaHCO3(s) given the following information:ΔfH°[ CO2(g) ] = −393.41 kJ mol-1, ΔfH° [ NaOH(s) ] = −425.61 kJ mol-1ΔrxnH°[NaOH(s) + CO2(g) ⟶ NaHCO3(s) ] = −127.5 kJ mol-1
Construct a diagram depicting ΔrxnH° of the above reaction and the standard enthalpies of formation of the associated products and reactants.
Calculate AG for the overall reaction if this process is coupled to the conversion of sulfur to
sulfur dioxide at 127°C. Use the table with formation constants to calculate your answer.
88.62 X mol
Species AH (kJ/mol) AS
f
S(s)
Cu(s) 0
Cu₂S(s)-79.5
0
O₂(g) 0
SO₂(g) -296.8
32.1
33
(J/mol·K)
120.9
205.2
248.2
Calculate the lattice energy of AgBr(s) using the following thermodynamic data (all data is in kJ/mol).
Ag(s)
ΔHsublimation = 265 kJ/mol
Ag(g)
Ionization energy = 711 kJ/mol
Br-Br(g)
Bond energy = 173 kJ/mol
Br(g)
Electron affinity = -345 kJ/mol
AgBr(s)
ΔH°f = -120 kJ/mol
______________ kJ/mol
Chapter 9 Solutions
Chemical Principles: The Quest for Insight
Ch. 9 - Prob. 9A.1ASTCh. 9 - Prob. 9A.1BSTCh. 9 - Prob. 9A.1ECh. 9 - Prob. 9A.2ECh. 9 - Prob. 9A.3ECh. 9 - Prob. 9A.4ECh. 9 - Prob. 9A.5ECh. 9 - Prob. 9A.6ECh. 9 - Prob. 9A.7ECh. 9 - Prob. 9A.8E
Ch. 9 - Prob. 9A.9ECh. 9 - Prob. 9A.10ECh. 9 - Prob. 9A.11ECh. 9 - Prob. 9A.12ECh. 9 - Prob. 9A.13ECh. 9 - Prob. 9A.14ECh. 9 - Prob. 9B.1ASTCh. 9 - Prob. 9B.1BSTCh. 9 - Prob. 9B.2ASTCh. 9 - Prob. 9B.2BSTCh. 9 - Prob. 9B.1ECh. 9 - Prob. 9B.2ECh. 9 - Prob. 9B.3ECh. 9 - Prob. 9B.4ECh. 9 - Prob. 9B.5ECh. 9 - Prob. 9B.6ECh. 9 - Prob. 9B.7ECh. 9 - Prob. 9B.8ECh. 9 - Prob. 9B.9ECh. 9 - Prob. 9B.10ECh. 9 - Prob. 9B.11ECh. 9 - Prob. 9B.12ECh. 9 - Prob. 9B.13ECh. 9 - Prob. 9B.14ECh. 9 - Prob. 9B.15ECh. 9 - Prob. 9B.16ECh. 9 - Prob. 9C.1ASTCh. 9 - Prob. 9C.1BSTCh. 9 - Prob. 9C.2ASTCh. 9 - Prob. 9C.2BSTCh. 9 - Prob. 9C.3ASTCh. 9 - Prob. 9C.3BSTCh. 9 - Prob. 9C.4ASTCh. 9 - Prob. 9C.4BSTCh. 9 - Prob. 9C.1ECh. 9 - Prob. 9C.2ECh. 9 - Prob. 9C.3ECh. 9 - Prob. 9C.4ECh. 9 - Prob. 9C.5ECh. 9 - Prob. 9C.6ECh. 9 - Prob. 9C.7ECh. 9 - Prob. 9C.8ECh. 9 - Prob. 9C.9ECh. 9 - Prob. 9C.10ECh. 9 - Prob. 9C.11ECh. 9 - Prob. 9C.12ECh. 9 - Prob. 9C.13ECh. 9 - Prob. 9C.14ECh. 9 - Prob. 9C.15ECh. 9 - Prob. 9C.16ECh. 9 - Prob. 9C.17ECh. 9 - Prob. 9C.18ECh. 9 - Prob. 9C.19ECh. 9 - Prob. 9C.20ECh. 9 - Prob. 9D.1ASTCh. 9 - Prob. 9D.1BSTCh. 9 - Prob. 9D.2ASTCh. 9 - Prob. 9D.2BSTCh. 9 - Prob. 9D.3ASTCh. 9 - Prob. 9D.3BSTCh. 9 - Prob. 9D.4ASTCh. 9 - Prob. 9D.4BSTCh. 9 - Prob. 9D.1ECh. 9 - Prob. 9D.2ECh. 9 - Prob. 9D.3ECh. 9 - Prob. 9D.4ECh. 9 - Prob. 9D.5ECh. 9 - Prob. 9D.6ECh. 9 - Prob. 9D.7ECh. 9 - Prob. 9D.8ECh. 9 - Prob. 9D.9ECh. 9 - Prob. 9D.10ECh. 9 - Prob. 9D.11ECh. 9 - Prob. 9D.12ECh. 9 - Prob. 9D.13ECh. 9 - Prob. 9D.14ECh. 9 - Prob. 9D.15ECh. 9 - Prob. 9D.16ECh. 9 - Prob. 9D.17ECh. 9 - Prob. 9D.18ECh. 9 - Prob. 9D.19ECh. 9 - Prob. 9D.20ECh. 9 - Prob. 9D.21ECh. 9 - Prob. 9D.22ECh. 9 - Prob. 9D.23ECh. 9 - Prob. 9D.24ECh. 9 - Prob. 9D.25ECh. 9 - Prob. 9D.26ECh. 9 - Prob. 9D.27ECh. 9 - Prob. 9D.28ECh. 9 - Prob. 9D.29ECh. 9 - Prob. 9D.30ECh. 9 - Prob. 9D.31ECh. 9 - Prob. 9D.32ECh. 9 - Prob. 9D.33ECh. 9 - Prob. 9D.34ECh. 9 - Prob. 9.1ECh. 9 - Prob. 9.2ECh. 9 - Prob. 9.3ECh. 9 - Prob. 9.4ECh. 9 - Prob. 9.5ECh. 9 - Prob. 9.6ECh. 9 - Prob. 9.7ECh. 9 - Prob. 9.8ECh. 9 - Prob. 9.9ECh. 9 - Prob. 9.10ECh. 9 - Prob. 9.11ECh. 9 - Prob. 9.12ECh. 9 - Prob. 9.13ECh. 9 - Prob. 9.14ECh. 9 - Prob. 9.15ECh. 9 - Prob. 9.16ECh. 9 - Prob. 9.17ECh. 9 - Prob. 9.18ECh. 9 - Prob. 9.19ECh. 9 - Prob. 9.20ECh. 9 - Prob. 9.21ECh. 9 - Prob. 9.23ECh. 9 - Prob. 9.25E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Write the expression for the equilibrium constant Kc for the following equation. FeO(s) + CO(g) ↔ Fe(s) + CO2(g)arrow_forwardGiven the enthalpy changes for the following reactions, calculate AH for CO C(gaphite) + 1/20 CO C(gaphite) + O → CO CO+ 1/202 → CO -> AH: = -393.5 kJ AH =-283.0 Jarrow_forward8. Given the standard heats of formation for the following compounds, calculate the ΔH° heat of reaction, for the following reaction: Fe3O4(s) + CO(g) ---> 3 FeO(s) + CO2(g) ΔHf° for Fe3O4 = -1118 kJΔHf° for CO = -110.5 kJΔHf° for FeO = -272 kJΔHf° for CO2 = -393.5 kJ Please show workarrow_forward
- Given the thermodynamic data in the table below, calculate the equilibrium constant (at 298 K) for the reaction: 2 SO2 (g) + O2 (g) --> 2 SO3 (g)arrow_forwardGiven the following information (and using only this information): Compound ∆Gof (kJ/mol) NiO –212 MgO –569 CuO –130 MnO –363 Rank the metals in order of increasing activity (tendency to give up electrons to become oxidized). Answers given as less active < more active.arrow_forwardThe molecular weight of sperm whale myoglobin is 17.8 kDa.17.8 kDa. The myoglobin content of sperm whale muscle is about 80 g · kg−1.80 g · kg−1. In contrast, the myoglobin content of some human muscles is about 8 g · kg−1.8 g · kg−1. Compare the amounts of O2O2 bound to myoglobin in human muscle and in sperm whale muscle. Assume that the myoglobin is saturated with O2,O2, and that the molecular weights of human and sperm whale myoglobin are the same. How much O2O2 is bound to myoglobin in human muscle? How much O2O2 is bound to myoglobin in whale muscle? The amount of oxygen dissolved in tissue water at 37°C37°C is about 3.5×10−5 M.3.5×10−5 M. What is the ratio of myoglobin‑bound oxygen to dissolved oxygen in the tissue water of sperm whale muscle?arrow_forward
- 4. The common oxidation number for an alkaline earth metal is +2. (a) Using the Born-Mayer equation (for determining the lattice enthalpy) and a Born-Haber cycle (draw it), show that CaCl is an exothermic compound (negative AHf). Make a reasonable prediction to estimate the ionic radius of Ca (explain your reasoning). The sublimation (atomization) enthalpy for Ca(s) is 178 kJ/mol. (b) Show that an explanation for the non-existence of CaCl can be found in the enthalpy change for the reaction below. The AHf for CaCl2(s) is -190.2 kcal/mol. 2 CaCl(s) → Ca(s) + CaCl2(s)arrow_forwardThe thermite reaction is written below. Show that the heat released in this reaction is sufficient for the iron to be produced as molten metal. Find the enthalpy of formation of the overall reaction. Al(s) + Where: Al ΔΗ°F= 0 Al2O3 AHF -2076 Fe AHF 0 Fe2O3 AHF -745 Fe₂O3(s)- → Al₂O3(s) + Fe(1)arrow_forwardDescribe the reaction Cu(OH)2 (s) + Heat →arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Calorimetry Concept, Examples and Thermochemistry | How to Pass Chemistry; Author: Melissa Maribel;https://www.youtube.com/watch?v=nSh29lUGj00;License: Standard YouTube License, CC-BY