Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
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Chapter 9, Problem 9.18E
Interpretation Introduction
Interpretation:
The correct formula, structure and the possible isomers of the complex
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CoCl3(H2N-CH2-CH2-NH2)2(H2O) corresponds to the empirical formula of two coordination compounds denoted A and B. When A is reacted with silver nitrate, 2/3 of the chlorine atoms precipitate. B, submitted to the same treatment, exhibits the precipitation of 1/3 of the present chlorine atoms.What is the reaction caused by the addition of silver nitrate on A and B?
Write the formula and draw the structure of each of these two isomers for the
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Chapter 9 Solutions
Chemical Principles: The Quest for Insight
Ch. 9 - Prob. 9A.1ASTCh. 9 - Prob. 9A.1BSTCh. 9 - Prob. 9A.1ECh. 9 - Prob. 9A.2ECh. 9 - Prob. 9A.3ECh. 9 - Prob. 9A.4ECh. 9 - Prob. 9A.5ECh. 9 - Prob. 9A.6ECh. 9 - Prob. 9A.7ECh. 9 - Prob. 9A.8E
Ch. 9 - Prob. 9A.9ECh. 9 - Prob. 9A.10ECh. 9 - Prob. 9A.11ECh. 9 - Prob. 9A.12ECh. 9 - Prob. 9A.13ECh. 9 - Prob. 9A.14ECh. 9 - Prob. 9B.1ASTCh. 9 - Prob. 9B.1BSTCh. 9 - Prob. 9B.2ASTCh. 9 - Prob. 9B.2BSTCh. 9 - Prob. 9B.1ECh. 9 - Prob. 9B.2ECh. 9 - Prob. 9B.3ECh. 9 - Prob. 9B.4ECh. 9 - Prob. 9B.5ECh. 9 - Prob. 9B.6ECh. 9 - Prob. 9B.7ECh. 9 - Prob. 9B.8ECh. 9 - Prob. 9B.9ECh. 9 - Prob. 9B.10ECh. 9 - Prob. 9B.11ECh. 9 - Prob. 9B.12ECh. 9 - Prob. 9B.13ECh. 9 - Prob. 9B.14ECh. 9 - Prob. 9B.15ECh. 9 - Prob. 9B.16ECh. 9 - Prob. 9C.1ASTCh. 9 - Prob. 9C.1BSTCh. 9 - Prob. 9C.2ASTCh. 9 - Prob. 9C.2BSTCh. 9 - Prob. 9C.3ASTCh. 9 - Prob. 9C.3BSTCh. 9 - Prob. 9C.4ASTCh. 9 - Prob. 9C.4BSTCh. 9 - Prob. 9C.1ECh. 9 - Prob. 9C.2ECh. 9 - Prob. 9C.3ECh. 9 - Prob. 9C.4ECh. 9 - Prob. 9C.5ECh. 9 - Prob. 9C.6ECh. 9 - Prob. 9C.7ECh. 9 - Prob. 9C.8ECh. 9 - Prob. 9C.9ECh. 9 - Prob. 9C.10ECh. 9 - Prob. 9C.11ECh. 9 - Prob. 9C.12ECh. 9 - Prob. 9C.13ECh. 9 - Prob. 9C.14ECh. 9 - Prob. 9C.15ECh. 9 - Prob. 9C.16ECh. 9 - Prob. 9C.17ECh. 9 - Prob. 9C.18ECh. 9 - Prob. 9C.19ECh. 9 - Prob. 9C.20ECh. 9 - Prob. 9D.1ASTCh. 9 - Prob. 9D.1BSTCh. 9 - Prob. 9D.2ASTCh. 9 - Prob. 9D.2BSTCh. 9 - Prob. 9D.3ASTCh. 9 - Prob. 9D.3BSTCh. 9 - Prob. 9D.4ASTCh. 9 - Prob. 9D.4BSTCh. 9 - Prob. 9D.1ECh. 9 - Prob. 9D.2ECh. 9 - Prob. 9D.3ECh. 9 - Prob. 9D.4ECh. 9 - Prob. 9D.5ECh. 9 - Prob. 9D.6ECh. 9 - Prob. 9D.7ECh. 9 - Prob. 9D.8ECh. 9 - Prob. 9D.9ECh. 9 - Prob. 9D.10ECh. 9 - Prob. 9D.11ECh. 9 - Prob. 9D.12ECh. 9 - Prob. 9D.13ECh. 9 - Prob. 9D.14ECh. 9 - Prob. 9D.15ECh. 9 - Prob. 9D.16ECh. 9 - Prob. 9D.17ECh. 9 - Prob. 9D.18ECh. 9 - Prob. 9D.19ECh. 9 - Prob. 9D.20ECh. 9 - Prob. 9D.21ECh. 9 - Prob. 9D.22ECh. 9 - Prob. 9D.23ECh. 9 - Prob. 9D.24ECh. 9 - Prob. 9D.25ECh. 9 - Prob. 9D.26ECh. 9 - Prob. 9D.27ECh. 9 - Prob. 9D.28ECh. 9 - Prob. 9D.29ECh. 9 - Prob. 9D.30ECh. 9 - Prob. 9D.31ECh. 9 - Prob. 9D.32ECh. 9 - Prob. 9D.33ECh. 9 - Prob. 9D.34ECh. 9 - Prob. 9.1ECh. 9 - Prob. 9.2ECh. 9 - Prob. 9.3ECh. 9 - Prob. 9.4ECh. 9 - Prob. 9.5ECh. 9 - Prob. 9.6ECh. 9 - Prob. 9.7ECh. 9 - Prob. 9.8ECh. 9 - Prob. 9.9ECh. 9 - Prob. 9.10ECh. 9 - Prob. 9.11ECh. 9 - Prob. 9.12ECh. 9 - Prob. 9.13ECh. 9 - Prob. 9.14ECh. 9 - Prob. 9.15ECh. 9 - Prob. 9.16ECh. 9 - Prob. 9.17ECh. 9 - Prob. 9.18ECh. 9 - Prob. 9.19ECh. 9 - Prob. 9.20ECh. 9 - Prob. 9.21ECh. 9 - Prob. 9.23ECh. 9 - Prob. 9.25E
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- How would you draw the isomer structure(s) for [Fe(C2O4)2(H2O)2] 0arrow_forwardA manganese complex formed from a solution containing potassium bromide and oxalate ion is purified and analyzed. It contains 10.0% Mn, 28.6% potassium, 8.8% carbon, and 29.2% bromine by mass. The remainder of the compound is oxygen. An aqueous solution of the complex has about the same electrical conductivity as an equimolar solution of K4[Fe(CN)6]. Write the formula of the compound, using brackets to denote the manganese and its coordination sphere.arrow_forwardCoCl3(H2N-CH2-CH2-NH2)2(H2O) corresponds to the empirical formula of two coordination compounds denoted A and B. When A is reacted with silver nitrate, 2/3 of the chlorine atoms precipitate. B, submitted to the same treatment, exhibits the precipitation of 1/3 of the present chlorine atoms. What are the formulas of compounds A and B?arrow_forward
- How many valence electrons surround the metal atom in potassium ferrioxalate (K3[Fe(C2O4)³])?arrow_forwardThe compound Cr(en)2(OH)2Cl has been prepared in several isomeric forms: Isomer A is optically inactive and undergoes no reaction with either AgNO3 or en. Isomer B is optically inactive and reacts with AgNO3 to form a white precipitate, but does not react with en. Isomer C is optically active and reacts both with en and AgNO3. Assuming the coordination number of chromium is 6, identify each of the three isomers by name and draw each of the structures.Hint: For the en ligand think about what angle the donor atoms form with the metal ion.arrow_forward[CuCl4]2− is green. [Cu(H2O)6]2+is blue. Which absorbs higher-energy photons? Which is predicted to have a larger crystal field splitting?arrow_forward
- Which of the following compounds can exhibit cis-trans isomerism? O [Fe(CO)2(NH3)2]?* O [Zn(CO)5Br]* [MNCIBR3]?- O [Cr(CO);NO2]²+ O IFe(H2O)6]³+arrow_forward(a) Deduce the number of 3d electrons in the following ions Fe3+ , Cu2+. (b) Why do transition metals forms alloys. (c) Write any two characteristics of interstitial compounds.arrow_forwardExplain how the diphosphate ion, [O3P−O−PO3]4−, can function as a water softener that prevents the precipitation of Fe2+ as an insoluble iron salt.arrow_forward
- Metal cations often form complex ions in solution or when reacted with suitable ligands. Write a balanced equation for the formation of Cu(en)22+ from Cu2+ and ethylenediamine (en) in an aqueous solution.arrow_forwardWhen the copper (II) sulphate solution is reacted with a bidentate ligand such as ethylenediamine (en), the same thing would have happened. However, since one bidentate ligand has two donor atoms (Brown et al, 2017), each Cu2+ ion would only have 3 ligands at most, instead of 6 when reacted with monodentate ligands. The equation of the reaction is as follows: [Cu(H2O)6]2+(aq) + 3en(aq) → [Cu(en)3](aq) + 6H2O(ℓ) a. How do we know how many ligands can enter? b. Explain briefly the discussion above.arrow_forward(a) Draw a Lewis dot and cross structure (including any lone pairs) for a NBr3 molecule and determine the shape of the molecule and number of valence electrons. (b) Six ammonia ligands form a complex ion with Co²+. What is the overall charge of the complex ion? Write the formula for the complex ion. What is the coordination number of the complex ion? Explain how ammonia ligands form a complex ion with Co²+? What is the geometry of the complex ion? Would you expect the complex to be coloured? Explain why? i. ii. iii. iv. V. vi.arrow_forward
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