Substitution product of 2-chloro-methyl-3 4 hexene added to a solution of sodium acetate in acetic acid has to be given. Concept Introduction: Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product. If the leaving group in S N 1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed. An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

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Answer 1

Question

Chapter 9, Problem 53P

(a)

Interpretation Introduction

Interpretation:

Substitution product of 2-chloro-methyl-3 4 hexene added to a solution of sodium acetate in acetic acid has to be given.

Concept Introduction:

Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.

If the leaving group in S_N1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.

An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

(b)

Interpretation Introduction

Interpretation:

Substitution product of 3-bromo-1-methylcyclohexene added to a solution of sodium acetate in acetic acid has to be given.

Concept Introduction:

Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.

If the leaving group in S_N1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.

An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

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The correct IUPAC name for this compound is: O a. 4-oxa-1-cyclohexanol O b. 4-hydroxyoxacyclohexene O c. 4-oxa-1-cyclohexenol O d. 4-oxacyclohexane-1-ol OH

7 Give the IUPAC name for the following compound. OH A. 3-methyl-1-pentenyl alcohol B. 3-vinyl-1-butanol C. 3-methyl-4-penten-1-ol

Based on the image attached, which of the following is the correct systematic name for the compound? A. 3-benzyl-6-bromo-3-ethyl-2-methyldecan-7,8-diol B. 5-bromo-8-cyclohexyl-8-ethyl-9-methyldecan-3,4-diol C. 3-benzyl-6-bromo-3-isopropyldecan-7,8-diol D. 5-bromo-8-cyclohexyl-8-isopropyldecan-3,4-diol

Answer 2

Question

Chapter 9, Problem 53P

(a)

Interpretation Introduction

Interpretation:

Substitution product of 2-chloro-methyl-3 4 hexene added to a solution of sodium acetate in acetic acid has to be given.

Concept Introduction:

Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.

If the leaving group in S_N1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.

An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

(b)

Interpretation Introduction

Interpretation:

Substitution product of 3-bromo-1-methylcyclohexene added to a solution of sodium acetate in acetic acid has to be given.

Concept Introduction:

Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.

If the leaving group in S_N1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.

An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

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Answer 3

Question

Chapter 9, Problem 53P

(a)

Interpretation Introduction

Interpretation:

Substitution product of 2-chloro-methyl-3 4 hexene added to a solution of sodium acetate in acetic acid has to be given.

Concept Introduction:

Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.

If the leaving group in S_N1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.

An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

(b)

Interpretation Introduction

Interpretation:

Substitution product of 3-bromo-1-methylcyclohexene added to a solution of sodium acetate in acetic acid has to be given.

Concept Introduction:

Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.

If the leaving group in S_N1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.

An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

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Answer 4

Question

Chapter 9, Problem 53P

(a)

Interpretation Introduction

Interpretation:

Substitution product of 2-chloro-methyl-3 4 hexene added to a solution of sodium acetate in acetic acid has to be given.

Concept Introduction:

Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.

If the leaving group in S_N1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.

An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

(b)

Interpretation Introduction

Interpretation:

Substitution product of 3-bromo-1-methylcyclohexene added to a solution of sodium acetate in acetic acid has to be given.

Concept Introduction:

Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.

If the leaving group in S_N1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.

An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

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Answer 5

Chapter 9, Problem 53P

(a)

Interpretation Introduction

Interpretation:

Substitution product of 2-chloro-methyl-3 4 hexene added to a solution of sodium acetate in acetic acid has to be given.

Concept Introduction:

Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.

If the leaving group in S_N1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.

An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

(b)

Interpretation Introduction

Interpretation:

Substitution product of 3-bromo-1-methylcyclohexene added to a solution of sodium acetate in acetic acid has to be given.

Concept Introduction:

Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.

If the leaving group in S_N1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.

An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

Answer 6

Chapter 9, Problem 53P

(a)

Interpretation Introduction

Interpretation:

Substitution product of 2-chloro-methyl-3 4 hexene added to a solution of sodium acetate in acetic acid has to be given.

Concept Introduction:

Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.

If the leaving group in S_N1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.

An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

Answer 7

Chapter 9, Problem 53P

(a)

Interpretation Introduction

Interpretation:

Substitution product of 2-chloro-methyl-3 4 hexene added to a solution of sodium acetate in acetic acid has to be given.

Concept Introduction:

Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.

If the leaving group in S_N1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.

An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Substitution product of 3-bromo-1-methylcyclohexene added to a solution of sodium acetate in acetic acid has to be given.

Concept Introduction:

Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.

If the leaving group in S_N1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.

An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Substitution product of 3-bromo-1-methylcyclohexene added to a solution of sodium acetate in acetic acid has to be given.

Concept Introduction:

Unimolecular nucleophilic substitution reaction in which the reversible ionization of alkyl halide in the presence of aqueous acetone or an aqueous ethyl alcohol provides a carbocation as an intermediate, attacked by the nucleophile to form the product.

If the leaving group in S_N1 reaction is attached to the asymmetric carbon, a pair of enantiomers will be formed.

An enantiomer, also known as an optical isomer, is one of two stereoisomers that are mirror images of each other that are non-superimposable.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 9.1 - Prob. 3P Ch. 9.1 - Does increasing the energy barrier for an SN2...Ch. 9.1 - Rank the following alkyl bromides from most...Ch. 9.2 - Prob. 8P Ch. 9.2 - Prob. 9P Ch. 9.2 - Prob. 10P Ch. 9.2 - Prob. 11P Ch. 9.2 - Which substitution reaction lakes place more...Ch. 9.2 - Prob. 14P Ch. 9.2 - Prob. 16P

Solution Summary: The author explains the reversible ionization of alkyl halide in the presence of acetone or ethyl alcohol provides a carbocation as an intermediate, attacked by the nucle

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