Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Question
Chapter 9, Problem 40P
(a)
Interpretation Introduction
Interpretation:
Affect of
Concept Introduction:
Thus,
Where k is the rate constant.
(b)
Interpretation Introduction
Interpretation:
Affect of rate of the reaction of
Concept Introduction:
Thus,
Where k is the rate constant.
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32. Which of the following reactions can be used to prepare 3-methyl-3-hexanol,
OH
I
CH3CH2CCH2CH2CH3 ?
1
CH 3
A.
B.
CH3CH2CCH2CH2CH3
i
CH3CCH2CH2CH3
i
CH3CCH2CH3
1. CH3MgBr
2. H30
C.
D. A and B
E. A, B, and C
1. CH3CH2MgBr
2. H30
1. CH3CH2CH2MgBr
2. H30
33. Complete the following reaction sequence by supplying the missing information:
(1)
(2)
4. ?
CH3OH
(3)
CH3Br
CH3CH2OH
5. ?
A. (1) NaBr; (2) Mg/ether; (3) CH3MgBr; (4) H2C=0; (5) H2O
B. (1) HBr; (2) Mg/ether; (3) CH3MgBr; (4) H2C=0; (5) H2O
c. (1) Br2; (2) Mg/ether; (3) CH3MgBr; (4) H2C=O; (5) H2O
D. (1) HBr; (2) CH3MgBr; (3) Mg/ether; (4) H2C=O; (5) H2O
4. Which of the following reactions is NOT a method of preparation of alkylhalide?
A. addition of halogens to alkenes
B. replacement of the -OH in alcohol by a halide
C. dehydrohalogenation
of hydrocarbon
D. addition of hydrogen halide to alkene
5. In SN₂ reaction of alkylhalide(substrate) with NaOH(nucleophile), the rate of the reaction is tripled if the
concentration of:
A. Substrate and nucleophile are both doubled
B. Nucleophile is decreased by 1/3 and substrate doubled
C. Substrate is tripled and nucleophile doubled
D. Nucleophile is tripled
6. Arrange the following alkylhalide in order of decreasing reactivity in an SN₁ reaction:
I. CH3CH(Br)CH₂CH3
A. I>II>III>IV
II. CH3CH(C1)CH₂CH3 III. CICH₂CH₂CH₂CH3 IV. (CH3)2C(Br)CHCH3
D. IV>II>I>III
B. IV>III>II>I C. IV>I>II>III
Consider the structure of pent-2-ene, if it undergoes ozonolysis, which of the following final product is formed?
a.Ethanal and Propanal
b.Ethanal and Propanone
c.CO2 and Propanal
d.Ethanal and CO2
Chapter 9 Solutions
Organic Chemistry
Ch. 9.1 - Prob. 3PCh. 9.1 - Does increasing the energy barrier for an SN2...Ch. 9.1 - Rank the following alkyl bromides from most...Ch. 9.2 - Prob. 8PCh. 9.2 - Prob. 9PCh. 9.2 - Prob. 10PCh. 9.2 - Prob. 11PCh. 9.2 - Which substitution reaction lakes place more...Ch. 9.2 - Prob. 14PCh. 9.2 - Prob. 16P
Ch. 9.3 - Prob. 17PCh. 9.4 - Prob. 18PCh. 9.5 - Prob. 19PCh. 9.5 - Prob. 20PCh. 9.5 - Prob. 21PCh. 9.5 - Prob. 22PCh. 9.6 - Prob. 23PCh. 9.6 - Prob. 24PCh. 9.6 - Which of the following reactions take place more...Ch. 9.7 - Prob. 26PCh. 9.7 - Prob. 27PCh. 9.7 - Prob. 28PCh. 9.7 - Prob. 30PCh. 9.7 - Under which of the following reaction conditions...Ch. 9.8 - After a proton is removed from the OH group, which...Ch. 9.8 - Prob. 33PCh. 9.9 - Prob. 34PCh. 9 - Prob. 1PCh. 9 - Methoxychlor is an insecticide that was intended...Ch. 9 - Prob. 35PCh. 9 - Prob. 36PCh. 9 - Prob. 37PCh. 9 - Prob. 38PCh. 9 - Prob. 39PCh. 9 - Prob. 40PCh. 9 - Starting with cyclohexene, how can the following...Ch. 9 - Prob. 42PCh. 9 - The pKa of acetic acid in water is 4.76. What...Ch. 9 - Prob. 44PCh. 9 - Prob. 45PCh. 9 - Prob. 46PCh. 9 - Prob. 47PCh. 9 - Prob. 48PCh. 9 - Prob. 49PCh. 9 - Prob. 50PCh. 9 - Prob. 51PCh. 9 - tert-Butyl chloride undergoes solvolysis in both...Ch. 9 - Prob. 53PCh. 9 - Prob. 54PCh. 9 - In which solventethanol or diethyl etherwould the...Ch. 9 - Prob. 56PCh. 9 - Two bromoethers are obtained from the reaction of...Ch. 9 - Prob. 58PCh. 9 - Prob. 59PCh. 9 - Prob. 60PCh. 9 - Propose a mechanism for the following reaction:Ch. 9 - Prob. 62PCh. 9 - Prob. 63PCh. 9 - Prob. 64PCh. 9 - Prob. 65PCh. 9 - When equivalent amounts of methyl bromide nod...Ch. 9 - Prob. 67PCh. 9 - The reaction of chloromethane with hydroxide ion...
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