Organic Chemistry
Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Chapter 9, Problem 68P

The reaction of chloromethane with hydroxide ion at 30°C has a ΔG° value of –21.7 kcal/mol. What is the equilibrium constant for the reaction?

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) The reaction of hydroxide ion with chloromethane to yield methanol and chloride ion is an example of a general reaction type called a nucleophilic substitution reaction: HO¯ + CH;CI = CH;OH + CI¯ The value of AHº for the reaction is -75 kJ/mol, and the value of ASº is +54 J/ (K- mol). What is the value of AG° (in kJ/mol) at 298 K? Is the reaction exothermic or endothermic? Is it exergonic or endergonic?
The conversion of butane to 2-methylpropane is an equilibrium process with ΔH° = −2.05 kcal/mol and ΔG° = −0.89 kcal/mol. What is the change in entropy for this conversion? What is the equilibrium constant for this reaction?
CH3COOH + 2H2 = C2H5OH + H2O %3D Acetate Ethanol Acetate may be hydrogenated to ethanol in industrial reaction systems using several catalysts: Select the most effective catalyst for this reaction system if the free energy of the reaction is -34 kJ/mol; Catalist effective at the temperature range 37-45°C, O Catalist effective at the temperature range 40-55°C, O Catalist effective at the temperature range 60-72°C,

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