
Interpretation:
The total heat energy required to melt 36.00 g of ice from −10∘C to 20∘C has to be calculated.
Concept Introduction:
Calculation of heat energy:
When both the phases are same, ΔH0=m×s×Δθ
When two phases are different, ΔH0=n×Δfus or vapH0

Answer to Problem 36QRT
The total heat energy required to melt a 36.00 g of ice from −10∘C to 20∘C has been calculated to be 15.7 kJ.
Explanation of Solution
Given data:
The heat capacities of solid ice and liquid water are 2.06 Jg−1 ∘C−1 and 4.184 Jg−1 ∘C−1 respectively. The fusion of enthalpy for solid ice is 6.02 kJ/mol. The vaporization enthalpy of liquid water is 40.7 kJ/mol.
Calculation of no. of moles of ice:
No. of moles (n)=mM=36 g18.0152 g/mol=1.998 mol.
- 1. Heat the ice from -10oC to 0oC
The heat energy required for 36 g of ice to melt can be calculated as given below.
ΔH0=m×s×Δθ=(36 g)(2.06 Jg−1 ∘C−1)[(0∘C)−(−10∘C)]=741.6 J=741.6 J×1 kJ1000J=0.7416 kJ.
Where, m= mass of ice, s= Specific heat of solid ice and Δθ= Temperature difference.
- 2. Melt the ice at 0oC
The heat energy required for this process can be calculated as given below.
ΔH0=n×ΔfusH0= 1.998 mol×6.020 kJmol= 12.02796 kJ.
Where, n= No. of moles of ice and ΔfusH0= Fusion enthalpy of solid ice.
- 3. Heat the water from 0oC to 20oC
The heat energy required for this process can be calculated as given below.
ΔH0=m×s×Δθ=(36 g)(4.184 Jg−1 ∘C−1)[(20∘C)−(0∘C)]=3012.48 J= 3012.48 J×1 kJ1000J= 3.01248 kJ.
Where, m= mass of water, s= Specific heat of liquid water and Δθ= Temperature difference.
Now, the total heat energy required to melt a 36.00 g of ice from −10∘C to 20∘C is the sum total of all the heat energies required for each transition:
ΔH∘= 0.7416 kJ+12.02796 kJ+3.01248 kJ= 15.78204 kJ ≅ 15.7 kJ.
Therefore, the total heat energy required to melt a 36.00 g of ice from −10∘C to 20∘C has been calculated to be 15.7 kJ.
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Chapter 9 Solutions
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