Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 8.7, Problem BQ
Interpretation Introduction
Interpretation:
The reason for the stabilization of radical formed in the reaction of the red
Concept introduction:
Autoxidation involves reaction of a
Mechanism involves a radical chain process in which resonance-delocalized allylic radical intermediates reacts with molecular oxygen to give peroxy radical that continues the radical chain.
Major product is more substituted double bond.
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The compound below is treated with chlorine in the presence of light.
H₂C
CH3
H3C
CH₂CH3
Draw the structure for the organic radical species produced by reaction of the compound with a chlorine
atom. Assume reaction occurs at the weakest C-H bond.
• You do not have to consider stereochemistry.
• You do not have to explicitly draw H atoms.
What are the bond-line formulas for the following compounds?
a. 6-butyl-4,7-diethylundecaneb. 1-bromo-3-ethyl-5-methylcyclohexanec. trans-1,3-dimethylcyclopentane
d. 1-bromopropane (the most stable Newman projection)e. trans-1,2-dibromocyclohexane (the most stable chair conformation)
10. A compound X of molecular formula C8H12 with no triple bonds reacts with one
equivalent of H2 to give a new compound having molecular formula CaH14.
What can be inferred about the structure of compound X?
A) Compound X has 3 rings.
B)
Compound X has 3 pi bonds.
Compound X has 1 ring and 2 pi bonds.
D) Compound X has 2 rings and 1 pi bond.
11. Determine the product of the following reaction.
H,
Lindlar's cat.
%3D
IV
A)I B) II C) III D) IV
Type here to search
互i | A C
三D
Chapter 8 Solutions
Organic Chemistry
Ch. 8.2 - Prob. 8.1PCh. 8.4 - Name and draw structural formulas for all...Ch. 8.4 - Using the table of bond dissociation enthalpies in...Ch. 8.5 - Prob. 8.4PCh. 8.6 - Given the solution to Example 8.5, predict the...Ch. 8.7 - Prob. 8.6PCh. 8.7 - Linoleic acid is shown below. What makes this...Ch. 8.7 - Prob. BQCh. 8.7 - Prob. CQCh. 8.7 - The strength of the HO bond in vitamin E is weaker...
Ch. 8.7 - Prob. EQCh. 8.8 - Prob. 8.7PCh. 8 - Prob. 8.8PCh. 8 - Prob. 8.9PCh. 8 - Prob. 8.10PCh. 8 - Prob. 8.11PCh. 8 - Account for the fact that among the chlorinated...Ch. 8 - Name and draw structural formulas for all possible...Ch. 8 - Prob. 8.14PCh. 8 - There are three constitutional isomers with the...Ch. 8 - Following is a balanced equation for bromination...Ch. 8 - Prob. 8.17PCh. 8 - Prob. 8.18PCh. 8 - Prob. 8.19PCh. 8 - Cyclobutane reacts with bromine to give...Ch. 8 - Prob. 8.21PCh. 8 - Following is a balanced equation for the allylic...Ch. 8 - Prob. 8.23PCh. 8 - Prob. 8.24PCh. 8 - The major product formed when methylenecyclohexane...Ch. 8 - Prob. 8.26PCh. 8 - Prob. 8.27PCh. 8 - Prob. 8.28PCh. 8 - Write the products of the following sequences of...Ch. 8 - Using your reaction roadmap as a guide, show...Ch. 8 - Prob. 8.31PCh. 8 - Prob. 8.32PCh. 8 - Prob. 8.33PCh. 8 - Prob. 8.34P
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