The iodination of ethylene at
(a) Calculate
(b) Is the reaction exergonic or endergonic at
(c) What happens to K as the temperature is raised?
Want to see the full answer?
Check out a sample textbook solutionChapter 8 Solutions
Organic Chemistry - Standalone book
- Actually, the carbon in CO2(g) is thermodynamically unstable with respect to the carbon in calcium carbonate(limestone). Verify this by determining the standardGibbs free energy change for the reaction of lime,CaO(s), with CO2(g) to make CaCO3(s).arrow_forwarda Calculate K1, at 25C for phosphoric acid: H3PO4(aq)H+(aq)+H2PO4(aq) b Which thermodynamic factor is the most significant in accounting for the fact that phosphoric acid is a weak acid? Why ?arrow_forwardAnother step in the metabolism of glucose, which occurs after the formation of glucose6-phosphate, is the conversion of fructose6-phosphate to fructose1,6-bisphosphate(bis meanstwo): Fructose6-phosphate(aq) + H2PO4(aq) fructose l,6-bisphosphate(aq) + H2O() + H+(aq) (a) This reaction has a Gibbs free energy change of +16.7 kJ/mol of fructose6-phosphate. Is it endergonic or exergonic? (b) Write the equation for the formation of 1 mol ADP fromATR for which rG = 30.5 kJ/mol. (c) Couple these two reactions to get an exergonic process;write its overall chemical equation, and calculate theGibbs free energy change.arrow_forward
- What is the sign of the standard Gibbs free-energy change at low temperatures and at high temperatures for the explosive decomposition of TNT? Use your knowledge of TNT and the chemical equation, particularly the phases, to answer this question. (Thermodynamic data for TNT are not in Appendix G.) 2C7H5N3O6(s) 3N2(g) + 5H2O() + 7C(s) + 7CO(g)arrow_forwardCalculate the standard Gibbs free-energy change when SO3 forms from SO2 and O2 at 298 K. Why is sulfur trioxide an important substance to study? (Hint: What happens when it combines with water?)arrow_forwardElemental boron, in the form of thin fibers, can be made by reducing a boron halide with H2. BCl3(g) + 3/2 H2(g) B(s) + 3HCl(g) Calculate H, S, and G at 25 C for this reaction. Is the reaction predicted to be product favored at equilibrium at 25 C? If so, is it enthalpy driven or entropy driven?arrow_forward
- Is the formation of ozone (O3(g)) from oxygen (O2(g)) spontaneous at room temperature under standard state conditions?arrow_forwardWhat information can be determined from G for a reaction? Does one get the same information from G, the standard free energy change? G allows determination of the equilibrium constant K for a reaction. How? How can one estimate the value of K at temperatures other than 25C for a reaction? How can one estimate the temperature where K = 1 for a reaction? Do all reactions have a specific temperature where K = 1?arrow_forwardWhat is a spontaneous reaction?arrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningPrinciples of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning