Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
8th Edition
ISBN: 9780134015187
Author: John E. McMurry, David S. Ballantine, Carl A. Hoeger, Virginia E. Peterson
Publisher: PEARSON
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Chapter 7.9, Problem 7.17P
Interpretation Introduction

Interpretation:

To number of moles of glucose that required to generate 272kcal of energy is to be determined.

Concept Introduction:

Chemical equation is the representation of a chemical reaction, in which the reactants and products of the reactions are represented left and right side of an arrow respectively by using their respective chemical formulas.

Metabolization of glucose produces carbon dioxide and water. overall Metabolism reaction is,

C6H12O6(aq)+6O2(g)6CO2(g)+6H2O(l)+678kcal

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A person weighing 150 pounds who is running 1 mile in ten minutes, will burn 100-120 Calories. A 200 lb person uses 135-155 Cal for the same run. A)How much ATP (in grams) is needed for such a workout? The molecular weight for ATP is 507 g/mol. The standard free energy for hydrolysis of the g-phosphate group in ATP is -32 kJ/mol. 1 Cal = 1000 calories, and 1kcal = 4.184 kJ. B)How many grams of glucose is needed to supply energy for this run under aerobicand anaerobicconditions? Assume that we make 30 ATP from one glucose molecule under aerobic conditions. MW(glucose)= 180 g/mol.
During glycolysis, glucose is converted into fructose-6- phosphate in two successive reactions: glucose + ATP glucose 6-phosphate + ADP glucose 6-phosphate fructose 6-phosphate The AG' for the overall reaction is: +15.0 kJ/mol. -18.4 kJ/mol. -16.7 kJ/mol. → -15.0 kJ/mol. +18.4 kJ/mol. AG¹⁰ = -16.7 kJ/mol AG¹⁰ = +1.7 kJ/mol
Glucose 1-phosphate is converted into fructose 6-phosphate in two successive reactions. Reaction 1: Glucose 1-phosphate → glucose 6-phosphate AG'° = -7.3 kJ/mol Reaction 2: Glucose 6-phosphate → fructose 6-phosphate AGʻ° = +1.7 kJ/mol Using the values given, calculate the standard free-energy change, AGʻ°, ,for the sum of the two reactions: sum > Sum: Glucose 1-phosphate → fructose 6-phosphate AG'°, kJ/mol sum Calculate the equilibrium constant, K', eq > for the sum of the two reactions. K'e eq II

Chapter 7 Solutions

Fundamentals of General, Organic, and Biological Chemistry (8th Edition)

Ch. 7.5 - The reaction between iron and oxygen to form rust...Ch. 7.6 - Prob. 7.10PCh. 7.8 - Prob. 7.11PCh. 7.8 - Prob. 7.12PCh. 7.8 - Prob. 7.13PCh. 7.8 - The following diagrams represent two similar...Ch. 7.9 - Prob. 7.3CIAPCh. 7.9 - Prob. 7.4CIAPCh. 7.9 - Is the yield of SO3 at equilibrium favored by a...Ch. 7.9 - Prob. 7.16PCh. 7.9 - Prob. 7.17PCh. 7 - What are the signs of H, S, and G for the...Ch. 7 - Prob. 7.19UKCCh. 7 - Prob. 7.20UKCCh. 7 - Two curves are shown in the following energy...Ch. 7 - Prob. 7.22UKCCh. 7 - Prob. 7.23APCh. 7 - Prob. 7.24APCh. 7 - Prob. 7.25APCh. 7 - Prob. 7.26APCh. 7 - Acetylene (H C C H) is the fuel used in welding...Ch. 7 - Prob. 7.28APCh. 7 - Prob. 7.29APCh. 7 - Prob. 7.30APCh. 7 - Prob. 7.31APCh. 7 - Prob. 7.32APCh. 7 - Prob. 7.33APCh. 7 - Prob. 7.34APCh. 7 - Why are most spontaneous reactions exothermic?Ch. 7 - Prob. 7.36APCh. 7 - Prob. 7.37APCh. 7 - Prob. 7.38APCh. 7 - Prob. 7.39APCh. 7 - Prob. 7.40APCh. 7 - Prob. 7.41APCh. 7 - Prob. 7.42APCh. 7 - Prob. 7.43APCh. 7 - Prob. 7.44APCh. 7 - Prob. 7.45APCh. 7 - Prob. 7.46APCh. 7 - Prob. 7.47APCh. 7 - Prob. 7.48APCh. 7 - What is meant by the term chemical equilibrium?...Ch. 7 - Prob. 7.50APCh. 7 - Prob. 7.51APCh. 7 - Prob. 7.52APCh. 7 - Prob. 7.53APCh. 7 - Prob. 7.54APCh. 7 - Use your answer from Problem 7.53 to calculate the...Ch. 7 - Use your answer from Problem 7.54 to calculate the...Ch. 7 - Prob. 7.57APCh. 7 - Prob. 7.58APCh. 7 - Prob. 7.59APCh. 7 - Prob. 7.60APCh. 7 - Prob. 7.61APCh. 7 - Prob. 7.62APCh. 7 - Prob. 7.63APCh. 7 - Prob. 7.64APCh. 7 - Prob. 7.65APCh. 7 - Prob. 7.66APCh. 7 - For the unbalanced combustion reaction shown, 1...Ch. 7 - Prob. 7.68CPCh. 7 - Prob. 7.69CPCh. 7 - Prob. 7.70CPCh. 7 - Urea is a metabolic waste product that decomposes...Ch. 7 - Prob. 7.72CPCh. 7 - Prob. 7.73CPCh. 7 - Methanol, CH3OH, is used as race car fuel. (a)...Ch. 7 - Prob. 7.75CPCh. 7 - Prob. 7.76CPCh. 7 - Prob. 7.77CPCh. 7 - Prob. 7.78GPCh. 7 - Prob. 7.79GPCh. 7 - Prob. 7.80GP
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