Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 7, Problem 19PP
Interpretation Introduction
Interpretation:
The products of the given acid–base reactions are to be predicted and, in each case, the stronger acid, the stronger base, the weaker acid, and the weaker base are to be labeled.
Concept introduction:
Substitution reaction: A reaction in which one of the hydrogen atoms of a hydrocarbon, or a
Elimination reaction: A reaction in which two substituent groups are detached and a double bond is formed is called elimination reaction.
Addition reaction: It is the reaction in which unsaturated bonds are converted to saturated molecules by addition of molecules.
Sodium amide is a strong base that helps in the removal of terminal hydrogen of
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6. Predict the products of the following acid-base reactions, and predict whether the equilibrium lies to the left or to the right of the reaction arrow:
(a) O2-(aq) + H2O(1)<--->
(b) CH3COOH(aq) + HS-(aq)<--->
(c) NO2-(aq) + H2O(1)<--->
Group of answer choices
A.) (a) 2 OH-; 100% to products
(b) CH3COO- + H2S; towards products
(c) HNO2 + OH-; towards reactants
B.) (a) 2 OH-; 100% to products
(b) CH3COO- + H2S; 100% to products
(c) HNO2 + OH-; towards reactants
C.) (a) 2 OH-; 100% to products
(b) CH3COO- + H2S; towards products
(c) HNO2 + OH-; towards products
D.) (a) 2 OH-; towards reactants
(b) CH3COO- + H2S; towards products
(c) HNO2 + OH-; towards reactants
(a) Predict the products of the following acid-base reactions using curved-arrow
mechanisms to indicate electron flow. (b) Indicate the acid, base, conjugate acid, and
conjugate base of each reaction. (c) Indicate whether the reactants or products are favored at
equilibrium
a)
CH,COOH
CH3O
b)
CH,CH,OH
H2N
(a) Find the equilibrium constant for following acid dissociation reaction at 25°C. Start your answer by writing the equation for Ka written with ΔG°.
NH4+ ↔ NH3 + H+
Is your calculated equilibrium constant (Ka) consistent with the value given in the course handout?
(b) Find Ka for the reaction at 10 and 40°C. Discuss how temperature affects fractionation between NH4+ and NH3.
(c) NH3 is often called free ammonia as opposed to ammonium ion. While ammonia ions are relatively benign, free ammonia is known to be toxic for microbial growth at high concentration especially in high strength wastewater treatment. Briefly discuss about potential temperature effects on the toxicity in biological wastewater treatment.
Chapter 7 Solutions
Organic Chemistry
Ch. 7 - Prob. 1PPCh. 7 - Prob. 2PPCh. 7 - Prob. 3PPCh. 7 - Prob. 4PPCh. 7 - Practice Problem 7.5
How many stereoisomers are...Ch. 7 - Prob. 6PPCh. 7 - Prob. 7PPCh. 7 - PRACTICE PROBLEM 7.8
Examine Solved Problem 7.3....Ch. 7 - Prob. 9PPCh. 7 - Practice Problem 7.10 When...
Ch. 7 - Practice Problem 7.11
(a) When...Ch. 7 - Prob. 12PPCh. 7 - Prob. 13PPCh. 7 - Practice Problem 7.14
Dehydration of 2-propanol...Ch. 7 - Practice Problem 7.15
Rank the following alcohols...Ch. 7 - Practice Problem 7.16
Acid-catalyzed dehydration...Ch. 7 - Practice Problem 7.17 Acid-catalyzed dehydration...Ch. 7 - Prob. 18PPCh. 7 - Prob. 19PPCh. 7 - Practice Problem 7.20
Show how you might...Ch. 7 - Prob. 21PPCh. 7 - Prob. 22PPCh. 7 - Practice Problem 7.23
Write the structure of...Ch. 7 - Prob. 24PPCh. 7 - Prob. 25PPCh. 7 - Practice Problem 7.26 (a) Devise retrosynthetic...Ch. 7 - Each of the following names is incorrect, Give the...Ch. 7 - Prob. 28PCh. 7 - Prob. 29PCh. 7 - Give the IUPAC names for each of the following:...Ch. 7 - Prob. 31PCh. 7 - Prob. 32PCh. 7 - Prob. 33PCh. 7 - Prob. 34PCh. 7 - 7.35. Write structural formulas for all the...Ch. 7 - 7.36. Explain the following observations: When...Ch. 7 - Prob. 37PCh. 7 - Arrange the following alcohols in order of their...Ch. 7 - Prob. 39PPCh. 7 - Prob. 40PPCh. 7 - Prob. 41PPCh. 7 - Prob. 42PPCh. 7 - Your task is to prepare isopropyl methyl ether by...Ch. 7 - Prob. 44PCh. 7 - Prob. 45PCh. 7 - Prob. 46PCh. 7 - 7.47. Starting with an appropriate alkyl halide...Ch. 7 - Prob. 48PCh. 7 - 7.49. What is the index of hydrogen deficiency...Ch. 7 - Prob. 50PCh. 7 - Prob. 51PCh. 7 - Compounds I and J both have the molecular formula...Ch. 7 - Prob. 53PCh. 7 - 7.54. Outline a synthesis of phenylethyne from...Ch. 7 - Prob. 55PPCh. 7 - Prob. 56PPCh. 7 - Prob. 57PPCh. 7 - cis-4-Bromocyclohexanol tBuOHtBuO racemic C6H10O...Ch. 7 - Prob. 59PPCh. 7 - Consider the interconversion of cis-2-butene and...Ch. 7 - Prob. 61PCh. 7 - (a) Using reactions studied in this chapter, show...Ch. 7 - Prob. 63PCh. 7 - Prob. 64PCh. 7 - 1. Write the structure(s) of the major product(s)...Ch. 7 - Prob. 2LGPCh. 7 - (a) Write the structure of the product(s) formed...Ch. 7 - Prob. 4LGP
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