Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
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Question
Chapter 6, Problem 6N.7E
(a)
Interpretation Introduction
Interpretation:
The potential of the given cell reaction has to be determined.
(b)
Interpretation Introduction
Interpretation:
The potential of the given cell reaction has to be determined.
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State what is expected to happen to the cell potential when the specified changes are made to the following cells. Confirm your prediction by using the Nernst equation in each case.(a) The molar concentration of silver nitrate in the left-hand compartment is increased in the cell Ag(s)|AgNO3(aq,mL)||AgNO3(aq,mR)|Ag(s).(b) The pressure of hydrogen in the left-hand compartment is increased in the Pt(s)|H2(g,pL)|HCl(aq)|H2(g,pL)|Pt(s).(c) The pH of the right-hand compartment is decreased in the cell Pt(s)|K3[Fe(CN)6](aq),K4[Fe(CN)6](aq)||Mn2+(aq),H+(aq)|MnO2(s)|Pt(s).(d) The concentration of HCl is increased in the cell Pt(s)|Cl2(g)|HCl(aq)||HBr(aq)|Br2(l)|Pt(s).(e) Some iron(III) chloride is added to both compartments of the cell Pt(s)|Fe3+(aq),Fe2+(aq)||Sn4+(aq),Sn2+(aq)|Pt(s)(f) Acid is added to both compartments of the cell Fe(s)|Fe2+(aq)||Mn2+(aq), H+(aq)|MnO2(s)|Pt(s).
13.38 For the cell at 25°C and 1 bar
Pt|Ag|AGCI(s)|HCI(aq)|Hg,Cl,(s)|Hg|Pt'
(a) write the cell reaction; (b) use Table 13.1 to find the emf if
the HCl molality is 0.100 mol/kg; (c) find the emf if the HCl mo-
lality is 1.00 mol/kg. (d) For this cell, (8E/aT)p = 0.338 mV/K
at 25°C and 1 bar. Find AG°, AH°, and ASº for the cell reaction
at 25°C.
Write the equilibrium constant expression, K, for the following reaction taking place in dilute aqueous solution.
HCN (aq) + OH" (aq) CN" (aq) + H,0 (1)
K =
Chapter 6 Solutions
Chemical Principles: The Quest for Insight
Ch. 6 - Prob. 6A.1ASTCh. 6 - Prob. 6A.1BSTCh. 6 - Prob. 6A.2ASTCh. 6 - Prob. 6A.2BSTCh. 6 - Prob. 6A.3ASTCh. 6 - Prob. 6A.3BSTCh. 6 - Prob. 6A.1ECh. 6 - Prob. 6A.2ECh. 6 - Prob. 6A.3ECh. 6 - Prob. 6A.4E
Ch. 6 - Prob. 6A.5ECh. 6 - Prob. 6A.6ECh. 6 - Prob. 6A.7ECh. 6 - Prob. 6A.8ECh. 6 - Prob. 6A.9ECh. 6 - Prob. 6A.10ECh. 6 - Prob. 6A.11ECh. 6 - Prob. 6A.12ECh. 6 - Prob. 6A.13ECh. 6 - Prob. 6A.14ECh. 6 - Prob. 6A.15ECh. 6 - Prob. 6A.16ECh. 6 - Prob. 6A.17ECh. 6 - Prob. 6A.18ECh. 6 - Prob. 6A.19ECh. 6 - Prob. 6A.20ECh. 6 - Prob. 6A.21ECh. 6 - Prob. 6A.22ECh. 6 - Prob. 6A.23ECh. 6 - Prob. 6A.24ECh. 6 - Prob. 6B.1ASTCh. 6 - Prob. 6B.1BSTCh. 6 - Prob. 6B.2ASTCh. 6 - Prob. 6B.2BSTCh. 6 - Prob. 6B.3ASTCh. 6 - Prob. 6B.3BSTCh. 6 - Prob. 6B.1ECh. 6 - Prob. 6B.2ECh. 6 - Prob. 6B.3ECh. 6 - Prob. 6B.4ECh. 6 - Prob. 6B.5ECh. 6 - Prob. 6B.6ECh. 6 - Prob. 6B.7ECh. 6 - Prob. 6B.8ECh. 6 - Prob. 6B.9ECh. 6 - Prob. 6B.10ECh. 6 - Prob. 6B.11ECh. 6 - Prob. 6B.12ECh. 6 - Prob. 6C.1ASTCh. 6 - Prob. 6C.1BSTCh. 6 - Prob. 6C.2ASTCh. 6 - Prob. 6C.2BSTCh. 6 - Prob. 6C.3ASTCh. 6 - Prob. 6C.3BSTCh. 6 - Prob. 6C.1ECh. 6 - Prob. 6C.2ECh. 6 - Prob. 6C.3ECh. 6 - Prob. 6C.4ECh. 6 - Prob. 6C.5ECh. 6 - Prob. 6C.6ECh. 6 - 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