Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 4.8, Problem 25P
Draw a perspective formula for each or the following:
- a. (S)-2-chlorobutane
- b. (R)-1.2-dibromobutanee
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1. Draw the structure of:
a. (S)-3-phenylheptane
b. (S)-3-methylcyclopentene
c. (R)-4-methyl-2-hexene
Glycerol contains:
Select one:
a. Oxygens double-bonded to carbon, with alkyls on both sides
b. oxygens single-bonded to primary and secondary carbons
O c. oxygens which are each bonded to two alkyl groups
Od. Oxygens double-bonded to carbon, with alkyls on one side only
Oe. Oxygens double-bonded to carbon, with an alkyl on one side and an --OH on the other side
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What is the IUPAC name of the following compound?
CH,
a. (R)-4-methyl-2-hexyne
b. (S)-4-methyl-2-hexyne
c. (R)-3-methyl-4-hexyne
d. (S)-3-methyl-4-hexyne
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Chapter 4 Solutions
Organic Chemistry (8th Edition)
Ch. 4.1 - Prob. 2PCh. 4.1 - Prob. 3PCh. 4.1 - Prob. 4PCh. 4.1 - Prob. 5PCh. 4.1 - Which of the roll owing compounds have a dipole...Ch. 4.2 - Draw and label the E and Z isomers for each of the...Ch. 4.2 - Assign relative priorities to each set of...Ch. 4.2 - Tamoxifen slows the growth of some breast tumors...Ch. 4.2 - Prob. 10PCh. 4.2 - Name each of the following:
Ch. 4.2 - Draw the Z isomer of an alkene that has a CH3 and...Ch. 4.3 - Prob. 13PCh. 4.4 - Prob. 14PCh. 4.5 - Prob. 16PCh. 4.6 - Prob. 17PCh. 4.7 - Prob. 18PCh. 4.8 - Prob. 20PCh. 4.8 - Prob. 22PCh. 4.8 - Prob. 23PCh. 4.8 - Prob. 24PCh. 4.8 - Draw a perspective formula for each or the...Ch. 4.8 - Prob. 27PCh. 4.9 - Prob. 28PCh. 4.9 - What is the configuration of the following...Ch. 4.9 - Prob. 32PCh. 4.10 - Prob. 33PCh. 4.10 - (S)-(+)-Monosodium glutamate (MSG) is a flavor...Ch. 4.11 - Prob. 35PCh. 4.11 - Prob. 36PCh. 4.12 - Prob. 38PCh. 4.12 - Prob. 39PCh. 4.12 - The stereoisomer of cholesterol found in nature is...Ch. 4.12 - Prob. 41PCh. 4.13 - 1-Bromo-2-methylcyclopentane has four pairs of...Ch. 4.13 - Prob. 43PCh. 4.13 - Draw all possible stereoisomers for each of the...Ch. 4.13 - Prob. 45PCh. 4.13 - Of all the possible cyclooctanes that have one...Ch. 4.13 - Prob. 47PCh. 4.13 - Prob. 48PCh. 4.14 - Which of the following compounds has a...Ch. 4.14 - Draw all the stereoisomers for each of the...Ch. 4.15 - Prob. 52PCh. 4.15 - Name the isomers you drew in Problem 52.Ch. 4.15 - Chloramphenicol is a broad-spectrum antibiotic...Ch. 4.15 - Draw a perspective formula for each of the...Ch. 4.15 - Name the following:Ch. 4.15 - Prob. 57PCh. 4.15 - Prob. 59PCh. 4.15 - Convert the perspective formula to a skeletal...Ch. 4.15 - Prob. 62PCh. 4.16 - Prob. 63PCh. 4.17 - Limonene exists as two different stereoisomers....Ch. 4 - a. Draw three constitutional isomers with...Ch. 4 - Prob. 65PCh. 4 - Prob. 66PCh. 4 - Which of the following has an asymmetric center?...Ch. 4 - Prob. 68PCh. 4 - Prob. 69PCh. 4 - Prob. 70PCh. 4 - Prob. 71PCh. 4 - Assign relative priorities to each set of...Ch. 4 - Prob. 73PCh. 4 - Which of the following are optically active?Ch. 4 - Prob. 75PCh. 4 - Name the following:Ch. 4 - Which of the following has an achiral...Ch. 4 - Using skeletal structures, draw the stereoisomers...Ch. 4 - Prob. 79PCh. 4 - Citrate synthase, one of the enzymes in the series...Ch. 4 - Prob. 81PCh. 4 - Prob. 82PCh. 4 - Prob. 83PCh. 4 - Prob. 84PCh. 4 - Prob. 85PCh. 4 - Prob. 86PCh. 4 - Prob. 87PCh. 4 - Prob. 88PCh. 4 - Prob. 89PCh. 4 - a. Draw all the isomers with molecular formula...Ch. 4 - Prob. 91PCh. 4 - Prob. 92PCh. 4 - Draw structures for the following: a....Ch. 4 - For each of the following structures, draw the...Ch. 4 - Prob. 95PCh. 4 - Prob. 96PCh. 4 - Prob. 97PCh. 4 - a. Using the wedge-and-dash notation, draw the...Ch. 4 - Prob. 99PCh. 4 - Prob. 100PCh. 4 - Prob. 101PCh. 4 - a. Draw the two chair conformers for each of the...Ch. 4 - Prob. 103PCh. 4 - Is the following compound optically active?Ch. 4 - Prob. 105P
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- Draw a condensed structure for each of the following: a. 2-hexyne b. 5-ethyl-3-octyne c. methylacetylene d. vinylacetylene e. methoxyethyne f. sec-butyl-tert-butylacetylene g. 1-bromo-1-pentyne h. 5-methyl-2-cyclohexenol i. diethylacetylene j. di-tert-butylacetylene k. cyclopentylacetylene l. 5,6-dimethyl-2-heptynearrow_forwardDraw the cis and trans isomers for the following: a. 1-bromo-4-chlorocyclohexane b. 1-ethyl-3-methylcyclobutanearrow_forwardDraw a condensed structure for each of the following: a. 2-hexyne b. 5-ethyl-3-octyne c. methylacetylene d. vinylacetylene e. methoxyethyne g. 1-bromo-1-pentyne h. 5-methyl-2-cyclohexeno i. diethylacetylene j. di-tert-butylacetylene k. cyclopentylacetylene l l. 5,6-dimethyl-2-heptynearrow_forward
- Using bond lines draw the structures of the following compounds: a. 5-ethyl-2-methyl-3-heptyne b. Cyclopentylcyclohexane c. 1-isopropyl-4-ethylcyclohexene d. 3-isobutyl-5-propylnonane e. 4-ethyl-3-methyl-2-heptene f. 6-methyl-5-phenyl-2-octynearrow_forwardEach of the following names is wrong. Give the structure and correct name of each compound. a 3-ethyl-2-methylbutanal b 2-ethyl-4-butanone c.4, 5-dibromocyclopentanonearrow_forward3. For the following questions, refer to the structures in the table: A. B. a CH3 H₂C H₂C- CH3 CH₂CH₂CH3 C. trans-1-ethyl-3- isopropylcyclohexane D. H3C CH3 3.1 What is the IUPAC name of the compound in A. 3.2 What is the IUPAC name of the compound in B. 3.3 Draw the other five Newman projections of the molecule in B (using the drawn structure as the first Newman Projection). Label your drawings with numeral numbers (II-VI). Determine which among the drawn structures is the most stable Newman projection and justify your answer. 3.4 Draw the chair and flipped chair conformation of the molecule in C. Show with an equilibrium arrow which is more stable and justify your answer. 3.5 Write is the balanced equation (use chemical formulas) when the molecule in compound D undergoes a complete combustion?arrow_forward
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- Give the IUPAC name of the following compounds: a. SH b. HSarrow_forward1. Provide the IUPAC name for each of the following organic molecules. a. b. C. H3C H3C, Home H3C CH3 CH3 CH3 Br H 2. Draw structures for the following organic molecules, using the wedged/hashed line convention to depict any stereochemical relationships between groups: a. cis-3-ethylcyclobutane-1-carbaldehyde b. (R)-1-chloro-6-iodo-6-methyloctan-3-onearrow_forwarda. b. Question 2: Give IUPAC name for each compound. o & C. d. 1 e. f.arrow_forward
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