The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound. Concept introduction: Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter. The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration. Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers. The pair of Enantiomers non-superimposable mirror images of each other.

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Answer 1

Question

Chapter 4, Problem 79P

(a)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

(b)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

(c)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

(d)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound are to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

Constitutional isomers have same molecular formula but different structural formula or bond connectivity.

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Answer 2

Question

Chapter 4, Problem 79P

(a)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

(b)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

(c)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

(d)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound are to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

Constitutional isomers have same molecular formula but different structural formula or bond connectivity.

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Answer 3

Question

Chapter 4, Problem 79P

(a)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

(b)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

(c)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

(d)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound are to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

Constitutional isomers have same molecular formula but different structural formula or bond connectivity.

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Answer 4

Question

Chapter 4, Problem 79P

(a)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

(b)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

(c)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

(d)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound are to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

Constitutional isomers have same molecular formula but different structural formula or bond connectivity.

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Answer 5

Chapter 4, Problem 79P

(a)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

(b)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

(c)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

(d)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound are to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

Constitutional isomers have same molecular formula but different structural formula or bond connectivity.

Answer 6

Chapter 4, Problem 79P

(a)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

Answer 7

Chapter 4, Problem 79P

(a)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound has to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound are to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

Constitutional isomers have same molecular formula but different structural formula or bond connectivity.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The identical, enantiomer, diastereomer or constitutional isomers for the given compound are to be identified from the given pairs of each compound.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

The interchanging the solid-hatched wedge line of two groups of asymmetric centers will give different configuration.

Diastereomers are stereoisomers which are neither mirror images nor identical. If two stereoisomers are not enantiomers, then they are Diastereomers.

The pair of Enantiomers non-superimposable mirror images of each other.

Constitutional isomers have same molecular formula but different structural formula or bond connectivity.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 4.1 - Prob. 2P Ch. 4.1 - Prob. 3P Ch. 4.1 - Prob. 4P Ch. 4.1 - Prob. 5P Ch. 4.1 - Which of the roll owing compounds have a dipole...Ch. 4.2 - Draw and label the E and Z isomers for each of the...Ch. 4.2 - Assign relative priorities to each set of...Ch. 4.2 - Tamoxifen slows the growth of some breast tumors...Ch. 4.2 - Prob. 10P Ch. 4.2 - Name each of the following:

Solution Summary: The author explains that stereoisomers have different spatial arrangement in spite of same bond connectivity.

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Chapter 4 Solutions