Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Textbook Question
Chapter 4, Problem 4.61P
Classify each pair of compounds as constitutional isomers, stereoisomers, identical molecules, or not isomers of each other.
a. 
and
e. 
and 
b. 
and
f. 
and 
c. 
and
g. 
and 
d. 
and
h. 
and 
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Students have asked these similar questions
1. Name each compound and determine the relationship between the pairs of compounds.
O
a. Name:
b. Name:
N
C. Relationship between structures above: Conformational isomer or Structural isomer
2. Name:
3. Is the following structure the cis stereoisomer or the trans stereoisomer?
Determine if each compound is a. constitutional isomers b. enantionmers c. diastereomers d. the same molecule
The following pair of molecules is best described as:
Select one:
a. structural isomers
O b. configurational isomers
O c. conformations of the same molecule
d. not a pair of isomers nor conformations of the same molecule
Chapter 4 Solutions
Organic Chemistry
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2PCh. 4 - (a) Classify the carbon atoms in each compound as...Ch. 4 - Problem 3.3 Classify a carbon atom by the number...Ch. 4 - Problem 4.3 Draw the five constitutional isomers...Ch. 4 - Prob. 4.6PCh. 4 - Prob. 4.7PCh. 4 - Draw the five constitutional isomers that have...Ch. 4 - Give the IUPAC name for each compound. a. c. b. ...Ch. 4 - Give the IUPAC name for each compound. a....
Ch. 4 - Problem 4.9 Give the structure corresponding to...Ch. 4 - Prob. 4.12PCh. 4 - Give the IUPAC name for each compound.Ch. 4 - Give the structure corresponding to each IUPAC...Ch. 4 - Arrange the following compounds in order of...Ch. 4 - Problem 4.14 Draw the staggered and eclipsed...Ch. 4 - Prob. 4.17PCh. 4 - a.Draw the three staggered and three eclipsed...Ch. 4 - Problem 4.19 Consider rotation around the...Ch. 4 - Calculate the destabilization present in each...Ch. 4 - Problem 4.21 Classify the ring carbons as up or...Ch. 4 - Draw a second chair conformation for each...Ch. 4 - Prob. 4.23PCh. 4 - Problem 4.25 Draw the structure for each compound...Ch. 4 - For cis-1, 3-diethylcyclobutane, draw a a...Ch. 4 - Prob. 4.26PCh. 4 - Problem 4.28 Consider .
Draw structures f or the...Ch. 4 - Problem 4.29 Draw a chair conformation of...Ch. 4 - Prob. 4.29PCh. 4 - Draw the products of each combustion reaction.Ch. 4 - Explain why beeswax is insoluble in H2O, slightly...Ch. 4 - Prob. 4.32PCh. 4 - Name each alkane using the ball-and-stick model,...Ch. 4 - Consider the substituted cyclohexane shown in the...Ch. 4 - Prob. 4.35PCh. 4 - 3.31 For each alkane: (a) classify each carbon...Ch. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Give the IUPAC name for each compound. a. h.k....Ch. 4 - 4.39 Give the structure and IUPAC name for each of...Ch. 4 -
4.40 Draw the structure corresponding to each...Ch. 4 - Prob. 4.42PCh. 4 - Prob. 4.43PCh. 4 - 4.42 Give the IUPAC name for each compound.
a....Ch. 4 - Prob. 4.45PCh. 4 - Prob. 4.46PCh. 4 - 4.45 Which conformation in each pair is higher in...Ch. 4 - Considering rotation around the bond highlighted...Ch. 4 - Prob. 4.49PCh. 4 - Prob. 4.50PCh. 4 - 4.49 Label the sites of torsional and steric...Ch. 4 - Prob. 4.52PCh. 4 - 4.51 The eclipsed conformation of is less...Ch. 4 - (a) Draw the anti and gauche conformations for...Ch. 4 - For each compound drawn below: a.Label each OH,Br...Ch. 4 - Draw the two possible chair conformations for...Ch. 4 - For each compound drawn below: a. Draw...Ch. 4 - 4.56 Convert each of the following structures into...Ch. 4 - Prob. 4.59PCh. 4 - Prob. 4.60PCh. 4 - Classify each pair of compounds as constitutional...Ch. 4 - Prob. 4.62PCh. 4 - Prob. 4.63PCh. 4 - 4.62 Draw the three constitutional isomers having...Ch. 4 - Prob. 4.65PCh. 4 - Prob. 4.66PCh. 4 - 4.65 Hydrocarbons like benzene are metabolized in...Ch. 4 - Which of the following compounds are lipids?Ch. 4 - Prob. 4.69PCh. 4 - Prob. 4.70PCh. 4 - Cyclopropane and cyclobutane have similar strain...Ch. 4 - Prob. 4.72PCh. 4 - Haloethanes (CH3CH2X,X=Cl,Br,I) have similar...Ch. 4 - Prob. 4.74PCh. 4 - Prob. 4.75PCh. 4 - Consider the tricyclic structure B (a) Label each...Ch. 4 - Read Appendix B on naming branched alkyl...Ch. 4 - Read Appendix B on naming bicyclic compounds. Then...
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- Explain the constitutional isomers ?arrow_forward6. Which of the following is not a constitutional isomer of the others? A. B. C. LOH etsarn D. -OHarrow_forwardWhich of the compounds can exist as enantiomers? A. Isopropyl chloride B. Bromochloromethane C. Sec-butyl chloride D. 1-chloro-2methylpentane a. A and B b. B and D c. C and D d. B and Carrow_forward
- Determine whether each compound exhibits optical isomerism. a. CCI4 b. CH3-CH2-CH-CH;-CH;-CH;-CH3 c. H CH3-C-CI NH2 d. CH,CHCICH,arrow_forwarda. 4.59 Classify each pair of compounds as constitutional isomers, stereoisomers, identical molecules, or not isomers of each other. and H- Дон -CH3 CH3 H b. and d. CH3CH2 H CH2CH3 and CH3CH2 CH3 H and CH3 H CH2CH3 Harrow_forwardHydrocarbons with only single covalent bond are known as... Select one: O a. alkanes O b. allylenes O C. alkynes O d. alkenesarrow_forward
- 179. Indicate whether the following pairs of skeletal line structures represent a pair of structural isomers or two different conformations of the same compound. a. and b. and and d.arrow_forward34. I and V are A. conformations B. chain (skeletal) isomers C. functional isomers D. positional isomers E. not isomersarrow_forwardWhich compound below is a trans isomer? a. b. c. d. none of the abovearrow_forward
- 1. Name and draw the isomers form from the given molecular formula. 20 pts. a. C4H10 b. C4H8Br2arrow_forwardWhich of the following is NOT an isomer of the other three? a. b. с. d.arrow_forwardThe dimethylcyclohexane with the structure shown below is: ÇH3 CH3 Select one: O a. a trans isomer with the CH3 groups in axial positions. O b. a cis isomer with the CH3 groups in equatorial positions. O c. a cis isomer with the CH3 groups in equatorial and axial positions. O d. a trans isomer with the CH3 groups in equatorial positions.arrow_forward
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