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The total surface area of Asia consisting of forest, cultivated land, grass land, and desert is
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Thermodynamics, Statistical Thermodynamics, & Kinetics
- If nitric acid were sufficiently heated, it can be decomposed into dinitrogen pentoxide and water vapor: 2HNO3(l)N2O5(g)+H2O(g)Hrxn=+176kJ (a) Calculate the enthalpy change that accompanies the reaction of 1.00 kg HNO3 (). (b) Is heat absorbed or released during the course of the reaction?arrow_forwardThe enthalpy change for the following reaction is 393.5 kJ. C(s,graphite)+O2(g)CO2(g) (a) Is energy released from or absorbed by the system in this reaction? (b) What quantities of reactants and products are assumed? (c) Predict the enthalpy change observed when 3.00 g carbon burns in an excess of oxygen.arrow_forwardAlthough the gas used in an oxyacetylene torch (Figure 5.7) is essentially pure acetylene, the heat produced by combustion of one mole of acetylene in such a torch is likely not equal to the enthalpy of combustion of acetylene listed in Table 5.2. Considering the conditions for which the tabulated data are reported, suggest an explanation.arrow_forward
- The thermochemical equation for the burning of methane, the main component of natural gas, is CH4(g)+2O2(g)CO2(g)+2H2O(l)H=890kJ (a) Is this reaction endothermic or exothermic? (b) What quantities of reactants and products are assumed if H = 890 kJ? (c) What is the enthalpy change when 1.00 g methane burns in an excess of oxygen?arrow_forwardThe Romans used calcium oxide, CaO, to produce a strong mortar to build stone structures. Calcium oxide was mixed with water to give Ca(OH)2, which reacted slowly with CO2 in the air to give CaCO3. Ca(OH)2(s) + CO2(g) CaCO3(s) + H2O(g) (a) Calculate the standard enthalpy change for this reaction. (b) How much energy is evolved or absorbed as heat if 1.00 kg of Ca(OH)2 reacts with a stoichiometric amount of CO2?arrow_forwardAcetic acid. CH3CO2H, is made industrially by the reaction of methanol and carbon monoxide. CH3OH () + CO(g) CH3CO2H() rH= 134.6 kJ/mol-rxn What is the enthalpy change for producing 1.00 L of acetic acid (d = 1.044 g/mL) by this reaction?arrow_forward
- The enthalpy of combustion of diamond is -395.4 kJ/mol. C s, dia O2 g CO2 g Determine the fH of C s, dia.arrow_forwardNitrogen monoxide, a gas recently found to be involved in a wide range of biological processes, reacts with oxygen to give brown NO2 gas. 2 NO(g) + O2(g) NO2(g)rH = 114.1 kJ/mol-rxn Is this reaction endothermic or exothermic? What is the enthalpy change if 1.25 g of NO is converted completely to NO2?arrow_forwardA rebreathing gas mask contains potassium superoxide, KO2, which reacts with moisture in the breath to give oxygen. 4KO2(s)+2H2O(l)4KOH(s)+3O2(g) Estimate the grams of potassium superoxide required to supply a persons oxygen needs for one hour. Assume a person requires 1.00 102 kcal of energy for this time period. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 1.00 102 kcal of heat, calculate the amount of oxygen consumed and hence the amount of KO2 required. The ff0 for glucose(s) is 1273 kJ/mol.arrow_forward
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