Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Textbook Question
Chapter 3, Problem 63P
Quinapril (trade name Accupril) is a drug used to treat hypertension and congestive heart
failure.
a. Identify the
b. Classify any alcohol, amide or
c. At which sites can quinapril hydrogen bond to water?
d. At which sites can quinapril hydrogen bond to acetone
e. Label the most acidic hydrogen atom.
f. Which site is most basic?
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Quinapril (trade name Accupril) is a drug used to treat hypertension and congestive heart failure.a.Identify the functional groups in quinapril.
b.Classify any alcohol, amide, or amine as 1°, 2°, or 3°.
c. At which sites can quinapril hydrogen bond to water?
d.At which sites can quinapril hydrogen bond to acetone [(CH3)2CO]?
e. Label the most acidic hydrogen atom.
f.Which site is most basic?
Erythronolide B is the biological precursor of erythromycin, a broad-spectrum antibiotic. What functional group
Erythronolide B does contain?
a.
b.
H₂CH₂C
C.
H₂C
1
H₂C
2
3
4
O
Amide
d. Amine
OH
Erythronolide B
Ketone
Aldehyde
a
CH₂
b
C
d
CH₂
OH
JCH₂
'OH
OH
List the products of each amine reaction.
H
b. CH;-N-CH-CH, + HCN
CH3
Chapter 3 Solutions
Organic Chemistry (6th Edition)
Ch. 3.1 - Prob. 1PCh. 3.2 - (a) Classify the carbon atoms in each compound as...Ch. 3.2 - Problem 3.3 Classify a carbon atom by the number...Ch. 3.2 - Classify each alkyl halide and alcohol as , or...Ch. 3.2 - Prob. 5PCh. 3.2 - Prob. 6PCh. 3.2 - Draw the structure of a compound of molecular...Ch. 3.2 - Prob. 8PCh. 3.2 - Prob. 9PCh. 3.2 - Draw the structure of a compound fitting each...
Ch. 3.4 - Predict which compound in each pair has the higher...Ch. 3.4 - Prob. 17PCh. 3.4 - a Label the hydrophobic and hydrophilic portions...Ch. 3.5 - Prob. 21PCh. 3 - 3.29
Identify the functional groups in the...Ch. 3 - Prob. 32PCh. 3 - 3.31 For each alkane: (a) classify each carbon...Ch. 3 - 3.32 Identify the functional groups in each...Ch. 3 - 3.33 Identify each functional group located in the...Ch. 3 - 3.34 (a)Identify the functional groups in...Ch. 3 - Draw seven constitutional isomers with molecular...Ch. 3 - Prob. 38PCh. 3 - Prob. 39PCh. 3 - Prob. 40PCh. 3 - Intramolecular force of attraction are often...Ch. 3 - 3.40 (a) Draw four compounds with molecular...Ch. 3 - 3.41 Rank the compounds in each group in order of...Ch. 3 - Explain why CH3CH2NHCH3 has higher boiling point...Ch. 3 - Prob. 45PCh. 3 - 3.44 Rank the following compounds in order of...Ch. 3 - Prob. 47PCh. 3 - 3.50 Predict the solubility of each of the...Ch. 3 - Prob. 52PCh. 3 - Prob. 53PCh. 3 - 3.53 THC is the active component in marijuana, and...Ch. 3 - Prob. 55PCh. 3 - Prob. 56PCh. 3 - 3.60 Quinapril (trade name Accupril) is a drug...Ch. 3 - 3.61 Answer each question about oxycodone, a...Ch. 3 - Prob. 65PCh. 3 - Prob. 66PCh. 3 - 3.64 Explain why A is less water soluble than B,...Ch. 3 - 3.65 Recall from section 1.10B that there is...
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