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Concept explainers
(a)
Interpretation:
The explanation for iodoacetic acid reaction with side chain thiol group of a cysteine residue is to be stated. The reason as to why this reaction is necessary before sequencing is to be stated.
Concept introduction:
The reagent DTT is known as dithiothreitol and is a common redox reagent. It is also known as Cleland’s reagent. It is relatively not a stable compound due to air oxidation. It is used as a deprotecting group and to break the disulfide bond in protein.
(b)
Interpretation:
The product obtained on oxidation of disulfide bond with H2O2 that accomplishes the same objective is to be stated.
Concept introduction:
The compound hydrogen peroxide represented by H2O2 is more viscous than water. It is used as an oxidizer, antiseptic, bleaching agent, and to break the disulfide bond in protein. It is an unstable compound and it decomposes in the presence of light.
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Chapter 27 Solutions
Organic Chemistry
- Choose the best reagents to complete the following reaction. i H A B 1. CH3CH2Na 2. H3O+ 1. CH3CH2MgBr 2. H3O+ 1. CH3MgBr Q C 2. H3O+ 1. H3O+ D 2. CH3MgBr 00 OH Q E CH³MgBrarrow_forwardThe kinetics of a gas phase reaction of the form A → Products results in a rate constant of 0.00781 M/min. For this reaction, the initial concentration of A is 0.501 M. What is the half-life for this reaction?arrow_forwardChoose the best reagents to complete the following reaction. 1. PhNa A 2. H3O+ 1. PhCH2MgBr B 2. H3O+ хё 1. PhMgBr C 2. H3O+ 00 HO Q E D 1. H3O+ 2. PhMgBr PhMgBrarrow_forward
- Please answer all of the questions and provide detailed explanations and include a drawing to show the different signals on the molecule and include which ones should be highlighted.arrow_forwardDraw the major product of this reaction. Ignore inorganic byproducts. Incorrect, 1 attempt remaining 1. LiAlH4 2. H3O+ Q OH ☑ Select to Drawarrow_forwardHow should I graph my data for the Absorbance of Pb and Fe for each mushroom? I want to compare the results to the known standard curve. Software: Excel Spreadsheets Link: https://mnscu-my.sharepoint.com/:x:/g/personal/vi2163ss_go_minnstate_edu/Eb2PfHdfEtBJiWh0ipHZ_kkBW4idWWwvpLPPtqoq2WkgbQ?rtime=HxrF0_tR3Ugarrow_forward
- Provide the proper IUPAC name only for the following compound. Dashes, commas, and spaces must be used correctly, but do not use italics in Canvas.arrow_forwardThe kinetics of a gas phase reaction of the form A → Products results in a rate constant of 0.00781 M/min. For this reaction, the initial concentration of A is 0.501 M. How many minutes will it take for the concentration of A to reach 0.144 Marrow_forwardWhat is the rate for the second order reaction A → Products when [A] = 0.256 M? (k = 0.761 M⁻¹s⁻¹)arrow_forward
- For reaction N2(g) + O2(g) --> 2NO(g) Write the rate of the reaction in terms of change of NO.arrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forwardThe reaction of 2-oxacyclopentanone with hydrochloric acid in water (i.e., "excess") produces which of the following carboxylic acids?arrow_forward
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